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The dynamics of flexible polymer molecules are often assumed to be governed by hydrodynamics of the solvent. However there is considerable evidence that internal dissipation of a polymer contributes as well. Here we investigate the dynamics…

Soft Condensed Matter · Physics 2013-05-29 J. M. Deutsch

By means of computer simulations, we investigate the relaxation of the Rouse modes in a simple bead-spring model for non-entangled polymer blends. Two different models are used for the fast component, namely fully-flexible and semiflexible…

Soft Condensed Matter · Physics 2015-05-20 Marco Bernabei , Angel J. Moreno , Juan Colmenero

We present Brownian dynamics simulation results of a flexible linear polymer with excluded-volume interactions under shear flow in the presence of active noise. The active noise strongly affects the polymer's conformational and dynamical…

Soft Condensed Matter · Physics 2023-11-21 Arindam Panda , Roland G. Winkler , Sunil P. Singh

In this paper we study the shape characteristics of a polymer chain in a good solvent using a mesoscopic level of modelling. The dissipative particle dynamics simulations are performed in the $3D$ space at a range of chain lengths $N$. The…

Soft Condensed Matter · Physics 2016-11-24 Ostap Kalyuzhnyi , Jaroslav Ilnytskyi , Yurij Holovatch , Christian von Ferber

We study the behavior of a flexible polymer chain in the presence of a low-molecular weight solvent in the vicinity of a liquid-gas critical point within the framework of a self-consistent field theory. The total free energy of the dilute…

Statistical Mechanics · Physics 2015-07-29 Yu. A. Budkov , A. L. Kolesnikov , N. Georgi , M. G. Kiselev

We study the relaxation dynamics of a coarse-grained polymer chain at different degrees of stretching by both analytical means and numerical simulations. The macromolecule is modelled as a string of beads, connected by anharmonic springs,…

Soft Condensed Matter · Physics 2009-11-13 M. Febbo , A. Milchev , V. Rostiashvili , T. A. Vilgis , D. Dimitrov

We study phenomenological scaling theories of the polymer dynamics in random media, employing the existing scaling theories of polymer chains and the percolation statistics. We investigate both the Rouse and the Zimm model for Brownian…

Soft Condensed Matter · Physics 2015-06-24 Bikas K. Chakrabarti , Amit K. Chattopadhyay , Amit Dutta

Although the stretching of polymers and biomolecules is important in numerous settings, their response when confined to two-dimensions is relatively poorly-studied. In this paper, we derive closed-form analytical expressions for the…

Soft Condensed Matter · Physics 2013-05-28 Sara Iliafar , Dmitri Vezenov , Anand Jagota

Following the Flory ideality hypothesis intrachain and interchain excluded volume interactions are supposed to compensate each other in dense polymer systems. Multi-chain effects should thus be neglected and polymer conformations may be…

Soft Condensed Matter · Physics 2009-11-13 H. Meyer , J. P. Wittmer , T. Kreer , P. Beckrich , A. Johner , J. Farago , J. Baschnagel

We suggest a theoretical description of the force-induced translocation dynamics of a polymer chain through a nanopore. Our consideration is based on the tensile (Pincus) blob picture of a pulled chain and the notion of propagating front of…

Soft Condensed Matter · Physics 2012-04-17 J. L. A. Dubbeldam , V. G. Rostiashvili , A. Milchev , T. A. Vilgis

We investigate a flexible polymer chain made up of chiral active Brownian particles in two dimensions using computer simulations. In the presence of chiral active Brownian forces, the radius of gyration of the chain reduces significantly.…

Soft Condensed Matter · Physics 2025-05-05 Shalabh K. Anand

Active polymers play a central role in many biological systems, from bacterial flagella to cellular cytoskeletons. Minimal models of semiflexible active filaments have been used to study a variety of interesting phenomena in active systems,…

Soft Condensed Matter · Physics 2020-02-19 Matthew S. E. Peterson , Michael F. Hagan , Aparna Baskaran

Solutions of semiflexible polymers confined by repulsive planar walls are studied by density functional theory and Molecular Dynamics simulations, to clarify the competition between the chain alignment favored by the wall and the depletion…

Soft Condensed Matter · Physics 2016-05-25 Sergei A. Egorov , Andrey Milchev , Peter Virnau , Kurt Binder

Using the pruned-enriched Rosenbluth Monte Carlo algorithm, the scattering functions of semiflexible macromolecules in dilute solution under good solvent conditions are estimated both in $d=2$ and $d=3$ dimensions, considering also the…

Soft Condensed Matter · Physics 2015-06-11 Hsiao-Ping Hsu , Wolfgang Paul , Kurt Binder

The Flory theory for a single polymer chain is derived as the lowest order of a cumulant expansion. In this approach, the full original Flory free energy (including the logarithmic term), is recovered. %This term does not change the…

Condensed Matter · Physics 2009-10-22 H. Orland

For biologically relevant macromolecules such as intrinsically disordered proteins, internal degrees of freedom that allow for shape changes have a large influence on both the motion and function of the compound. A detailed understanding of…

The collapse and swelling behavior of a generic homopolymer is studied using implicit-solvent, explicit-cosolvent Langevin dynamics computer simulations for varying interaction strengths. The systematic investigation reveals that polymer…

Soft Condensed Matter · Physics 2012-11-06 Anja Muzdalo , Jan Heyda , Joachim Dzubiella

By means of Brownian dynamics simulations we study the steady-state dynamic properties of a flexible active polymer in a poor solvent condition. Our results show that the effective diffusion constant of the polymer $D_{\rm eff}$ gets…

Soft Condensed Matter · Physics 2023-08-29 Suman Majumder , Subhajit Paul , Wolfhard Janke

We use molecular dynamics simulations to study the swelling of randomly end-cross-linked polymer networks in good solvent conditions. We find that the equilibrium degree of swelling saturates at Q_eq = N_e**(3/5) for mean strand lengths N_s…

Soft Condensed Matter · Physics 2009-10-31 Mathias Puetz , Ralf Everaers , Kurt Kremer

We study dynamics of a Rouse polymer chain, which diffuses in a three-dimensional space under the constraint that one of its ends, referred to as the slip-link, may move only along a one-dimensional line containing randomly placed,…

Statistical Mechanics · Physics 2007-05-23 S. Nechaev , G. Oshanin , A. Blumen