Related papers: Long-range interactions between polar bialkali gro…
Ultracold diatomic molecules find application in quantum studies ranging from controlled chemistry and precision measurement physics to quantum many-body simulation and potentially quantum computing. Accurate knowledge of molecular…
We report calculations of Born-Oppenheimer potential energy curves of the chromium-rubidium heteronuclear molecule 52Cr-87Rb, and the long-range dispersion coefficient for the interaction between ground state Cr and Rb atoms. Our calculated…
We investigate theoretically the long-range electrostatic interactions between a ground-state homonuclear alkali-metal dimer and an excited alkali-metal atom taking into account its fine-structure. The interaction involves the combination…
The random-phase approximation with exchange (RPAE) is used with a $B$-spline basis to compute dynamic dipole polarizabilities of noble-gas atoms and several other closed-shell atoms (Be, Mg, Ca, Zn, Sr, Cd, and Ba). From these, values of…
The efficiency of optical trapping of ultracold atoms depend on the atomic dynamic dipole polarizability governing the atom-field interaction. In this article, we have calculated the real and imaginary parts of the dynamic dipole…
Following the first principles the analytic Born-Oppenheimer (BO) potential curve for the ground state $X^1\Sigma^+$ of the molecule ClF is proposed for whole range of internuclear distances $R \in [0,\infty)$. It is based on matching the…
We report a high-resolution spectroscopic investigation of the long-range states of the $^{23}$Na$^{87}$Rb molecule near its Na($3^2S_{1/2}$)+Rb($5^2P_{3/2}$) asymptote. This study was performed with weakly bound ultracold molecules…
The long-range interaction of excited neutral atoms has a number of interesting and surprising properties, such as the prevalence of long-range, oscillatory tails, and the emergence of numerically large can der Waals C_6 coefficients.…
We consider long-range interactions between two alkali-metal atoms in their respective ground states. We extend the previous relativistic many-body calculations of C_6 dispersion coefficients [Phys.Rev. Lett. {\bf 82}, 3589 (1999)] to…
By inferring the dynamic permittivity of different material media from the observations and calculating dynamic electric dipole polarizabilties of the Li through Cs alkali atoms, precise values of $C_3$ coefficients were estimated in Phys.…
We study the van der Waals interaction between Rydberg alkali-metal atoms with fine structure ($n^2L_j$; $L\leq 2$) and heteronuclear alkali-metal dimers in the ground rovibrational state ($X^1\Sigma^+$; $v=0$, $J=0$). We compute the…
We consider the zero-temperature van der Waals interaction between two molecules, each of which has a zero or near-zero electronic gap between a groundstate and the first excited state, using a toy model molecule ( equilateral H3) as an…
The interaction of two excited hydrogen atoms in metastable states constitutes a theoretically interesting problem because of the quasi-degenerate 2P_{1/2} levels which are removed from the 2S states only by the Lamb shift. The total…
Mutual Coulomb interactions between electrons lead to a plethora of interesting physical and chemical effects, especially if those interactions involve many fluctuating electrons over large spatial scales. Here, we identify and study in…
The isotropic and anisotropic coefficients $C^{l,m}_n$ of the long-range spherical expansion $\sim 1/R^n$ ($R$ -- the intermolecular distance) of the dispersion and inductions intermolecular energies are calculated using the first…
General formulas for calculating the several leading long-range interactions among three identical atoms where two atoms are in identical $S$ states and the other atom is in a $P$ state are obtained using perturbation theory for the…
We consider the long-range states expected for complexes formed from an alkali-metal diatomic molecule in a singlet state and an alkali-metal atom. We explore the structure of the Hamiltonian for such systems, and the couplings between the…
The mounting interest in conducting thorough analyses and studies of long-range interactions stems from their wide-ranging applications in cold atomic physics, making it a compelling area for research. In this work, we have evaluated long…
Relativistic many-body calculations of van der Waals coefficients C_6 for dimers correlating to two ground state alkaline-earth atoms at large internuclear separations are reported. The following values and uncertainties were determined :…
Ultracold collisions between Cs atoms and Cs2 dimers in the electronic ground state are observed in an optically trapped gas of atoms and molecules. The Cs2 molecules are formed in the triplet ground state by cw-photoassociation through the…