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Electronic polarization and charge transfer effects play a crucial role in thermodynamic, structural and transport properties of room-temperature ionic liquids (RTILs). These non-additive interactions constitute a useful tool for tuning…

Materials Science · Physics 2014-09-09 Vitaly V. Chaban , Oleg V. Prezhdo

In the Bose-Einstein condensation of interacting atoms or molecules such as 87Rb, 23Na and 7Li, the theoretical understanding of the transition temperature is not always obvious due to the interactions or zero point energy which cannot be…

We developed a new physical model to predict macroscopic properties of inorganic molten systems using a realistic description of inter-atomic interactions. Unlike the conventional approach, which tends to overestimate viscosity by several…

Materials Science · Physics 2015-06-04 Vitaly V. Chaban , Yuriy V. Pereverzev , Oleg V. Prezhdo

With recent developments in simulating nonadiabatic systems to high accuracy, it has become possible to determine how much energy is attributed to nuclear quantum effects beyond zero-point energy. In this work we calculate the…

Chemical Physics · Physics 2016-08-23 Yubo Yang , Ilkka Kylanpaa , Norm Tubman , Jaron Krogel , Sharon Hammes-Schiffer , David Ceperley

Quantum non-Markovianity represents memory during the system dynamics, which is typically weakened by the temperature. We here study the effects of environmental temperature on the non-Markovianity of an open quantum system by virtue of…

Quantum Physics · Physics 2018-06-13 Zhong-Xiao Man , Yun-Jie Xia , Rosario Lo Franco

Non-equilibrium effects are studied using a full Lorentz-invariant formalism. Our analysis shows that in reactions considered here, no global or local equilibrium is reached. The heavier masses are found to be equilibrated more than the…

Nuclear Theory · Physics 2016-09-08 Rajeev K. Puri , E. Lehmann , Amand Faessler , S. W. Huang

We study an excited atom-polar molecular ion chemical reaction (Ca$^*$ + BaCl$^+$) at low temperature by utilizing a hybrid atom-ion trapping system. The reaction rate and product branching fractions are measured and compared to model…

In the BCS limit density profiles for unpolarized trapped fermionic clouds of atoms are largely featureless. Therefore, it is a delicate task to analyze them in order to quantify their respective interaction and temperature contributions.…

Quantum Gases · Physics 2023-11-16 Sejung Yong , Sian Barbosa , Jennifer Koch , Felix Lang , Axel Pelster , Artur Widera

Atom-molecule equilibrium for molecular formation processes is discussed for boson-fermion, fermion-fermion, and boson-boson mixtures of ultracold atomic gases in the framework of quasichemical equilibrium theory. After presentation of the…

Soft Condensed Matter · Physics 2008-08-06 T. Nishimura , A. Matsumoto , H. Yabu

Ion conduction in noncrystals (glasses, polymers, etc) has a number of properties in common. In fact, from a purely phenomenological point of view, these properties are even more widely observed: ion conduction behaves much like electronic…

Disordered Systems and Neural Networks · Physics 2007-05-23 Jeppe C. Dyre , Thomas B. Schroeder

The usual formulation of thermodynamics is based on the additivity of macroscopic systems. However, there are numerous examples of macroscopic systems that are not additive, due to the long-range character of the interaction among the…

Statistical Mechanics · Physics 2022-06-22 Ivan Latella , Agustín Pérez-Madrid , Alessandro Campa , Lapo Casetti , Stefano Ruffo

Sympathetic cooling is the process of energy exchange between a system and a colder bath. We investigate this fundamental process in an atom-ion experiment where the system is composed of a single ion, trapped in a radio-frequency Paul…

Atomic Physics · Physics 2018-08-08 Ziv Meir , Meirav Pinkas , Tomas Sikorsky , Ruti Ben-shlomi , Nitzan Akerman , Roee Ozeri

Studying chemical reactions at very low temperatures is of importance for the understanding of fundamental physical and chemical processes. At very low energies, collisions are dominated by only a few partial waves. Thus, studies in this…

Chemical Physics · Physics 2017-03-30 Dongdong Zhang , Stefan Willitsch

The dynamics of open quantum systems connected with several reservoirs attract great attention due to its importance in quantum optics, biology, quantum thermodynamics, transport phenomena, etc. In many problems, the Born approximation is…

Quantum Physics · Physics 2023-12-20 I. V. Vovchenko , A. A. Zyablovsky , A. A. Pukhov , E. S. Andrianov

Thermodynamics properties of an interacting system of bosons are considered at finite temperatures and zero chemical potential within the Skyrme-like mean-field model. An interplay between attractive and repulsive interactions is…

High Energy Physics - Phenomenology · Physics 2021-05-26 O. S. Stashko , D. V. Anchishkin , O. V. Savchuk , M. I. Gorenstein

Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level…

Statistical Mechanics · Physics 2015-06-15 George L. Barnes , Michael E. Kellman

The onset of collision dynamics between an ion and a Rydberg atom is studied in a regime characterized by a multitude of collision channels. These channels arise from coupling between a non-polar Rydberg state and numerous highly polar…

The process of deriving an interatomic potentials represents an attempt to integrate out the electronic degrees of freedom from the full quantum description of a condensed matter system. In practice it is the derivatives of the interatomic…

Materials Science · Physics 2016-06-23 G. J. Ackland

Molecular dynamics simulations are used to model ion and neutral temperature evolution in partially-ionized atmospheric pressure plasma at different ionization fractions. Results show that ion-ion interactions are strongly coupled at…

Plasma Physics · Physics 2023-01-04 M. D. Acciarri , C. Moore , S. D. Baalrud

Alkaline electrolyte solutions are important components in rechargeable batteries and alkaline fuel cells. As the ionic conductivity is thought to be a limiting factor in the performance of these devices, which are often operated at…

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