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The results of the first investigations of the process of local decomposition of lead-lanthanum zirconate-titanate solid solution in the vicinity of the interphase boundaries separating domains of coexisting ferroelectric and…

Materials Science · Physics 2007-05-23 V. M. Ishchuk , Z. A. Samoylenko , V. L. Sobolev

Results presented in this article demonstrate importance of taking into account such a phenomenon as the solid solution decomposition at the boundaries separating coexisting phases in lead-zirconate-titanate-based solid solutions with…

Materials Science · Physics 2016-10-21 V. M. Ishchuk , D. V. Kuzenko , V. L. Sobolev

This paper contains results of investigations of inhomogeneous states caused by the coexistence of ferroelectric and antiferroelectric phases in lead-zirconate-titanate based solid solutions. The domains of ferroelectric and…

Materials Science · Physics 2007-05-23 V. M. Ishchuk , N. A. Spiridonov , V. L. Sobolev

Comprehensive review of investigations of substances with a small difference in the energies of the ferroelectric and antiferroelectric types of dipole ordering is presented. Detailed analysis of the stability of homogeneous phases and…

Materials Science · Physics 2018-01-11 V. M. Ishchuk , V. L. Sobolev

Physical effects caused by the presence of interfaces between the domains of coexisting ferroelectric and antiferroelectric phases in solid solutions with small difference in free energies of the ferroelectric and antiferroelectric states…

Materials Science · Physics 2015-06-08 V. M. Ishchuk , V. L. Sobolev

Results of detailed investigations of stability of phases in substances with the small difference in the energies of the ferroelectric and the antiferroelectric types of dipole ordering are presented. It is shown that interaction of locally…

Materials Science · Physics 2010-12-14 V. M. Ishchuk , V. L. Sobolev

Dielectric capacitors hold a tremendous advantage for energy storage due to their fast charge/discharge times and stability in comparison to batteries and supercapacitors. A key limitation to today's dielectric capacitors, however, is the…

The coexistence of different ferroelectric phases enables the tunability of the macroscopic properties and extensive applications from piezoelectric transducers to nonvolatile memories. Here we develop a thermodynamic model to predict the…

Materials Science · Physics 2022-01-26 Yang Zhang , Fei Xue , Bo Wang , Jia-Mian Hu , Shuai Dong , Jun-Ming Liu , Long-Qing Chen

Understanding the appearance of commensurate and incommensurate modulations in perovskite antiferroelectrics (AFEs) is of great importance for material design and engineering. The dielectric and elastic properties of the AFE domain…

Materials Science · Physics 2020-09-09 Zhen Liu , Bai-Xiang Xu

Dabconium hybrid perovskites include a number of recently-discovered ferroelectric phases with large spontaneous polarisations. The origin of ferroelectric response has been rationalised in general terms in the context of hydrogen bonding,…

Materials Science · Physics 2020-06-11 Dominic J. W. Allen , Nicholas C. Bristowe , Andrew L. Goodwin , Hamish H. -M. Yeung

Prediction of properties from composition is a fundamental goal of materials science and can greatly accelerate development of functional materials. It is particularly relevant for ferroelectric perovskite solid solutions where…

The electronic functionality of thin films is governed by their interfaces. This is very important for the ferroelectric (FE) state which depends on thin-film clamping and interfacial charge transfer. Here we show that in a heterostructure…

Mesoscale and Nanoscale Physics · Physics 2020-02-24 Michael Huth , Achim Rippert , Roland Sachser , Lukas Keller

Composite multiferroics, heterostructures of ferromagnetic (FM) and ferroelectric (FE) materials, are characterized by a remarkable magnetoelectric effect at the interface. Previous work has supported the ferromagnetic structure with…

Mesoscale and Nanoscale Physics · Physics 2016-04-01 Zidong Wang , Malcolm J. Grimson

Antiferroelectrics are emerging as advanced functional materials and are fertile ground for unusual electric effects. For example, they enhance the recoverable energy density in energy storage applications and give rise to large…

Using first-principles calculations, we predict that tunable ferroelectricity can be realized in oxide perovskites with the Grenier structure and ordered oxygen vacancies. Specifically, we show that $R_{1/3}A_{2/3}\mathrm{FeO}_{2.67}$…

Materials Science · Physics 2023-07-12 Yongjin Shin , Giulia Galli

By performing first-principles calculations on four capacitor structures based on BaTiO3 and PbTiO3, we determine the intrinsic interfacial effects that are responsible for the destabilization of the polar state in thin-film ferroelectric…

Materials Science · Physics 2011-03-03 Massimiliano Stengel , David Vanderbilt , Nicola A. Spaldin

An effective medium model is developed for disordered metamaterials containing a spatially random distribution of dielectric spheres. Similar to effective medium models for ordered metamaterials, this model predicts resonances in the…

Optics · Physics 2017-03-09 Brian A Slovick

The control of the dielectric and conductive properties of device-level systems is important for increasing the efficiency of energy- and information-related technologies. In some cases, such as neuromorphic computing, it is desirable to…

Mesoscale and Nanoscale Physics · Physics 2020-07-28 Dimitrios Fraggedakis , Mohammad Mirzadeh , Tingtao Zhou , Martin Z. Bazant

Natural interfaces in ferroic oxides have developed into versatile playgrounds for studying electronic correlation effects in 2D systems. The microscopic origin of the emergent local electronic properties is often debated, however, as…

We consider phase separated states in magnetic oxides (MO) thin films. We show that these states have a non-zero electric polarization. Moreover, the polarization is intimately related to a spatial distribution of magnetization in the film.…

Strongly Correlated Electrons · Physics 2019-10-09 O. G. Udalov , I. S. Beloborodov
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