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Following the discovery of superconductivity in an iron-based arsenide LaO1-xFxFeAs with a superconducting transition temperature (Tc) of 26 K[1], Tc was pushed up surprisingly to above 40 K by either applying pressure[2] or replacing La…

We report that the incorporation of hydroxide ions (OH)- significantly enhances the superconducting transition temperature (Tc) in the LnFeAsO-based superconductors (Ln1111: Ln = La, Ce and Pr). For La1111, Tc of the (OH)- incorporated…

We have successfully synthesized one member of LnFeAsO (Ln stands for lanthanides) with Ln=Tb. By partial substitution of Tb$^{3+}$ by Th$^{4+}$, superconductivity with onset $T_{c}$ up to 52 K was observed. In the undoped parent compound,…

Superconductivity · Physics 2008-10-11 Lin-jun Li , Yu-ke Li , Zhi Ren , Yong-kang Luo , Xiao Lin , Mi He , Qian Tao , Zeng-wei Zhu , Guang-han Cao , Zhu-an Xu

Here we report the superconductivity in the LaFeAsO1-xFx system prepared by high pressure synthesis. The highest onset superconducting transition temperature (Tc) in this La-based system is 41.0 K with the nominal composition of…

Hydrogen is the simplest bipolar element and its valence state can be controlled from +1 to -1. We synthesized the 1111-type CaFeAsH and LnFeAsO1-xHx (Ln = lanthanide) with the ZrCuSiAs type structure by a high-pressure synthesis method.…

Superconductivity · Physics 2017-08-02 Hideo Hosono , Satoru Matsuishi

The recently discovered quaternary arsenide oxide superconductor La[O1-xFx]FeAs with the superconducting critical transition temperature (Tc) of 26 K [1], has been quickly expanded to another high-Tc superconducting system beyond copper…

We report the realization of superconductivity by 5d element Ir doping in LaFeAsO, a prototype parent compound of high-temperature iron based superconductors. X-ray diffraction patterns indicate that the material has formed the…

Superconductivity · Physics 2009-08-06 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Zhiyu Zhang , Yanwei Ma

The response of the worldwide scientific community to the discovery in 2008 of superconductivity at Tc = 26 K in the Fe-based compound LaFeAsO_{1-x}F_x has been very enthusiastic. In short order, other Fe-based superconductors with the same…

Superconductivity · Physics 2015-03-17 David C. Johnston

Iron arsenide superconductors based on the material LaFeAsO1-xFx are characterized by a two-dimensional Fermi surface (FS) consisting of hole and electron pockets yielding structural and antiferromagnetic transitions at x = 0. Electron…

Study of superconductivity in layered iron-based materials was initiated in 2006 by Hosono's group, and boosted in 2008 by the superconducting transition temperature, Tc, of 26 K in LaFeAsO1-xFx. Since then, enormous researches have been…

Superconductivity · Physics 2012-01-04 Hyungju Oh , Jisoo Moon , Donghan Shin , Chang-Youn Moon , Hyoung Joon Choi

High temperature superconductors with a Tc above 40 K have been found to be strongly correlated electron systems and to have a layered structure. Guided by these rules, Kamihara et al. discovered a Tc up to 26 K in the layered…

Superconductivity · Physics 2008-08-05 B. Lorenz , K. Sasmal , R. P. Chaudhury , X. H. Chen , R. H. Liu , T. Wu , C. W. Chu

The effect of pressure on superconductivity of 111 type NaxFeAs is investigated through temperature dependent electrical resistance measurement in a diamond anvil cell. The superconducting transition temperature (Tc) increases from 26 K to…

Superconductivity · Physics 2015-05-14 S. J. Zhang , X. C. Wang , Q. Q. Liu , Y. X. Lv , X. H. Yu , Z. J. Lin. , Y. S. Zhao , L. Wang , Y. Ding , H. K. Mao , C. Q. Jin

A wide-range doping was achieved by a high-pressure method for TbFeAsO1-x from "under doped" to "over doped" superconducting compositions throughout the optimized superconductivity (Tc of 44 K). Tc vs. lattice constant shows a dome-shaped…

Since the discovery of copper oxide superconductor in 1986 [1], extensive efforts have been devoted to the search of new high-Tc superconducting materials, especially high-Tc systems other than cuprates. The recently discovered quaternary…

Superconductivity · Physics 2008-09-19 Zhi-An Ren , Jie Yang , Wei Lu , Wei Yi , Guang-Can Che , Xiao-Li Dong , Li-Ling Sun , Zhong-Xian Zhao

Compounds of Sr1-xLaxFe2As2 were synthesized by solid state reaction at 1273 K, under pressures of 2 or 3 GPa. The Sr1-xLaxFe2As2 phase was dominant up to x = 0.5, and superconductivity was observed at $x \ge 0.2$. A maximum critical…

Superconductivity · Physics 2015-05-18 Yoshinori Muraba , Satoru Matsuishi , Sung-Wng Kim , Toshiyuki Atou , Osamu Fukunaga , Hideo Hosono

Utilizing the high stability of calcium and rare earth hydrides, CaFeAsF1-xHx (x = 0.0-1.0) and SmFeAsO1-xHx (x = 0.0-0.47) have been first synthesized using high pressure to form hydrogen-substituted 1111 type iron-arsenide…

The discovery of high temperature superconductivity in La[O1-xFx]FeAs at the beginning of this year [1] has generated much excitement and has led to the rapid discovery of similar compounds with as high as 55 K transition temperatures [2].…

Superconductivity · Physics 2008-06-30 M. C. Boyer , Kamalesh Chatterjee , W. D. Wise , G. F. Chen , J. L. Luo , N. L. Wang , E. W. Hudson

Co-doping of lanthanum and phosphorus in CaFe2As2 induces superconductivity at 45 K. This superconducting transition temperature is higher than the 38 K transition in Ba1-xKxFe2As2, which is the maximum found thus far among the 122 phases.…

The effects of isovalent doping on the superconducting transition temperature Tc in novel 112-type iron arsenide Ca1-xLaxFeAs2 were studied by conducting measurements of electrical resistivity rho and magnetization M. P or Sb doping…

We have succeeded in synthesizing single-phase polycrystalline samples of oxygen-deficient oxypnictide superconductors, LnFeAsO1-y (Ln: lanthanide elements) with Ln=La, Ce, Pr, Nd, Sm, Gd, Tb and Dy using high-pressure synthesis technique.…

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