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The problem of construction of the Wannier functions (WFs) in a restricted Hilbert space of eigenstates of the one-electron Hamiltonian $\hat{H}$ (forming the so-called low-energy part of the spectrum) can be formulated in several different…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev , Z. V. Pchelkina , V. I. Anisimov

Maximally-localized Wannier functions (MLWFs) are a powerful and broadly used tool to characterize the electronic structure of materials, from chemical bonding to dielectric response to topological properties. Most generally, one can…

Computational Physics · Physics 2023-11-07 Junfeng Qiao , Giovanni Pizzi , Nicola Marzari

Maximally localized Wannier functions are the key tool for a variety of physical applications of Bloch states. Here we develop a simple and exact procedure to construct maximally localized Wannier functions for one dimensional periodic…

Strongly Correlated Electrons · Physics 2014-12-12 Yuri Lensky , Colin Kennedy

Maximally-localised Wannier functions (MLWFs) are routinely used to compute from first-principles advanced materials properties that require very dense Brillouin zone integration and to build accurate tight-binding models for scale-bridging…

Computational Physics · Physics 2020-07-02 Valerio Vitale , Giovanni Pizzi , Antimo Marrazzo , Jonathan R. Yates , Nicola Marzari , Arash A. Mostofi

In this work, the nonlinear optical response, and in particular, the high harmonic generation of semiconductors is addressed by using the Wannier gauge. One of the main problems in the time evolution of the Semiconductor Bloch equations…

Mesoscale and Nanoscale Physics · Physics 2019-11-20 R. E. F. Silva , F. Martín , M. Ivanov

We present Wannier90, a program for calculating maximally-localised Wannier functions (MLWF) from a set of Bloch energy bands that may or may not be attached to or mixed with other bands. The formalism works by minimising the total spread…

Materials Science · Physics 2011-05-18 A. A. Mostofi , J. R. Yates , Y. -S. Lee , I. Souza , D. Vanderbilt , N. Marzari

Maximally-localized Wannier functions (MLWFs) are widely employed as an essential tool for calculating the physical properties of materials due to their localized nature and computational efficiency. Projectability-disentangled Wannier…

Materials Science · Physics 2025-11-25 Yuhao Jiang , Junfeng Qiao , Nataliya Paulish , Weisheng Zhao , Nicola Marzari , Giovanni Pizzi

Localized Wannier functions provide an efficient and intuitive means by which to compute dielectric properties from first principles. They are most commonly constructed in a post-processing step, following total-energy minimization.…

Materials Science · Physics 2012-05-16 David D. O'Regan , Mike C. Payne , Arash A. Mostofi

We present a robust algorithm that computes (maximally localized) Wannier functions (WFs) without the need of providing an initial guess. Instead, a suitable starting point is constructed automatically from so-called local orbitals which…

Materials Science · Physics 2020-07-01 Sebastian Tillack , Andris Gulans , Claudia Draxl

Wannier functions provide a localized representation of spectral subspaces of periodic Hamiltonians, and play an important role for interpreting and accelerating Hartree-Fock and Kohn-Sham density functional theory calculations in quantum…

Computational Physics · Physics 2018-01-29 Anil Damle , Antoine Levitt , Lin Lin

When the first four spectral moments are considered, spectral features missing in standard Kohn-Sham (KS) density-functional theory (DFT), such as upper and lower Hubbard bands, as well as spectral satellite peaks, can be described, and the…

Strongly Correlated Electrons · Physics 2023-01-13 Frank Freimuth , Stefan Blügel , Yuriy Mokrousov

A non-iterative method is presented to calculate the closest Wannier functions (CWFs) to a given set of localized guiding functions, such as atomic orbitals, hybrid atomic orbitals, and molecular orbitals, based on minimization of a…

Materials Science · Physics 2023-07-03 Taisuke Ozaki

Ab initio determination of model Hamiltonian parameters for strongly correlated materials is a key issue in applying many-particle theoretical tools to real narrow-band materials. We propose a self-contained calculation scheme to construct,…

Strongly Correlated Electrons · Physics 2008-09-09 Dm. Korotin , A. V. Kozhevnikov , S. L. Skornyakov , I. Leonov , N. Binggeli , V. I. Anisimov , G. Trimarchi

A robust, user-friendly, and automated method to determine quantum conductance in disordered quasi-one-dimensional systems is presented. The scheme relies upon an initial density- functional theory calculation in a specific geometry after…

Computational Physics · Physics 2015-03-17 Matthew Shelley , Nicolas Poilvert , Arash A Mostofi , Nicola Marzari

The construction of Wannier functions from Bloch orbitals offers a unitary freedom that can be exploited to yield Wannier functions with advantageous properties. Minimizing the spatial variance is a well-known choice; another, previously…

Materials Science · Physics 2026-04-29 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

A standard task in solid state physics and quantum chemistry is the computation of localized molecular orbitals known as Wannier functions. In this manuscript, we propose a new procedure for computing Wannier functions in one-dimensional…

Mathematical Physics · Physics 2025-10-21 Abinand Gopal , Hanwen Zhang

We present a spin-dependent extension of the non-orthogonal generalized Wannier function (NGWF) formalism within the framework of linear-scaling density functional theory (LS-DFT) as implemented in the ONETEP code. In traditional LS-DFT…

We develop a computational workflow for high-throughput Wannierization of density functional theory (DFT) based electronic band structure calculations. We apply this workflow to 1771 materials, and we create a database with the resulting…

Materials Science · Physics 2020-07-03 Kevin F. Garrity , Kamal Choudhary

We present an approach to parameterize DFT+$U$+$V$ from hybrid-functional calculations using Wannier-function projections. The method constructs a common localized Wannier basis for both semilocal DFT and hybrid-functional calculations,…

Strongly Correlated Electrons · Physics 2026-02-25 Dmitry M. Korotin , Anna A. Anisimova , Vladimir I. Anisimov

In this work, we use Wannier functions to analyze topological phase transitions in one dimensional photonic crystals. We first review the construction of exponentially localized Wannier functions in one dimension, and show how to…

Optics · Physics 2022-06-07 Vaibhav Gupta , Barry Bradlyn
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