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We show that very long range repulsive interactions of a generalized Coulomb-like form $V(R)\sim R^{-\alpha}$, with $\alpha<d$ ($d$-dimensionality), typically introduce very strong frustration, resulting in extreme fragility of the…

Strongly Correlated Electrons · Physics 2011-09-20 Y. Pramudya , H. Terletska , S. Pankov , E. Manousakis , V. Dobrosavljević

The reversible phase transition from hydrochloric-acid-doped ice VI to its hydrogen-ordered counterpart ice XV is followed using differential scanning calorimetry. Upon cooling at ambient pressure fast hydrogen ordering is observed at first…

Materials Science · Physics 2016-05-10 Jacob J. Shephard , Christoph G. Salzmann

Water ice's remarkable properties make it an important material across a range of disciplines. The combination of covalent and hydrogen bonds form a long-range lattice of oxygens, which hosts a disordered yet correlated hydrogen network. We…

We conducted experiments to directionally freeze agar hydrogel drops with different polymer concentrations, on a copper substrate maintained at low temperature. Unlike the water droplet studied in the literature, where the liquid part can…

Soft Condensed Matter · Physics 2024-10-10 Lila Séguy , Axel Huerre , Suzie Protière

We present evidence that the prismatic and secondary prism facets of ice-I$_\mathrm{h}$ crystals possess structural features that can reduce the effective hydrophilicity of the ice/water interface. The spreading dynamics of liquid water…

Chemical Physics · Physics 2015-01-07 Patrick B. Louden , J. Daniel Gezelter

We use molecular dynamics simulations of a simple model to show that dispersions of slightly elongated colloidal particles with long-range dipolar interactions, like ferrofluids, can form a physical (reversible) gel at low volume fractions.…

Soft Condensed Matter · Physics 2007-05-23 Ronald Blaak , Mark A. Miller , Jean-Pierre Hansen

Water is the main component of interstellar ice mantles, is abundant in the solar system and is a crucial ingredient for life. The formation of this molecule in the interstellar medium cannot be explained by gas-phase chemistry only and its…

Solar and Stellar Astrophysics · Physics 2017-08-23 S. Ioppolo , H. M. Cuppen , C. Romanzin , E. F. van Dishoeck , H. Linnartz

We discuss the problem of proton motion in Hydrogen bond materials with special focus on ice. We show that phenomenological models proposed in the past for the study of ice can be recast in terms of microscopic models in close relationship…

Materials Science · Physics 2009-11-11 A. H. Castro Neto , P. Pujol , Eduardo Fradkin

Cooling forces result from the retarded dipole interaction between an illuminated particle and its reflection. For a one-dimensional example, we find cooling times of milliseconds and limiting temperatures in the millikelvin range. The…

Quantum Physics · Physics 2013-03-08 Tim Freegarde , James Bateman , André Xuereb , Peter Horak

A laboratory study on the band profiles and band strengths of H2O in CO ice, and vice versa, is presented and interpreted in terms of two models. The results show that a mutual interaction takes place between the two species in the solid,…

We report a detailed ab initio investigation on hydrogen bonding, geometry, electronic structure, and lattice dynamics of ice under a large high pressure range, including the ice X phase (55-380GPa), the previous theoretically proposed…

Materials Science · Physics 2008-01-03 Renjun Xu , Zhiming Liu , Yanming Ma , Tian Cui , Bingbing Liu , Guangtian Zou

We use extensive first-principles quantum mechanical calculations to show that, although the static lattice and harmonic vibrational energies are almost identical, the anharmonic vibrational energy of hexagonal ice is significantly lower…

Materials Science · Physics 2015-08-13 Edgar A. Engel , Bartomeu Monserrat , Richard J. Needs

An equation of state for the domain extending from hot gases to cool-dense fluids is formulated for a hydrogen-helium mixture. The physical processes take account of temperature ionization and dissociation, electron degeneracy, Coulomb…

Astrophysics · Physics 2009-10-30 G. Q. Luo

A uniform solidification front undergoes non-trivial deformations when encountering an insoluble dispersed particle in a melt. For solid particles, the overall deformation characteristics are primarily dictated by heat transfer between the…

Fluid Dynamics · Physics 2024-03-01 Duco van Buuren , Pallav Kant , Jochem G. Meijer , Christian Diddens , Detlef Lohse

The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore)…

Experiments on the hydrogenation of CO on crystalline and amorphous ice at 15 K were carried out to investigate the structural effects of the ice surface. The effective rate of H atom addition to CO on the amorphous ice was found to be…

Astrophysics · Physics 2008-05-23 H. Hidaka , N. Miyauchi , A. Kouchi , N. Watanabe

Molecular undercoordination shortens and stiffens the H-O bond but lengthens and softens the O:H nonbond simultaneously associated with O 1s energy entrapment and nonbonding electron dual polarization, which dictates behavior of water and…

Soft Condensed Matter · Physics 2015-02-24 Chang Q. Sun

The presence of liquid water in frozen media impacts the strength of soils, the growth of frost heave, plant life and microbial activities, or the durability of infrastructures in cold regions. If the effect of confinement on freezing is…

Soft Condensed Matter · Physics 2019-07-25 Felix Ginot , Théo Lenavetier , Dmytro Dedovets , Sylvain Deville

When materials freeze, they often undergo damage due to ice growth. Although this damage is commonly ascribed to the volumetric expansion of water upon freezing, it is usually driven by suction of water towards growing ice crystals. The…

Soft Condensed Matter · Physics 2022-08-24 Dominic Gerber , Lawrence A. Wilen , Florian Poydenot , Eric R. Dufresne , Robert W. Style

The hydrogen mean force from experimental neutron Compton profiles is derived using deep inelastic neutron scattering on amorphous and polycrystalline ice. The formalism of mean force is extended to probe its sensitivity to anharmonicity in…