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We present high-quality optical data and density functional perturbation theory calculations for the vibrational spectrum of solid picene (C$_{22}$H$_{14}$) under pressure up to 8 GPa. First-principles calculations reproduce with a…

The Raman spectrum and particularly the Raman scattering intensities of monoclinic $\beta\text{-Ga}_2\text{O}_3$ are investigated by experiment and theory. The low symmetry of $\beta\text{-Ga}_2\text{O}_3$ results in a complex dependence of…

Materials Science · Physics 2017-02-07 Christian Kranert , Chris Sturm , Rüdiger Schmidt-Grund , Marius Grundmann

Magneto-Raman spectroscopy is applied to study spin-phonon coupling in the layered two-dimensional (2D) van der Waals antiferromagnet CrSBr. We report on the effects of temperature and external magnetic field on Raman-active phonons of…

Materials Science · Physics 2025-03-20 Urszula D. Wdowik , Vaibhav Varade , Jana Vejpravova , Dominik Legut

Phonon-phonon anharmonic effects have a strong influence on the phonon spectrum; most prominent manifestation of these effects are the softening (shift in frequency) and broadening (change in FWHM) of the phonon modes at finite temperature.…

We have carried out temperature and pressure-dependent Raman and x-ray measurements on single crystals of Tb$_2$Ti$_2$O$_7$. We attribute the observed anomalous temperature dependence of phonons to phonon-phonon anharmonic interactions. The…

Two-dimensional layered trichalcogenide materials have recently attracted the attention of the scientific community because of its robust mechanical, thermal properties and applications in opto and nanoelectronics devices. We report the…

We have developed a theory of the one-phonon intraband resonance Raman scattering (IRRS) in anisotropic quantum dots subjected to an arbitrarily directed magnetic field. The differential Raman cross section is obtained. The resonance…

Mesoscale and Nanoscale Physics · Physics 2010-01-08 A. V. Shorokhov , V. A. Margulis

Magnetic and crystallographic transitions in the Cairo pentagonal magnet Bi2Fe4O9 are investigated by means of infrared synchrotron-based spectroscopy as a function of temperature (20 - 300 K) and pressure (0 - 15.5 GPa). One of the phonon…

Other Condensed Matter · Physics 2021-05-05 M. Verseils , A. P. Litvinchuk , J-B Brubach , P. Roy , K. Beauvois , E. Ressouche , V. Skumryev , M. Gospodinov , V. Simonet , S. deBrion

Using very uniform large scale chemical vapor deposition grown graphene transferred onto silicon, we were able to identify 15 distinct Raman lines associated with graphene monolayers. This was possible thanks to a combination of different…

Mesoscale and Nanoscale Physics · Physics 2012-11-07 Simon Bernard , Eric Whiteway , Victor Yu , D. G. Austing , Michael Hilke

The IR- and Raman-active phonon frequencies, as well as the elastic constants of orthorhombic GeSe, were calculatedas a function of hydrostatic pressure using the method of density functional in the ABINIT software package. Comparison with…

Materials Science · Physics 2013-03-12 F. M. Hashimzade , D. A. Huseinova , Z. A. Jahangirli , B. H. Mehdiyev , G. S. Orudzhev

The electrical conductivity and Raman spectroscopy measurements have been performed on MoS$_2$ at high pressures up to 90 GPa and variable temperatures down to 5 K. We find that the temperature dependence of the resistance in a metallic…

Materials Science · Physics 2018-06-27 Zi-Yu Cao , Jia-Wei Hu , Alexander F. Goncharov , Xiao-Jia Chen

We examine anharmonic contributions to the optical phonon modes in bulk $T_d$-MoTe$_2$ through temperature-dependent Raman spectroscopy. At temperatures ranging from 100 K to 200 K, we find that all modes redshift linearly with temperature…

Materials Science · Physics 2016-07-20 Jaydeep Joshi , Iris Stone , Ryan Beams , Sergiy Krylyuk , Irina Kalish , Albert Davydov , Patrick Vora

We present low-temperature Raman measurements on gate tunable graphene encapsulated in hexagonal boron nitride, which allows to study in detail the Raman G and 2D mode frequencies and line widths as function of the charge carrier density.…

Mesoscale and Nanoscale Physics · Physics 2023-02-15 Jens Sonntag , Kenji Watanabe , Takashi Taniguchi , Bernd Beschoten , Christoph Stampfer

We present results of our study of polarized Raman scattering and infrared reflectivity of rhombohedral ceramic La_1-ySr_yMn_1-xM_xO_3 manganites in the temperature range between 77 and 320K. In our samples, a part of the Mn atoms is…

Strongly Correlated Electrons · Physics 2009-11-11 A. Dubroka , J. Humlicek , M. V. Abrashev , Z. V. Popovic , F. Sapina , A. Cantarero

Orhorhombic $\alpha$-MoO$_3$ is a layered oxide with various applications and with excellent potential to be exfoliated as a 2D ultrathin film or monolayer. In this paper, we present a first-principles computational study of its vibrational…

Materials Science · Physics 2021-09-20 Amol Ratnaparkhe , Santosh Kumar Radha , Walter R. L. Lambrecht

Thermodynamic stability and vibrational anharmonicity of single layer black phosphorene (SLBP) are studied using a spectral energy density (SED) method. Thermal stability of SLBP sheet is analyzed by computing phonon dispersion at 300 K,…

Mesoscale and Nanoscale Physics · Physics 2020-06-24 P. Anees

New techniques for probing hyperbolic phonon polaritons (HPP) in 2D materials will support the development of the emerging technologies in this field. Previous reports have shown that it is possible for WSe2 monolayers in contact with the…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Jacob J. S. Viner , Liam P. McDonnell , Pasqual Rivera , Xiaodong Xu , David C. Smith

We report a systematic investigation of orthorhombic perovskite-type RCrO3 powder samples by Raman scattering for nine different rare earth R3+ cations (R = Y, La, Pr, Sm, Gd, Dy, Ho, Yb, Lu). The room-temperature Raman spectra and the…

Materials Science · Physics 2012-02-13 M. Weber , J. Kreisel , P. A. Thomas , M. Newton , K. Sardar , R. I. Walton

Broadening of the Raman scattering (RS) spectra was studied in monolayer graphene samples irradiated with various dose of ions followed by annealing of radiation damage at different temperatures. It is shown that the width {\Gamma} (full…

Mesoscale and Nanoscale Physics · Physics 2019-12-13 I. Shlimak , A. Butenko , E. Kogan , M. Kaveh

The pressure-induced changes in the optical properties of $\beta$-Na$_{0.33}$V$_2$O$_5$ single crystals at room temperature were studied by polarization-dependent Raman and far-infrared reflectivity measurements under high pressure. From…

Strongly Correlated Electrons · Physics 2018-02-02 Simone Frank , Christine A. Kuntscher , Ivan Gregora , Touru Yamauchi , Yutaka Ueda