Related papers: A rigorous derivation of multicomponent diffusion …
We study a model of assisted diffusion of hard-core particles on a line. The model shows strongly ergodicity breaking : configuration space breaks up into an exponentially large number of disconnected sectors. We determine this…
We consider a class of multidimensional conservation laws with vanishing nonlinear diffusion and dispersion terms. Under a condition on the relative size of the diffusion and dispersion coefficients, we establish that the…
We derive a large-scale hydrodynamic equation, including diffusive and dissipative effects, for systems with generic static position-dependent driving forces coupling to local conserved quantities. We show that this equation predicts…
We present a classical approach of a mixture of compressible fluids when each constituent has its own temperature. The introduction of an average temperature together with the entropy principle dictates the classical Fick law for diffusion…
The Onsager linear relations between macroscopic flows and thermodynamics forces are derived from the point of view of large deviation theory. For a given set of macroscopic variables, we consider the short-time evolution of…
Second-order dissipative hydrodynamic equations for each component of a multi-component system are derived using the entropy principle. Comparison of the solutions with kinetic transport results demonstrates validity of the obtained…
We study a class of variational problems for regularized conservation laws with Lax's entropy-entropy flux pairs. We first introduce a modified optimal transport space based on conservation laws with diffusion. Using this space, we…
The Onsager reciprocal relations are established within the phenomenological framework of the thermodynamics of irreversible processes. In order to do so, the dissipated power densities associated to scalar and vectorial processes are…
In this article we focus our attention on the principle of energy conservation within the context of systems of fluid dynamics. We give an overview of results concerning the resolution of the famous Onsager conjecture - which states…
We present a linear response theory that establishes the continuum-mechanical origin of Onsager reciprocity in colloidal motion. By decoupling hydrostatic and hydrodynamic stress, we show that Onsager reciprocal relations emerge from the…
We investigate the link between information and thermodynamics embodied by Landauer's principle in the open dynamics of a multipartite quantum system. Such irreversible dynamics is described in terms of a collisional model with a finite…
The convective transport in a multicomponent isothermal compressible fluid subject to the mass continuity equations is considered. The velocity is proportional to the negative pressure gradient, according to Darcy's law, and the pressure is…
The observed general time-asymmetric behavior of macroscopic systems -- embodied in the second law of thermodynamics -- arises naturally from time-symmetric microscopic laws due to the great disparity between macro and micro-scales. More…
We extend Onsager's minimum dissipation principle to stationary states that are only subject to local equilibrium constraints, even when the transport coefficients depend on the thermodynamic forces. Crucial to this generalization is a…
In this paper, we rigorously derive a Boltzmann equation for mixtures from the many body dynamics of two types of hard sphere gases. We prove that the microscopic dynamics of two gases with different masses and diameters is well defined,…
We present the Onsager--Stefan--Maxwell thermodiffusion equations, which account for the Soret and Dufour effects in multicomponent fluids. Unlike transport laws derived from kinetic theory, this framework preserves the structure of the…
Onsager's variational principle is generalized to address the diffusive dynamics of an electrolyte solution composed of charge-regulated macro-ions and counterions. The free energy entering the Rayleighian corresponds to the…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
The global-in-time existence of bounded weak solutions to the Maxwell-Stefan-Fourier equations in Fick-Onsager form is proved. The model consists of the mass balance equations for the partial mass densities and and the energy balance…
The equations of reversible (inviscid, adiabatic) fluid dynamics have a well-known variational formulation based on Hamilton's principle and the Lagrangian, to which is associated a Hamiltonian formulation that involves a Poisson bracket…