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Structural changes in REMnO3 (RE= Y, Ho, Lu) under high pressure were examined by synchrotron x-ray diffraction methods at room temperature. Compression occurs more readily in the ab plane than along the c-axis. Under hydrostatic pressure…

Materials Science · Physics 2015-05-20 P. Gao , Z. Chen , T. A. Tyson , T. Wu , K. H. Ahn , Z. Liu , R. Tappero , S. B. Kim , S. -W. Cheong

We present a combined experimental and theoretical study on the quasi-one-dimensional organic conductor (TMTTF)$_2$PF$_6$, and elucidate the variation of its physical properties under pressure. We fully resolve the crystal structure by…

We present results of the magnetic susceptibility on high-quality single crystals of EuPd$_2$(Si$_{1-x}$Ge$_x$)$_2$ for Ge concentrations 0 $\leq x \leq$ 0.105 performed under varying hydrostatic (He-gas) pressure 0 $\leq p \leq$ 0.5 GPa.…

Strongly Correlated Electrons · Physics 2023-07-12 Bernd Wolf , Theresa Lundbeck , Jan Zimmermann , Marius Peters , Kristin Kliemt , Cornelius Krellner , Michael Lang

The pressure behavior of the absorption edge of PbWO4 was studied up to 15.3 GPa. It red-shifts at -71 meV/GPa below 6.1 GPa, but at 6.3 GPa the band-gap collapses from 3.5 eV to 2.75 eV. From 6.3 GPa to 11.1 GPa, the absorption edge moves…

Materials Science · Physics 2007-05-23 D. Errandonea , D. Martinez-Garcia , R. Lacomba-Perales , J. Ruiz-Fuertes , A. Segura

The structural parameters of $\epsilon$-FeGe have been determined at ambient conditions using single crystal refinement. Powder diffraction have been carried out to determine structural properties and compressibility for pressures up to 30…

Strongly Correlated Electrons · Physics 2009-11-13 H. Wilhelm , M. Schmidt , R. Cardoso-Gil , U. Burkhardt , M. Hanfland , U. Schwarz , L. Akselrud

The temperature-dependent phase transitions in Ruddlesden-Popper oxides with perovskite bilayers have been under increased scrutiny in recent years due to the so-called hybrid improper ferroelectricity that some chemical compositions…

Materials Science · Physics 2021-12-08 Gabriel Clarke , Dominik Daisenberger , X. Luo , S. W. Cheong , Nicholas C. Bristowe , Mark S. Senn

We present a study of the effect of very high pressure on the orthorhombic perovskite GdMnO3 by Raman spectroscopy and synchrotron x-ray diffraction up to 53.2 GPa. The experimental results yield a structural and insulator-to-metal phase…

Strongly Correlated Electrons · Physics 2011-11-22 J. Agostinho Moreira , A. Almeida , J. Oliveira , V. H. Rodrigues , M. M. R. Costa , P. B. Tavares , P. Bouvier , M. Guennou , J. Kreisel

We investigate the pressure-induced evolution of crystal structure and magnetism in the kagome ferromagnet Fe$_3$Sn$_2$ by combining X-ray diffraction, X-ray Emission Spectroscopy, X-ray Magnetic Circular Dichroism, and spin-polarized…

Strongly Correlated Electrons · Physics 2026-03-27 S. Chattopadhyay , L. Thomarat , C. S. Ong , K. Kargeti , Lipika , J. -P. Rueff , L. Nataf , K. Manna , S. K. Panda , C. Shekhar , V. Balédent

The orthorhombic phase of Si-doped Fe carbide is synthesized at high pressures and temperatures using laser-heated diamond anvil cell (LHDAC), followed by its characterization using X-ray diffraction (XRD) measurements, Transmission…

Materials Science · Physics 2020-11-17 Pinku Saha , Konstantin Glazyrin , Goutam Dev Mukherjee

The crystal structures of the quasi-one-dimensional organic salts (TMTTF)$_2$PF$_6$ and (TMTSF)$_2$PF$_6$ were studied by pressure-dependent x-ray diffraction up to 10 GPa at room temperature. The unit-cell parameters exhibit a clear…

Strongly Correlated Electrons · Physics 2009-10-05 A. Pashkin , M. Dressel , S. G. Ebbinghaus , M. Hanfland , C. A. Kuntscher

We report the effects of hydrostatic pressure on the temperature-induced phase transitions in Fe1.08Te in the pressure range 0-3 GPa using synchrotron powder x-ray diffraction (XRD). The results reveal a plethora of phase transitions. At…

Superconductivity · Physics 2012-09-07 C. Koz , S. Rößler , A. A. Tsirlin , D. Kasinathan , C. Börrnert , M. Hanfland , H. Rosner , S. Wirth , U. Schwarz

We report direct experimental evidence of antiferroelectric to paraelectric phase transition under pressure in NaNbO3 using neutron diffraction at room temperature. The paraelectric phase is found to stabilize above 8 GPa and its crystal…

Materials Science · Physics 2015-06-11 S. K. Mishra , M. K. Gupta , R. Mittal , S. L. Chaplot , Thomas Hansen

Neutron powder diffraction studies of the crystal and magnetic structures of the magnetocaloric compound Mn1.1Fe0.9(P0.8Ge0.2) have been carried out as a function of temperature, applied magnetic field, and pressure. The data reveal that…

Materials Science · Physics 2009-11-30 D. M. Liu , Q. Huang , M. Yue , J. W. Lynn , L. J. Liu , Y. Chen , Z. H. Wu , J. X. Zhang

We report the structural and magnetic properties of four-layer Aurivillius compound Bi$_5$FeTi$_3$O$_{15}$ (BFTO) at high hydrostatic pressure conditions. The high-pressure XRD data does not explicitly show structural phase transitions with…

A comprehensive study of the structural properties of the heavily investigated rare-earth A2Ir2O7 series under extreme conditions is presented. The series is covered by studying iridates with A = Pr, Sm, Dy-Lu. Temperature- and…

The structural behaviour of CsCdF3 under pressure is investigated by means of theory and experiment. High-pressure powder x-ray diffraction experiments were performed up to a maximum pressure of 60 GPa using synchrotron radiation. The cubic…

Manganese, in the a-Mn structure, has been studied using synchrotron powder x-ray diffraction in a diamond anvil cell up to 220 GPa at room temperature combined with density functional calculations (DFT). The experiment reveals an extended…

Barium zirconate BaZrO3 is one of few perovskites that is claimed to retain an average cubic structure down to 0K at ambient pressure, while being energetically very close to a tetragonal phase obtained by condensation of a soft phonon mode…

Materials Science · Physics 2024-03-22 Erik Fransson , Petter Rosander , Paul Erhart , Göran Wahnström

Compositionally tunable vanadium oxyhydrides Sr2VO4-xHx (x = 0 - 1) without considerable anion vacancy were synthesized by high-pressure solid state reaction. The crystal structures and their properties were characterized by powder neutron…

Actinide-bearing intermetallics display unusual electronic, magnetic, and physical properties which arise from the complex behavior of their 5$f$ electron orbitals. Temperature ($T$) effects on actinide intermetallics are well studied, but…