Related papers: An improved approximation for the moist-air entrop…
It is important to be able to calculate the moist-air entropy of the atmosphere with precision. A potential temperature has already been defined from the third law of thermodynamics for this purpose. However, a doubt remains as to whether…
A moist entropy potential temperature -- denoted by ${\theta}_{s}$ -- is defined analytically in terms of the specific entropy for moist air. The expression for ${\theta}_{s}$ is valid for a general mixing of dry air, water vapour and…
A framework is introduced to compare moist `potential' temperatures. The equivalent potential temperature, $\theta_e,$ the liquid water potential temperature, $\theta_\ell,$ and the entropy potential temperature, $\theta_s$, are all shown…
The aim of this note is to derive the mixed-phase version of the moist-air entropy potential temperature $\theta_s$ derived in Marquet (2011). This mixed-phase version is suitable to describe parcels where liquid water and ice are allowed…
The aim of this note is to describe several meteorological properties shown in a conference talk (Marquet, January 2022) for the moist-air specific entropy, the associated potential temperature ($\theta_s$) defined in Marquet (2011) and the…
Internal energy, enthalpy and entropy are the key quantities to study thermodynamic properties of the moist atmosphere, because they correspond to the First (internal energy and enthalpy) and Second (entropy) Laws of thermodynamics. The aim…
Moist-air norms and inner-products are currently used in atmospheric science for computing dry or moist singular vectors and for determining forecast errors or sensitivity to observations based on tangent linear and adjoint models. A new…
This paper is the second part of a previous paper (Marquet, 2019) dealing with the need to define the entropy with an absolute way, by using the third law of thermodynamics. In this second part it is shown that there is a need and interest…
The specific thermal enthalpy of a moist-air parcel is defined analytically following a method in which specific moist entropy is derived from the Third Law of thermodynamics. Specific thermal enthalpy is computed by integrating specific…
This study presents a new formulation for the norms and scalar products used in tangent linear or adjoint models to determine forecast errors and sensitivity to observations and to calculate singular vectors. The new norm is derived from…
A new potential vorticity is derived by using a specific entropy formulation expressed in terms of a moist-air entropy potential temperature. The new formulation is compared with Ertel's version and with others based on virtual and…
Some existing approaches to modeling the thermodynamics of moist air make approximations that break $\textit{thermodynamic consistency}$, such that the resulting thermodynamics do not obey the 1st and 2nd laws or have other inconsistencies.…
The exergy of the dry atmosphere can be considered as another aspect of the meteorological theories of available energies. The local and global properties of the dry available enthalpy function, also called flow exergy, were investigated in…
Calculations of entropy fluxes and production rate have been evaluated with some success to study atmospheric processes. However, recurring questions arise as to how best to take into account entropy flux due to radiation, for example. This…
The moist-air entropy can be used to analyze and better understand the general circulation of the atmosphere or convective motions. Isentropic analyses are commonly based on studies of different equivalent potential temperatures, all of…
The length-scale dependence of the dynamic entropy is studied in a molecular dynamics simulation of a binary Lennard-Jones liquid above the mode-coupling critical temperature $T_c$. A number of methods exist for estimating the entropy of…
In a paper [8] the authors classify entropy into three categories, as a thermodynamics quantity, as a measure of information production, and as a means of statistical inference. An entropy measure introduced by Mathai falls into the second…
We define the entropy S and uncertainty function of a squeezed system interacting with a thermal bath, and study how they change in time by following the evolution of the reduced density matrix in the influence functional formalism. As…
Uncertainty exists concerning the proper formulation of surface heat fluxes, namely the sum of "sensible" and "latent" heat fluxes, and in fact concerning these two fluxes if they are considered as separate fluxes. In fact, eddy flux of…
This paper is a natural continuation of a previous one by the author, which was concerned with the foundations of statistical thermodynamics far from equilibrium. One of the problems left open in that paper was the correct definition of…