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Despite the rapid rise in the performance of a variety of perovskite optoelectronic devices with vertical charge transport, the effects of ion migration remain a common and longstanding Achilles heel limiting the long-term operational…

In band-like semiconductors, charge carriers form a thermal energy distribution rapidly after optical excitation. In hybrid lead halide perovskites, the cooling of such thermal carrier distributions occurs on timescales of ~300 fs via…

We explore solid electrolytes for electrostatic gating using field-effect transistors (FETs) in which thin WSe$_2$ crystals are exfoliated and transferred onto a lithium-ion conducting glass ceramic substrate. For negative gate voltages…

Mesoscale and Nanoscale Physics · Physics 2018-07-25 Marc Philippi , Ignacio Gutiérrez-Lezama , Nicolas Ubrig , Alberto F. Morpurgo

Metal halide perovskites, a class of cost-effective semiconductor materials, are of great interest for modern and upcoming display technologies that prioritize the light-emitting diodes (LEDs) with high efficiency and excellent color…

Films of (FA$_{0.79}$MA$_{0.16}$Cs$_{0.05}$)$_{0.97}$Pb(I$_{0.84}$Br$_{0.16}$)$_{2.97}$ were grown over TiO$_{2}$, SnO$_{2}$, ITO, and NiO. Film conductivity was interrogated by measuring the in-phase and out-of-phase forces acting between…

Applied Physics · Physics 2019-01-18 Ali Moeed Tirmzi , Jeffrey A. Christians , Ryan P. Dwyer , David T. Moore , John A. Marohn

Here we develop a microscopic approach aimed at the description of a suite of physical effects related to carrier transport in, and the optical properties of, halide perovskites. Our theory is based on the description of the nuclear…

Materials Science · Physics 2018-11-13 Matthew Z. Mayers , Liang Z. Tan , David A. Egger , Andrew M. Rappe , David R. Reichman

The field effect transistors (FETs) exhibited ultrahigh responsivity (107 A/W) to infrared light with great improvement of mobility in graphene / PbS quantum dot (QD) hybrid. These reported transistors are either unipolar or depletion mode…

Instrumentation and Detectors · Physics 2014-10-10 Ran Wang , Yating Zhang , Haiyang Wang , Xiaoxian Song , Lufan Jin , Haitao Dai , Sen Wu , Jianquan Yao

The emergence of methyl-ammonium lead halide (MAPbX3) perovskites motivates the identification of unique properties giving rise to exceptional bulk transport properties, and identifying future materials with similar properties. Here, we…

Materials Science · Physics 2015-05-25 Riley E. Brandt , Vladan Stevanović , David S. Ginley , Tonio Buonassisi

The thermoelectric properties of halide perovskites $\mathrm{CsMI_3}$ (M=Sn and Pb) are investigated from a combination of first-principles calculations and semiclassical Boltzmann transport theory by considering both the electron and…

Materials Science · Physics 2016-05-31 San-Dong Guo , Jian-Li Wang

Exposure to environmental factors is generally expected to cause degradation in perovskite films and solar cells. Herein, we show that films with certain defect profiles can display the opposite effect, healing upon exposure to oxygen under…

We report the application of femtosecond four-wave mixing (FWM) to the study of carrier transport in solution-processed CH3NH3PbI3. The diffusion coefficient was extracted through direct detection of the lateral diffusion of carriers…

Materials Science · Physics 2017-10-11 D. Webber , C. Clegg , A. W. Mason , S. A. March , I. G. Hill , K. C. Hall

Ferroelectric all-inorganic halide perovskites nanocrystals with both spontaneous polarizations and visible light absorption are promising candidates for designing functional ferroelectric photovoltaic devices. Three dimensional halide…

We investigated the metal-insulator transition for epitaxial thin films of the perovskite CaFeO3, a material with a significant oxygen ligand hole contribution to its electronic structure. We find that biaxial tensile and compressive strain…

Ionic migration has been proposed as a possible cause of photovoltaic current-voltage hysteresis in hybrid perovskite solar cells. However, a major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial…

Quasi-two-dimensional (quasi-2D) metal halide perovskites exhibit rich phase heterogeneity that profoundly influences light-matter interactions and charge transport. However, the fundamental mechanisms governing carrier transfer across…

Materials Science · Physics 2025-12-09 Soumya Halder , Koushik Gayen , Nagendra S. Kamath , Suman Kalyan Pal

Efficient charge separation at the interfaces between the perovskite and with the carrier transport layers is crucial for perovskite solar cells to achieve high power conversion efficiency. We systematically investigate the hole injection…

Materials Science · Physics 2017-10-05 Kunie Ishioka , Bobby G. Barker , Masatoshi Yanagida , Yasuhiro Shirai , Kenjiro Miyano

Phase transitions in metal halide perovskites triggered by external provocations produce significantly different material properties, providing a prodigious opportunity for a comprehensive applications. In the present study, the first…

Inorganic lead halide perovskite materials have attracted great attention recently due to their potential for greater thermal stability compared to hybrid organic perovskites. However, the high processing temperature to convert from the…

Applied Physics · Physics 2018-09-13 Dianyi Liu , Chenchen Yang , Matthew Bates , Richard R. Lunt

Modulation of the grain boundary properties in thermoelectric materials that have thermally activated electrical conductivity is crucial in order to achieve high performance at low temperatures. In this work, we show directly that the…

Materials Science · Physics 2021-04-01 Jianyun Cao , Dursun Ekren , Yudong Peng , Feridoon Azough , Ian A. Kinloch , Robert Freer

The presence of hot carriers is presented in the operational properties of an (FA,Cs)Pb(I, Br, Cl)3 solar cell at ambient temperatures and under practical solar concentration. At 100 K, clear evidence of hot carriers is observed in both the…

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