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Related papers: High-pressure powder x-ray diffraction study of Eu…

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Pressure-induced phase transitions in orthovanadates have led to interesting physical phenomena. The observed transitions usually involve large volume collapses and drastic changes in the electronic and vibrational properties of the…

Materials Science · Physics 2020-07-30 Daniel Errandonea

The orthovanadates are useful as host matrices for immobilization of radioactive wastes. The thermodynamic stability of these materials is crucial for their applications in high pressure and temperatures environment. It is necessary to…

Materials Science · Physics 2019-05-01 R. Mittal , M. K. Gupta , Baltej Singh , L. Pintschovius , Yu D. Zavartsev , S. L. Chaplot

We report on the crystal structure and electronic properties of the heavy fermion superconductor UTe2 at high pressure up to 11 GPa, as investigated by X-ray diffraction and electrical resistivity experiments. The X-ray diffraction…

Germanates are often used as structural analogs of planetary silicates. We have explored the high-pressure phase relations in Mg$_2$GeO$_4$ using diamond anvil cell experiments combined with synchrotron x-ray diffraction and computations…

Geophysics · Physics 2024-03-06 R. V. Divya , G. Kumar , R. E. Cohen , S. J. Tracy , Y. Meng , S. Chariton , V. B. Prakapenka , R. Dutta

We report high pressure powder synchrotron x-ray diffraction studies on MFe2As2 (M=Ba, Ca) over a range of temperatures and pressures up to about 56 GPa using a membrane diamond anvil cell. A phase transition to a collapsed tetragonal phase…

We have performed experimental and theoretical studies of the structural stability of YAsO4 and YCrO4 at high pressures. X-ray diffraction experiments together with ab initio total-energy and lattice-dynamics calculations have allowed us to…

Materials Science · Physics 2012-01-26 D. Errandonea , R. Kumar , J. Lopez-Solano , P. Rodriguez-Hernandez , A. Munoz , M. G. Rabie , R. Saez Puche

In this paper we perform a high-pressure study of fergusonite-type HoNbO4. Powder x-ray diffraction experiments and ab initio density-functional theory simulations provide evidence of a phase transition at 18.9(1.1) GPa from the monoclinic…

Materials Science · Physics 2025-08-08 A. B. Garg , D. Errandonea , P. Rodriguez-Hernandez , A. Munoz

We report a high-pressure study of monoclinic monazite-type SrCrO4 up to 26 GPa. Therein we combined x-ray diffraction, Raman and optical-absorption measurements with ab initio calculations, to find a pressure-induced structural phase…

We present a combined theoretical and experimental study of the high-pressure behavior of thallium. X-ray diffraction experiments have been carried out at room temperature up to 125 GPa using diamond-anvil cells, nearly doubling the…

Materials Science · Physics 2016-10-04 C. Cazorla , S. G. MacLeod , D. Errandonea , K. A. Munro , M. I. McMahon , C. Popescu

High pressure x-ray diffraction up to 30 GPa and resonant emission x-ray spectroscopy and partial fluorescence yield x-ray absorption spectroscopy up to 52 GPa were used to study how the structural and electronic properties of UTe$_2$…

Certain alumino-silicates display exotic properties enabled by their framework structure made of corner-sharing tetrahedral rigid units. Using \textit{in situ} diamond-anvil cell x-ray diffraction (XRD), we study the pressure-induced…

Synchrotron x-ray diffraction experiments have been carried out on Eu metal at ambient temperature to pressures as high as 92 GPa (0.92 Mbar). Following the well-known bcc-to-hcp transition at 12 GPa, a mixed phase region is observed from…

Materials Science · Physics 2015-05-20 W. Bi , Y. Meng , R. S. Kumar , A. L. Cornelius , W. W. Tipton , R. G. Hennig , Y. Zhang , C. Chen , J. S. Schilling

First-principles calculations have been carried out to study the InVO4 compound under pressure. In this work, total energy calculations were performed in order to analyze the structural behavior of the experimentally known polymorphs of…

X-ray diffraction, dynamical mechanical analysis and infrared reflectivity studies revealed an antiferrodistortive phase transition in EuTiO3 ceramics. Near 300K the perovskite structure changes from cubic Pm-3m to tetragonal I4/mcm due to…

In situ high-pressure energy dispersive x-ray diffraction experiments on polycrystalline powder TiN with NaCl-type structure have been conducted with the pressure up to 30.1 GPa by using the diamond anvil cell instrument with synchrotron…

Materials Science · Physics 2009-11-11 J. G. Zhao , L. X. Yang , Y. Yu , S. J. You , R. C. Yu , L. C. Chen , F. Y. Li , C. Q. Jin , X. D. Li , Y. C. Li , J. Liu

Combined X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) experiments have been carried out on GaAsO4 (berlinite structure) at high pressure and room temperature. XAS measurements indicate four-fold to six-fold coordination…

Materials Science · Physics 2009-10-30 James Badro , Philippe Gillet , Paul F. McMillan , Alain Polian , Jean-Paul Itié

The behavior of LuLiF4 sheelite (I41/a, Z = 4) under hydrostatic pressure was investigated by means of the first principles calculations. The ferroelastic phase transition from the tetragonal structure of LuLiF4 to fergusonite structure…

Materials Science · Physics 2014-06-02 Anastasia Petrova , Oleg Nedopekin , Dmitrii Tayurskii , Benoit Minisini

\emph{Ab-initio} calculations were performed on the scheelite type MGeO$_4$ (M = Hf, and Zr) compounds which find wide range of applications such as in x-ray imaging. We have studied the high pressure structural stability, elastic…

Materials Science · Physics 2014-05-30 G. Shwetha , V. Kanchana , K. Ramesh Babu , G. Vaitheeswaran , M. C. Valsakumar

In order to probe the changes in the valence state and magnetic properties of Eu metal under extreme pressure, x-ray absorption near-edge spectroscopy, x-ray magnetic circular dichroism and synchrotron M\"ossbauer spectroscopy experiments…

We have recently predicted and subsequently verified experimentally by specific heat measurements that EuTiO3 undergoes a structural phase transition at elevated temperature TS = 282 K. The origin of the phase transition has been attributed…

Materials Science · Physics 2012-05-25 J. Köhler , R. Dinnebier , A. Bussmann-Holder