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We derive and analyze a hierarchy of approximations to the strongly correlated limit of the Hohenberg-Kohn functional. These "density representability approximations" are obtained by first noting that in the strongly correlated limit,…

Chemical Physics · Physics 2013-10-25 Gero Friesecke , Christian B. Mendl , Brendan Pass , Codina Cotar , Claudia Klüppelberg

Modern density functional theory (DFT) calculations employ the Kohn-Sham (KS) system of non-interacting electrons as a reference, with all complications buried in the exchange-correlation energy (Exc). The adiabatic connection formula gives…

Other Condensed Matter · Physics 2009-10-02 Zhenfei Liu , Kieron Burke

As a universal quantum mechanical approach to the dynamical many-body problem, the time-dependent density functional theory (TDDFT) might be inadequate to describe crucial observables that rely on two-body evolution behavior, like the…

Computational Physics · Physics 2025-11-17 Jiong-Hang Liang , Yunfeng Xiong

The exact reduced density-matrix functional is derived from the Luttinger-Ward functional of the single-particle Green's function. Thereby, a formal link is provided between diagrammatic many-body approaches using Green's functions on the…

Strongly Correlated Electrons · Physics 2013-12-11 Peter E. Blöchl , Thomas Pruschke , Michael Potthoff

We study ground-state properties of a two-site, two-electron Holstein model describing two molecules coupled indirectly via electron-phonon interaction by using both exact diagonalization and self-consistent diagrammatic many-body…

Strongly Correlated Electrons · Physics 2016-01-20 N. Säkkinen , Y. Peng , H. Appel , R. van Leeuwen

The symmetric heavy-light ansatz is a method for finding the ground state of any dilute unpolarized system of attractive two-component fermions. Operationally it can be viewed as a generalization of the Kohn-Sham equations in density…

Superconductivity · Physics 2010-02-11 Dean Lee

We calculate and resolve with unprecedented detail the local density of states (DOS) and momentum-dependent spectral functions at zero temperature of one of the key models for strongly correlated electron materials, the degenerate…

Strongly Correlated Electrons · Physics 2021-01-04 K. Hallberg , Y. Núñez-Fernández

The method of many-body Green's functions is developed for arbitrary systems of electrons and nuclei starting from the full (beyond Born-Oppenheimer) Hamiltonian of Coulomb interactions and kinetic energies. The theory presented here…

Other Condensed Matter · Physics 2020-06-23 Ville J. Härkönen , Robert van Leeuwen , E. K. U. Gross

One of the central problems in quantum mechanics is to determine the ground state properties of a system of electrons interacting via the Coulomb potential. Since its introduction by Hohenberg, Kohn, and Sham, Density Functional Theory…

Quantum Physics · Physics 2010-09-28 Norbert Schuch , Frank Verstraete

Microscopically conserving reduced models of many-body systems have a long, highly successful history. Established theories of this type are the random-phase approximation for Coulomb fluids and the particle-particle ladder model for…

Strongly Correlated Electrons · Physics 2019-07-19 Frederick Green

The two-site Holstein model represents a first non-trivial paradigm for the interaction between an itinerant charge with a quantum oscillator, a very common topic in different ambits. Exact results can be achieved both analytically and…

Strongly Correlated Electrons · Physics 2008-06-19 Simone Paganelli , Sergio Ciuchi

At zero temperature, two-site dynamical mean field theory is applied to the Dynamic Hubbard model. The Dynamic Hubbard model describes the orbital relaxation that occurs when two electrons occupy the same site, by using a two-level boson…

Strongly Correlated Electrons · Physics 2010-12-16 G. Bach , J. E. Hirsch , F. Marsiglio

We provide solid evidence for the long-standing presumption that model Hamiltonians with short-range interactions faithfully reproduce the physics of the long-range Coulomb interaction in real materials. For this aim, we address a generic…

Strongly Correlated Electrons · Physics 2025-06-09 Florian Gebhard , Kevin Bauerbach , Örs Legeza

We present a density functional theory (DFT) for lattice models with local electron-electron (e-e) and electron-phonon (e-ph) interactions. Exchange-correlation potentials are derived via dynamical mean field theory for the…

Strongly Correlated Electrons · Physics 2019-09-04 E. Viñas Boström , P. Helmer , P. Werner , C. Verdozzi

Based on the work of Gorling and that of Levy and Nagy, density-functional formalism for many Fermionic excited-states is explored through a careful and rigorous analysis of the excited-state density to external potential mapping. It is…

Materials Science · Physics 2009-11-11 Prasanjit Samal , Manoj K. Harbola

A relativistic density-functional theory based on a Fock-space effective quantum-electrodynamics (QED) Hamiltonian using the Coulomb or Coulomb-Breit two-particle interaction is developed. This effective QED theory properly includes the…

Chemical Physics · Physics 2021-05-03 Julien Toulouse

For classical many-body systems subject to Brownian dynamics we develop a superadiabatic dynamical density functional theory (DDFT) for the description of inhomogeneous fluids out-of-equilibrium. By explicitly incorporating the dynamics of…

Soft Condensed Matter · Physics 2022-12-20 S. M. Tschopp , J. M. Brader

We perform model calculations for a stretched LiF molecule, demonstrating that nonadiabatic charge transfer effects can be accurately and seamlessly described within a density functional framework. In alkali halides like LiF, there is an…

Chemical Physics · Physics 2018-03-01 Chen Li , Ryan Requist , E. K. U. Gross

The interplay of disorder and strong correlations in quantum many-body systems remains an open question. That is despite much progress made in recent years with ultracold atoms in optical lattices to better understand phenomena such as…

Strongly Correlated Electrons · Physics 2021-10-19 Jacob Park , Ehsan Khatami

Two very different methods -- exact diagonalization on finite chains and a variational method -- are used to study the possibility of a metal-insulator transition in the symmetric half-filled periodic Anderson-Hubbard model. With this aim…

Strongly Correlated Electrons · Physics 2015-06-05 I. Hagymasi , K. Itai , J. Solyom