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X-ray powder diffraction and electrical resistivity measurements were performed on the tetragonal compound CeCoSi under pressure to elucidate the phase boundary of the pressure-induced structural transition and the change in the 4$f$…

In order to tune the magnetic properties of the cleavable high-Curie temperature ferromagnet Fe$_{5-x}$GeTe$_2$, the effect of increasing the electron count through arsenic substitution has been investigated. Small additions of arsenic (2.5…

Materials Science · Physics 2021-11-15 Andrew F. May , Jiaqiang Yan , Raphael Hermann , Mao-Hua Du , Michael A. McGuire

We report on the synthesis of superconducting single crystals of FeSe, and their characterization by X-ray diffraction, magnetization and resistivity. We have performed ac susceptibility measurements under high pressure in a hydrostatic…

Superconductivity · Physics 2015-05-13 D Braithwaite , B Salce , G Lapertot , F Bourdarot , C Marin , D Aoki , M Hanfland

As a new type of topological materials, ZrTe5 shows many exotic properties under extreme conditions. Utilizing resistance and ac magnetic susceptibility measurements under high pressure, while the resistance anomaly near 128 K is completely…

We have investigated temperature dependence of the lattice parameters and the unit cell volume of ZnF$_2$ by neutron diffraction and have discovered negative thermal expansion (NTE) at low temperature. To understand why this simple compound…

Materials Science · Physics 2012-07-03 Tapan Chatterji , Mohamed Zbiri , Thomas C. Hansen

The temperature-induced structural and electronic transformation in VO$_2$ between the monoclinic M1 and tetragonal rutile phases was studied by means of \textit{ab initio} molecular dynamics, based on density functional theory with Hubbard…

Materials Science · Physics 2017-10-11 Dušan Plašienka , Roman Martoňák , Marcus C. Newton

The dynamical, dielectric and elastic properties of GeTe, a ferroelectric material in its low temperature rhombohedral phase, have been investigated using first-principles density functional theory. We report the electronic energy bands,…

Materials Science · Physics 2009-01-06 R. Shaltaf , E. Durgun , J. -Y. Raty , Ph. Ghosez , X. Gonze

The crystal structure of the thermoelectric material tin selenide has been investigated with angle-dispersive synchrotron x-ray powder diffraction under hydrostatic pressure up to 27 GPa. With increasing pressure, a continuous evolution of…

Materials Science · Physics 2015-04-03 I Loa , R J Husband , R A Downie , S R Popuri , J-W G Bos

The paper presents an analysis of mechanical, structural, thermophysical and spectral properties of solid methane in temperature interval $0.5T_{tr} -T_{tr}$ ($T_{tr}$ is the triple point temperature) under equilibrium vapor pressure. It is…

Materials Science · Physics 2014-04-30 A. V. Leont'eva , A. Yu. Prokhorov , A. Yu. Zakharov , A. I. Erenburg

Ambient pressure studies on high purity single crystals of the stoichiometric 4f-electron metal CeNi2Ge2 reveal anomalous low temperature forms of the resistivity which challenge our understanding of the metallic state. Comparisons are made…

Soft phonon behavior associated with a structural phase transition from the low-temperature-orthorhombic (LTO) phase ($Bmab$ symmetry) to the low-temperature-tetragonal (LTT) phase ($P4_{2}/ncm$ symmetry) was investigated in…

Superconductivity · Physics 2009-11-10 H. Kimura , Y. Noda , H. Goka , M. Fujita , K. Yamada , G. Shirane

We report the temperature dependent x-ray powder diffraction of the FeAs-based superconductors in the range between 300 K and 95 K. In the case of NdOFeAs we have detected the structural phase transition from the tetragonal phase, with…

Superconductivity · Physics 2009-01-12 Alessandro Ricci , Michela Fratini , Antonio Bianconi

We use a combination of Raman spectroscopy and transport measurements to study thin flakes of the type-II Weyl semimetal candidate MoTe2 protected from oxidation. In contrast to bulk crystals, which undergo a phase transition from…

We report a Raman scattering investigation of multiferroic bismuth ferrite BiFeO3 epitaxial (c-axis oriented) thin films from -192 to 1000C. Phonon anomalies have been observed in three temperature regions: in the gamma-phase from 930C to…

Materials Science · Physics 2015-05-14 R. Palai , J. F. Scott , R. S. Katiyar

We report neutron inelastic scattering on single crystal 0.68Pb(Mg1/3Nb2/3O3)-0.32PbTiO3 (PMN-0.32PT), a relaxor ferroelectric material that lies within the compositional range of the morphotropic phase boundary (MPB). Data were obtained…

Materials Science · Physics 2009-11-13 Hu Cao , Chris Stock , Guangyong Xu , Peter M. Gehring , Jiefang Li , Dwight Viehland

Layered transition-metal trichalcogenides have become one of the research frontiers as two-dimensional magnets and candidate materials used for phase-change memory devices. Herein we report the high-pressure synchrotron X-ray diffraction…

Strongly Correlated Electrons · Physics 2019-06-03 Zhenhai Yu , Wei Xia , Kailang Xu , Ming Xu , Hongyuan Wang , Xia Wang , Na Yu , Zhiqiang Zou , Jinggeng Zhao , Lin Wang , Xiangshui Miao , Yanfeng Guo

Y$_{0.9}$Gd$_{0.1}$Fe$_{2}$, which crystallizes in a C15 cubic structure, can absorb up to 5 H/f.u. and its pressure-composition isotherm displays a multiplateau behavior related to the existence of several hydrides with different crystal…

Materials Science · Physics 2022-10-06 V. Paul-Boncour , K. Provost , E. Alleno , A. N Diaye , F. Couturas , E. Elkaim

Here we report the discovery of superconductivity in multiple phases of the compressed GeSb2Te4 (GST) phase change memory alloy, which has attracted considerable attention for the last decade due to its unusual physical properties with many…

The Fe-Cu system has attracted much attention over the last several decades due to its technological importance as a model alloy for Cu steels. In spite of these efforts several aspects of its phase diagram remain unexplained. Here we use…

Materials Science · Physics 2013-11-20 Paul Erhart , Jaime Marian , Babak Sadigh

The specific heat, magnetization and thermal expansion of single crystals of antiferromagnetic insulator EuTe, measured at temperatures down to 2 K and in magnetic fields up to 90 kOe, demonstrate non trivial properties. The Neel…

Strongly Correlated Electrons · Physics 2015-04-29 S. M. Stishov , A. E. Petrova , S. Yu. Gavrilkin , L. A. Klinkova