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The second law of thermodynamics is discussed and reformulated from a quantum information theoretic perspective for open quantum systems using relative entropy. Specifically, the relative entropy of a quantum state with respect to…

Quantum Physics · Physics 2020-11-11 Neil Dowling , Stefan Floerchinger , Tobias Haas

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

Quantum Physics · Physics 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

Redfield theory provides a closed kinetic description of a quantum system in weak contact with a very dense reservoir. Landau-Zener theory does the same for a time-dependent driven system in contact with a sparse reservoir. Using a simple…

Statistical Mechanics · Physics 2017-11-22 Juzar Thingna , Felipe Barra , Massimiliano Esposito

The standard approach to deriving fluctuation theorems fails to capture the effect of quantum correlation and coherence in the initial state of the system. Here we overcome this difficulty and derive heat exchange fluctuation theorem in the…

Quantum Physics · Physics 2020-09-30 Amikam Levy , Matteo Lostaglio

The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime,…

Statistical Mechanics · Physics 2016-06-29 Kay Brandner , Udo Seifert

Why do quantum evolutions occur and why do they stop at certain points? In classical thermodynamics affinity was introduced to predict in which direction an irreversible process proceeds. In this paper the quantum mechanical counterpart of…

Quantum Physics · Physics 2018-12-11 B. Ahmadi , S. Salimi , F. Kheirandish , A. S. Khorashad

The wide-spread opinion is that original quantum mechanics is a reversible theory, but this statement is only true for undecomposed systems, that are those systems which sub-systems are out of consideration. Taking sub-systems into account,…

Quantum Physics · Physics 2022-11-24 Wolfgang Muschik

The reduced dynamics of an open quantum system obtained from an underlying microscopic Hamiltonian can in general only approximately be described by a time local master equation. The quality of that approximation depends primarily on the…

Quantum Physics · Physics 2020-01-15 Richard Hartmann , Walter T. Strunz

The nature of a physical law is examined, and it is suggested that there may not be any fundamental dynamical laws. This explains the intrinsic indeterminism of quantum theory. The probabilities for transition from a given initial state to…

Quantum Physics · Physics 2007-05-23 Jeeva S. Anandan

Recent work using tools from quantum information theory has shown that at the nanoscale where quantum effects become prevalent, there is not one thermodynamical second law but many. Derivations of these laws assume that an experimenter has…

Quantum Physics · Physics 2018-12-19 Chris Perry , Piotr Ćwikliński , Janet Anders , Michał Horodecki , Jonathan Oppenheim

Thermodynamic principles are often deceptively simple and yet surprisingly powerful. We show how a simple rule, such as the net flow of energy in and out of a moving atom under nonequilibrium steady state condition, can expose the…

Quantum Physics · Physics 2020-11-30 Daniel Reiche , Francesco Intravaia , Jen-Tsung Hsiang , Kurt Busch , Bei-Lok Hu

If the second law of thermodynamics forbids a transition from one state to another, then it is still possible to make the transition happen by using a sufficient amount of work. But if we do not have access to this amount of work, can the…

Quantum Physics · Physics 2016-11-02 Álvaro M. Alhambra , Jonathan Oppenheim , Christopher Perry

The validity of the Second Law of thermodynamics, indisputable in the macroscopic world, is challenged at the mesoscopic level: a mesoscopic isolated system, possessing spatial dimensions of the order of a few microns, is capable, as shown…

Classical Physics · Physics 2007-05-23 B. Crosignani , P. Di Porto , C. Conti

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small systems. Their general validity arbitrarily far from equilibrium makes them invaluable in nonequilibrium physics. So far, experimental studies of…

Fluctuation theorems and the second law of thermodynamics are powerful relations constraining the behavior of out-of-equilibrium systems. While there exist generalizations of these relations to feedback controlled quantum systems, their…

Quantum Physics · Physics 2024-10-07 Kacper Prech , Patrick P. Potts

Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…

General Physics · Physics 2007-05-23 Bin Zhou

Thermodynamics dictates that the specific heat of a system is strictly non-negative. However, in finite classical systems there are well known theoretical and experimental cases where this rule is violated, in particular finite atomic…

Statistical Mechanics · Physics 2015-06-15 Pablo Serra , Marcelo Carignano , Fahhad Alharbi , Sabre Kais

We present a short derivation and discussion of the master equation for an open quantum system weakly coupled to a heat bath and then its generalization to the case of with periodic external driving based on the Floquet theory. Further, a…

Quantum Physics · Physics 2012-05-22 Robert Alicki , David Gelbwaser-Klimovsky , Gershon Kurizki

The explanation of the apparent universality of thermodynamics points toward the extension of the usual conceptual background of the second law. Arguments are collected that a basic guiding idea of stability of thermodynamic equilibrium…

Classical Physics · Physics 2014-07-23 P. Ván

Originally formulated for macroscopic machines, the laws of thermodynamics were recently shown to hold for quantum systems coupled to ideal sources of work (external classical fields) and heat (systems at equilibrium). Ongoing efforts have…

Quantum Physics · Physics 2023-06-29 Cyril Elouard , Camille Lombard Latune