Related papers: The effect of selective desorption mechanisms duri…
Context. The presence of dust in the interstellar medium has profound consequences on the chemical composition of regions where stars are forming. Recent observations show that many species formed onto dust are populating the gas phase,…
The degree of porosity in interstellar dust-grain material is poorly defined, although recent work has suggested that the grains could be highly porous. Aside from influencing the optical properties of the dust, porosity has the potential…
Observational evidence seems to indicate that the depletion of interstellar carbon into dust shows rather wide variations and that carbon undergoes rather rapid recycling in the interstellar medium (ISM). Small hydrocarbon grains are…
Methanol and formaldehyde are two simple organic molecules that are ubiquitously detected in the interstellar medium. An origin in the solid phase and a subsequent nonthermal desorption into the gas phase is often invoked to explain their…
Aims. The mobility of H atoms on the surface of interstellar dust grains at low temperature is still a matter of debate. In dense clouds, the hydrogenation of adsorbed species (i.e., CO), as well as the subsequent deuteration of the…
In cold core of dark molecular clouds, where the UV radiation from external sources is strongly attenuated, cosmic rays can induce chemical reactions on the surface of ice-covered grains promoting the ejection of the processed material to…
Aims: Ices in dense star-forming cores contain the bulk of volatile molecules apart from H2 and thus represent a large fraction of dark cloud chemistry budget.To directly constrain the freeze-out profile of CO, the formation route of CO2…
Context. Interstellar dust particles, which represent 1% of the total mass, are recognized to be very powerful interstellar catalysts in star-forming regions. The presence of dust can have a strong impact on the chemical composition of…
Understanding the history and evolution of small bodies, such as dust grains and comets, in planet-forming disks is very important to reveal the architectural laws responsible for the creation of planetary systems. These small bodies in…
The detection of high gas-phase abundances of SO2 and SO in the cold envelope of an intermediate mass protostar suggests that these molecules might form on icy dust grains and subsequently desorb to the gas phase by non-thermal desorption…
Glycoaldehyde, ethylene glycol, and methyl formate are complex organic molecules that have been observed in dark molecular clouds. Because there is no efficient gas-phase route to produce these species, it is expected that a low-temperature…
We have used a coupled dynamical and chemical model to examine the chemical changes induced by the passage of an interstellar shock in well shielded regions. Using this model we demonstrate that the formation of water in a shock will be…
CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…
We present observations of the stretching mode of 13CO2 ice along 13 lines of sight in the Galaxy, using the Short Wavelength Spectrometer on board of the Infrared Space Observatory. Remarkable variations are seen in the absorption band…
The first off-lattice Monte Carlo kinetics model of interstellar dust-grain surface chemistry is presented. The positions of all surface particles are determined explicitly, according to the local potential minima resulting from the…
The typical amount of molecular hydrogen (${\rm H_2}$) in interstellar ices is not known, but significant freeze-out of ${\rm H_2}$ on dust grains is not expected. However, chemical models ubiquitously predict large amounts of $\rm H_2$…
Water is usually the main component of ice mantles, which cover the cores of dust grains in cold portions of dense interstellar clouds. When molecular hydrogen is adsorbed onto an icy mantle through physisorption, a common assumption in…
Cosmic-ray-induced whole-grain heating induces evaporation and other processes that affect the chemistry of interstellar clouds. With recent data on grain heating frequencies as an input for a modified rate-equation astrochemical model,…
Context: Chemical models of dense cloud cores often utilize the so-called pseudo-time-dependent approximation, in which the physical conditions are held fixed and uniform as the chemistry occurs. In this approximation, the initial…
Ionized carbon is the main gas-phase reservoir of carbon in the neutral diffuse interstellar medium and its 158 micron fine structure transition [CII] is the most important cooling line of the diffuse interstellar medium (ISM). We combine…