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In this paper we study the surface effects that bulk flexoelectric models in finite samples exhibit. We first show that when the body is infinite, flexoelectric materials do not exhibit electromechanical response under homogeneous loading.…

Materials Science · Physics 2025-01-30 H. Mohammadi , F. Greco , D. Codony , I. Arias

Static flexoelectric effect in a finite sample of a solid is addressed in terms of phenomenological theory for the case of a thin plate subjected to bending. It has been shown that despite an explicit asymmetry inherent to the bulk…

Materials Science · Physics 2015-05-30 Alexander K. Tagantsev , Alexander S. Yurkov

Electrostatics in the solution phase is governed by free electrical charges such as ions, as well as by bound charges that arise when a polarizable medium responds to an applied field. In a local medium, described by a constant dielectric…

Soft Condensed Matter · Physics 2025-02-04 Ali Behjatian , Ralf Blossey , Madhavi Krishnan

In many cases the correct theoretical description of flexoelectricity requires the consideration of the finite size of a body and is reduced to the solution of boundary problems for partial differential equations. Generally speaking, in…

Materials Science · Physics 2015-01-20 A. S. Yurkov

Flexoelectricity is the linear response of polarization to a strain gradient. Here we address the simplest class of dielectrics, namely elemental cubic crystals, and we prove that therein there is no extrinsic (i.e. surface) contribution to…

Materials Science · Physics 2010-11-09 R. Resta

The polarization response of a material to a strain gradient, known as flexoelectricity, holds great promise for novel electromechanical applications. Despite considerable recent progress, however, the effect remains poorly understood. From…

Materials Science · Physics 2014-12-03 Massimiliano Stengel

We study the effect of depolarization field related with inhomogeneous polarization distribution, strain and surface energy parameters on a domain wall profile near the surface of a ferroelectric film within the framework of…

In this work we analyze the finite-size effects on the structural properties and on the polarization of the rhombohedral phase of HfO$_2$ subjected to a biaxial compressive strain. We show how the presence of surface charges affects the…

Materials Science · Physics 2022-10-12 Francesco Delodovici , Paolo Barone , Silvia Picozzi

We study the effects of long-range electrostatic interactions on the thermal fluctuations of free-standing crystalline membranes exhibiting spontaneous electric polarization directed at each point along the local normal to the surface. We…

Statistical Mechanics · Physics 2019-11-20 Achille Mauri , Mikhail I. Katsnelson

In the framework of the thermodynamic approach Landau-Ginzburg-Devonshire (LGD) combined with the equations of electrostatics, we investigated the effect of polarization surface screening on finite size effects of the phase diagrams, polar…

Flexoelectricity is characterised by the coupling of the gradient of the deformation and the electrical polarization in a dielectric material. A novel micromorphic approach is presented to accommodate the resulting higher-order gradient…

Classical Physics · Physics 2023-07-19 Andrew McBride , Denis Davydov , Paul Steinmann

The standard Maxwell formulation of the problem of polarized dielectrics suffers from a number of difficulties, both conceptual and practical. These difficulties are particularly significant in the case of liquid interfaces, where the…

Soft Condensed Matter · Physics 2015-06-18 Dmitry V. Matyushov

Surface effects on the electronic energy loss of charged particles entering a metal surface are investigated within linear-response theory, in the framework of time-dependent density functional theory. Interesting phenomena occur in the…

Materials Science · Physics 2007-05-23 A. Garcia-Lekue , J. M. Pitarke

Theoretical analysis based on the Landau-Ginzburg-Devonshire (LGD) theory is used to show that the joint action of flexoelectric effect and rotostriction leads to a large spontaneous in-plane polarization (~ 1-5 muC/cm2) and pyroelectric…

Materials Science · Physics 2015-06-03 A. N. Morozovska , E. A. Eliseev , S. V. Kalinin , Long Qing Chen , Venkatraman Gopalan

Surface electric (charge) noise influences spin defects due to fluctuation of the surface charge density and also the electrostatic potential at the crystal surface. Surprisingly, the two-point correlation function of both the charged…

Mesoscale and Nanoscale Physics · Physics 2025-04-22 Denis R. Candido , Michael E. Flatté

We developed a Landau type theory for the description of polar phenomena in low-dimensional transition metal dichalcogenides (TMDs), specifically exploring flexoelectric origin of the polarization induced by a spontaneous bending and by…

Upon application of a uniform strain, internal sub-lattice shifts within the unit cell of a non-centrosymmetric dielectric crystal result in the appearance of a net dipole moment: a phenomenon well known as piezoelectricity. A macroscopic…

Materials Science · Physics 2015-05-13 R. Maranganti , P. Sharma

The theory of size effects of the properties of nanocrystalline ferroelectric ceramic or nanoparticle powder allowing for surface tension and depolarization field is proposed. Surface tension was included into free energy functional and…

Materials Science · Physics 2015-06-24 M. D. Glinchuk , A. N. Morozovskaya

The statistical theory of the dipole flexoelectric (FE) polarization in liquid crystals is used to calculate the temperature dependence of order parameters, the elastic constants and the FE coefficients. Two systems with polar wedge-shaped…

Soft Condensed Matter · Physics 2011-02-10 A. Kapanowski

Dielectric nano-swithes made of the materials that exhibit piezoelectric and/or flexoelectric properties with significant electro-mechanical coupling are considered. In this case, a nonuniform strain field may locally break inversion…

Materials Science · Physics 2010-02-16 M. M. Toropova
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