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Related papers: Proposal for Chiral Detection by the AC Stark-Effe…

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We report on a method for measuring ac Stark shifts observed in stored light experiments while simultaneously determining the energetic splitting between the electronic ground states involved in the two-photon transition. To this end we…

Quantum Physics · Physics 2021-09-22 Deviprasath Palani , Daniel Hoenig , Leon Karpa

Recently, the extremely sensitive torsion-rotation transitions in methanol have been used to set a tight constraint on a possible variation of the proton-to-electron mass ratio over cosmological time scales. In order to improve this…

Enantio-conversion with the help of electromagnetic fields is an essential issue due to the chirality-dependence of many chemical, biological, and pharmaceutical processes. Here, we propose a method for this issue based on a five-level…

Quantum Physics · Physics 2021-03-03 Chong Ye , Bo Liu , Yu-Yuan Chen , Yong Li

The ac Stark shift (or light shift) of the 6$^{2}$S$_{1/2}$ (F $=$ 3 $\leftrightarrow $ 4) transition in $^{133}$Cs, as observed through coherent population trapping under pulsed excitation, is measured using a $^{133}$Cs gas cell and the…

Atomic Physics · Physics 2014-08-07 Yuichiro Yano , Wujie Gao , Shigeyoshi Goka , Masatoshi Kajita

In this study, we apply the monitoring master equation describing decoherence of internal states to an optically active molecule prepared in a coherent superposition of nondegenerate internal states interacting with thermal photons at low…

Quantum Physics · Physics 2013-11-19 Farhad Taher Ghahramani , Afshin Shafiee

In a hybrid pumping alkali vapor cell that both K and Rb are filled, K atom spins are optically pumped by laser and Rb atom spins are polarized by the K spins through spin exchange. We find that the AC Stark shift of the Rb atoms is…

Atomic Physics · Physics 2016-12-07 Yao Chen , Yan Lu , Jiancheng Fang

Optical methods of enantiomeric-specific state transfer had been proposed theoretically based on a cyclic three-level system of chiral molecule. According to these theoretical methods, recently the breakthrough progress has been reported in…

Quantum Physics · Physics 2020-11-16 Quansheng Zhang , Chong Ye , Yu-Yuan Chen , Yong Li

Chiral objects typically exhibit a different extinction for the two circular polarizations of light. Researchers often detect the chirality of objects by measuring this extinction difference employing Circular Dichroism (CD) spectroscopy.…

A novel optical method for distinguishing chiral molecules is proposed and validated within a quantum simulator employing a trapped-ion qudit. This approach correlates the sign disparity of the dipole moment of chiral molecules with…

Quantum Physics · Physics 2024-03-11 Teng Liu , Fa Zhao , Pengfei Lu , Qifeng Lao , Min Ding , Ji Bian , Feng Zhu , Le Luo

In the close vicinity of a chiral nanostructure, the circular dichroism of a biomolecule could be greatly enhanced, due to the interaction with the local superchiral fields. Modest enhancement of optical activity using a planar…

A problem of inducing a required sign of chirality in a racemic mixture of enantiomers of a chiral molecule is analyzed. As an example, a racemic mixture (vapor) of left- and right-handed enantiomers of hydrogen peroxide (H2O2) molecule is…

Chemical Physics · Physics 2007-05-23 Boris Grishanin , Victor Zadkov

We demonstrate the effectiveness of a guided-wave Bose-Einstein condensate interferometer for practical measurements. Taking advantage of the large arm separations obtainable in our interferometer, the energy levels of the 87Rb atoms in one…

Atomic Physics · Physics 2009-11-13 B. Deissler , K. J. Hughes , J. H. T. Burke , C. A. Sackett

Recent research discovered that charge transfer processes in chiral molecules can be spin selective and named the effect chiral-induced spin selectivity (CISS). Follow-up work studied hybrid spintronic devices with conventional electronic…

Mesoscale and Nanoscale Physics · Physics 2019-06-25 Xu Yang , Tom Bosma , Bart J. van Wees , Caspar H. van der Wal

Circular Dichroism (CD) can distinguish the handedness of chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest Thermal Circular Dichroism (TCD) for chiral…

Optics · Physics 2024-07-19 Ershad Mohammadi , Giulia Tagliabue

We demonstrate magic wavelengths, at which external electric field produces null differential Stark shifts, for the $6s ~ {^2}S_{1/2}-6p ~ {^2}P_{1/2,3/2}$ transitions in the Cs atom due to circularly polarized light. In addition, we also…

Atomic Physics · Physics 2016-07-20 Sukhjit Singh , Kiranpreet Kaur , B. K. Sahoo , Bindiya Arora

We derive density-dependent corrections to the in-medium nucleon-nucleon interaction from the leading-order chiral three-nucleon force. To this order there are six distinct one-loop diagrams contributing to the in-medium nucleon-nucleon…

Nuclear Theory · Physics 2010-04-06 J. W. Holt , N. Kaiser , W. Weise

A model potential previously developed for the ammonia molecule is treated in a single-center partial-wave approximation in analogy with a self-consistent field method developed by Moccia. The latter was used in a number of collision…

Chemical Physics · Physics 2024-04-17 Patrik Pirkola , Marko Horbatsch

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

Photoexcitable donor-bridge-acceptor (D-B-A) molecules that support intramolecular charge transfer are ideal platforms to probe the influence of chiral-induced spin selectivity (CISS) in electron transfer and resulting radical pairs. In…

Quantum Physics · Physics 2023-04-27 Laura A. Völker , Konstantin Herb , Erika Janitz , Christian L. Degen , John M. Abendroth

Hydrogen dissociation is an unwanted competing pathway if a torsional motion around the C=C double bond in a chiral fluoroethylene derivative, namely (4-methylcyclohexylidene) fluoromethane (4MCF), is to be achieved. We show that the…

Chemical Physics · Physics 2021-03-26 Daniel Kinzel , Philipp Marquetand , Leticia González