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Most of dynamic nuclear polarization (DNP) has been requiring helium cryogenics and strong magnetic fields for a high degree of polarization. In this work, we instead demonstrate an optical hyperpolarization of naturally abundant $^{13}$C…

Color-center-hosting semiconductors are emerging as promising source materials for low-field dynamic nuclear polarization (DNP) at or near room temperature, but hyperfine broadening, susceptibility to magnetic field heterogeneity, and…

Quantum Physics · Physics 2022-06-01 J. Henshaw , D. Pagliero , P. R. Zangara , B. Franzoni , A. Ajoy , R. Acosta , J. A. Reimer , A. Pines , C. A. Meriles

After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…

Mesoscale and Nanoscale Physics · Physics 2021-01-27 J. -P. Tetienne , L. T. Hall , A. J. Healey , G. A. L. White , M. -A. Sani , F. Separovic , L. C. L. Hollenberg

We report bulk, room-temperature hyperpolarization of 13C nuclear spins observed via high-field nuclear magnetic resonance (NMR). The hyperpolarization is achieved by optical pumping (OP) of nitrogen vacancy defect centers in diamond…

Optically accessible spin-active nanomaterials are promising as quantum nanosensors for probing biological samples. However, achieving bioimaging-level brightness and high-quality spin properties for these materials is challenging and…

A broad effort is underway to improve the sensitivity of nuclear magnetic resonance through the use of dynamic nuclear polarization. Nitrogen-vacancy (NV) centers in diamond offer an appealing platform because these paramagnetic defects can…

Quantum sensors have attracted broad interest in the quest towards sub-micronscale NMR spectroscopy. Such sensors predominantly operate at low magnetic fields. Instead, however, for high resolution spectroscopy, the high-field regime is…

We demonstrate three-dimensional localization of a single nitrogen-vacancy (NV) center in diamond by combining nitrogen doping during growth with a post-growth 12C implantation technique that facilitates vacancy formation in the crystal. We…

Currently, the primary applications of fluorescent nanodiamonds (FNDs) are in the area of biosensing, by using photoluminescence or spin properties of colour centres, mainly represented by the Nitrogen Vacancy (NV) point defect. The…

Mesoscale and Nanoscale Physics · Physics 2026-05-19 Jeroen Prooth , Michael Petrov , Alevtina Shmakova , Michal Gulka , Petr Cigler , Jan D'Haen , Hans-Gerd Boyen , Milos Nesladek

The sensing capability of a single optically bright electronic spin in diamond can be enhanced by making use of proximal dark nuclei as ancillary spins. Such systems, so far only realized in bulk diamond, provide orders of magnitude higher…

Quantum Physics · Physics 2017-10-04 Helena S. Knowles , Dhiren M. Kara , Mete Atatüre

In many chemical reactions, short-lived radical intermediates play a crucial role, while detecting such short-lived species in-situ remains challenging. The optically readable electronic spin of nitrogen-vacancy (NV) centers in diamond is a…

Mesoscale and Nanoscale Physics · Physics 2026-04-22 Emma Herbst , Sebastian Westrich , Alena Erlenbach , Jonas Gutsche , Maria Wächtler , Elke Neu

The integration of NMR and high pressure technique brings unique opportunities to study electronic, structural and dynamical properties under extreme conditions. Despite a great degree of success has been achieved using coil-based schemes,…

Quantum Physics · Physics 2022-03-22 Yan-Xing Shang , Fang Hong , Jian-Hong Dai , Ya-Nan Lu , Hui Yu , Yong-Hong Yu , Xiao-Hui Yu , Xin-Yu Pan , Gang-Qin Liu

Nanodiamonds containing negatively charged nitrogen vacancy centres (${\text{NV}}^{-}$) have applications as localized sensors in biological material and have been proposed as a platform to probe the macroscopic limits of spatial…

Bulk 13C polarization can be strongly enhanced in diamond at room-temperature based on the optical pumping of nitrogen-vacancy color centers. This effect was confirmed by irradiating suitably aligned single-crystals at a ~50 mT field…

We report on a nuclear magnetic resonance (NMR) study of ultrananocrystalline diamond (UNCD) materials produced by detonation technique. Analysis of the 13C and 1H NMR spectra, spin-spin and spin-lattice relaxation times in purified UNCD…

Materials Science · Physics 2009-11-13 A. M. Panich , A. I. Shames , H. -M. Vieth , E. Osawa , M. Takahashi , A. Ya. Vul

Nuclear Magnetic Resonance (NMR) spans diverse fields from biology to quantum science. Employing NMR on a floating object could unveil novel possibilities beyond conventional operational paradigms. Here, we observe Nuclear Magnetic…

Quantum Physics · Physics 2024-07-30 J. Voisin , A. Durand , T. Copie , M. Perdriat , G. Hétet

The nitrogen-vacancy (NV) centers in nanodiamonds can be utilized as low-cost, highly versatile quantum sensors for studying surface properties in condensed matter physics through the application of relaxometry protocols. For such…

Mesoscale and Nanoscale Physics · Physics 2025-09-03 Izidor Benedičič , Yuri Tanuma , Žiga Gosar , Bastien Anézo , Mariusz Mrózek , Adam Wojciechowski , Denis Arčon

We report a study of the relaxation time of the restoration of the resistive superconducting state in single crystalline boron-doped diamond using amplitude-modulated absorption of (sub-)THz radiation (AMAR). The films grown on an…

The nuclear spin singlet order involving coupled pairs of spins-1/2 may be used to store nuclear spin hyperpolarization in a room temperature liquid for a time much longer than the spin-lattice relaxation time $T_1$. There both are…

Quantum Physics · Physics 2021-06-02 Y. Yang , L. Zhou , Q. Chen

Nitrogen-vacancy (NV) centers in millimeter-scale diamond samples were produced by irradiation and subsequent annealing under varied conditions. The optical and spin relaxation properties of these samples were characterized using confocal…