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An effective field theory exists describing a very large class of biophysically interesting Coulomb gas systems: the lowest order (mean-field) version of this theory takes the form of a generalized Poisson-Boltzmann theory. Interaction…

High Energy Physics - Lattice · Physics 2008-11-26 Anthony Duncan

Plasma-boundaries floating in an ionized gas are usually negatively charged. They accumulate electrons more efficiently than ions which leads to the formation of a quasi-stationary electron film at the boundaries. We propose, in a…

Plasma Physics · Physics 2009-08-24 Franz X. Bronold , H. Deutsch , H. Fehske

The work reviews on a general level various modified Poisson-Boltzmann equations and demonstrates their use on the specific system of charged particles at an interface. This system is special, first, because it exhibits the long-range…

Soft Condensed Matter · Physics 2012-11-14 Derek Frydel , Martin Oettel

We propose an analytical approximation for the dependence of the effective charge on the bare charge for spherical and cylindrical macro-ions as a function of the size of the colloid and salt content, for the situation of a unique colloid…

Soft Condensed Matter · Physics 2016-08-31 M. Aubouy , E. Trizac , L. Bocquet

We studied polyelectrolyte adsorption on a repulsive charged surface by scaling analysis. At low ionic strength and low surface charge density in which a single polyelectrolyte is able to be adsorbed onto the surface, different regimes in…

Soft Condensed Matter · Physics 2016-08-31 Chi-Ho Cheng , Pik-Yin Lai

We present a model for the ion distribution near a charged surface, based on the response of the ions to the presence of a single test particle. Near an infinite planar surface this model produces the exact density profile in the limits of…

Soft Condensed Matter · Physics 2009-11-10 Y. Burak , D. Andelman , H. Orland

A two-level system interacting with a cavity field is an important model for investigating the photon blockade (PB) effect. Most work on this topic has been based on the assumption that the atomic transition frequency is resonant with the…

Quantum Physics · Physics 2019-12-25 Xinyun Liang , Zhenglu Duan , Qin Guo , Cunjin Liu , Shengguo Guan , Yi Ren

Macromolecules, when immersed in a polar solvent like water, become charged by a fixed surface charge density which is compensated by ``counter-ions'' moving out of the surface. Such classical particle systems exhibit poor screening…

Statistical Mechanics · Physics 2015-11-04 Ladislav Šamaj

In mixtures of colloids and nonadsorbing polyelectrolytes, a Donnan potential arises across the region between surfaces that are depleted of polyelectrolyte and the rest of the system. This Donnan potential tends to shift the…

Soft Condensed Matter · Physics 2022-10-27 Jasper Landman , Max P. M. Schelling , Remco Tuinier , Mark Vis

We investigate the interaction between highly charged lipid bilayers in the presence of monovalent counterions. Neutron and X-ray reflectivity experiments show that the water layer between like-charged bilayers is thinner than for…

Within a dipolar Poisson-Boltzmann theory including electrostatic correlations, we consider the effect of explicit solvent structure on solvent and ion partition confined to charged nanopores. We develop a relaxation scheme for the solution…

Soft Condensed Matter · Physics 2015-10-28 Sahin Buyukdagli

Classical theory of the electric double layer is based on the fundamental assumption of a dilute solution of point ions. There are a number of situations such as high applied voltages, high concentration of electrolytes, systems with…

Fluid Dynamics · Physics 2015-06-11 Brian D. Storey , Martin Z. Bazant

The interaction force between likely charged particles/surfaces is usually repulsive due to the Coulomb interaction. However, the counterintuitive like-charge attraction in electrolytes has been frequently observed in experiments, which has…

Soft Condensed Matter · Physics 2016-11-08 Pei Liu , Manman Ma , Zhenli Xu

The interaction between two chemically identical charge-regulated surfaces is studied using the classical density functional theory. In contrast to common expectations and assumptions, under certain realistic conditions we find a…

Soft Condensed Matter · Physics 2018-02-26 Arghya Majee , Markus Bier , Rudolf Podgornik

Near solid-liquid or liquid-liquid interfaces with dielectric contrast, charged particles interact with the induced polarization charge of the interface. These interactions contribute to an effective self-energy of the bulk ions and mediate…

Soft Condensed Matter · Physics 2021-12-16 Francisco J. Solis , Monica Olvera de la Cruz

We investigate the effects of the Born-Infeld action on the Abelian sector of the electroweak model. The consequence of this approach is the emergence of anomalous couplings in the neutral sector of the $Z$-gauge boson and photon. These new…

High Energy Physics - Theory · Physics 2022-04-19 M. J. Neves , L. P. R. Ospedal , J. A. Helayël-Neto , Patricio Gaete

A simple model of soap films with nonionic surfactants stabilized by added electrolyte is studied. The model exhibits charge regularization due to the incorporation of a physical mechanism responsible for the formation of a surface charge.…

Soft Condensed Matter · Physics 2009-11-07 D. S. Dean , R. R. Horgan

We perform a linearization of the Poisson-Boltzmann (PB) density functional for spherical Wigner-Seitz cells that yields Debye-H\"uckel-like equations agreeing asymptotically with the PB results in the weak-coupling (high-temperature)…

Soft Condensed Matter · Physics 2009-11-07 M. N. Tamashiro , H. Schiessel

The adsorption of large ions from solution to a charged surface is investigated theoretically. A generalized Poisson--Boltzmann equation, which takes into account the finite size of the ions is presented. We obtain analytical expressions…

Soft Condensed Matter · Physics 2009-10-31 I. Borukhov , D. Andelman , H. Orland

The general solution to the nonlinear Poisson-Boltzmann equation for two parallel charged plates, either inside a symmetric elecrolyte, or inside a 2q:-q asymmetric electrolyte, is found in terms of Weierstrass elliptic functions. From this…

Classical Physics · Physics 2010-10-26 Xiangjun Xing
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