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We analyze the slow, glassy structural relaxation as measured through collective and tagged-particle density correlation functions obtained from Brownian dynamics simulations for a polydisperse system of quasi-hard spheres in the framework…

Soft Condensed Matter · Physics 2010-10-18 F. Weysser , A. M. Puertas , M. Fuchs , Th. Voigtmann

We describe experimentally observed collective dynamics in colloidal suspensions of model hard-sphere particles using a modified mode coupling theory (MCT). This rescaled MCT is capable to describe quantitatively the wave-vector and…

Soft Condensed Matter · Physics 2024-03-08 Joel Diaz Maier , Joachim Wagner

We apply the macroscopic fluctuation theory (MFT) to study the large-scale dynamical properties of Brownian particles with arbitrary pairwise interaction. By combining it with standard results of equilibrium statistical mechanics for the…

Statistical Mechanics · Physics 2026-05-19 Aurélien Grabsch , Davide Venturelli , Olivier Bénichou

We present molecular dynamics simulations of the SPC/E model of water to probe the dynamic properties at temperatures from 350 K down to 190 K and pressures from 2.5GPa (25kbar) down to -300MPa (-3kbar). We compare our results with those…

Condensed Matter · Physics 2009-10-31 Francis W. Starr , Francesco Sciortino , H. Eugene Stanley

We present a diagrammatic formulation of a theory for the time dependence of density fluctuations in equilibrium systems of interacting Brownian particles. To facilitate derivation of the diagrammatic expansion we introduce a basis that…

Soft Condensed Matter · Physics 2009-11-13 Grzegorz Szamel

We solved the mode-coupling equations for the Kob-Andersen binary mixture using the structure factors calculated from Brownian dynamics simulations of the same system. We found, as was previously observed, that the mode-coupling…

Soft Condensed Matter · Physics 2009-11-11 Elijah Flenner , Grzegorz Szamel

Dense or glassy active matter, as a result of its remarkable resemblance to passive glass-forming materials, is enjoying increasing scientific interest. To better grasp the subtle effect of active motion on the process of vitrification, a…

Soft Condensed Matter · Physics 2023-10-20 Vincent E. Debets , Liesbeth M. C. Janssen

A combination of molecular-dynamics (MD) computer simulation and mode-coupling theory (MCT) is used to elucidate the structure-dynamics relation in sodium-silicate melts (NSx) of varying sodium concentration. Using only the partial static…

Disordered Systems and Neural Networks · Physics 2009-11-11 Thomas Voigtmann , Juergen Horbach

We present a theoretical analysis of the dynamic structure factor (DSF) of a liquid at and below the mode coupling critical temperature $T_c$, by developing a self-consistent theoretical treatment which includes the contributions both from…

Statistical Mechanics · Physics 2007-05-23 Sarika Maitra Bhattacharyya , Biman Bagchi , Peter G. Wolynes

We perform lengthy molecular dynamics simulations of the SPC/E model of water to investigate the dynamics under pressure at many temperatures and compare with experimental measurements. We calculate the isochrones of the diffusion constant…

Condensed Matter · Physics 2009-10-31 Francis W. Starr , Stephen Harrington , Francesco Sciortino , H. Eugene Stanley

The predictions of the mode-coupling theory of the glass transition (MCT) for the tagged-particle density-correlation functions and the mean-squared displacement curves are compared quantitatively and in detail to results from Newtonian-…

Statistical Mechanics · Physics 2009-11-10 Th. Voigtmann , A. M. Puertas , M. Fuchs

Using molecular dynamics computer simulations we study the dynamics of a molecular liquid by means of a general class of time-dependent correlators S_{ll'}^m(q,t) which explicitly involve translational (TDOF) and orientational degrees of…

Statistical Mechanics · Physics 2009-10-30 Stefan Kammerer , Walter Kob , Rolf Schilling

The friction and diffusion coefficients of rigid spherical colloidal particles dissolved in a fluid are determined from velocity and force autocorrelation functions by mesoscale hydrodynamic simulations. Colloids with both slip and no-slip…

Soft Condensed Matter · Physics 2016-03-10 Mario Theers , Elmar Westphal , Gerhard Gompper , Roland G. Winkler

In a microrheological set-up a single probe particle immersed in a complex fluid is exposed to a strong external force driving the system out of equilibrium. Here, we elaborate analytically the time-dependent response of a probe particle in…

Soft Condensed Matter · Physics 2021-08-06 Sebastian Leitmann , Suvendu Mandal , Matthias Fuchs , Antonio M. Puertas , Thomas Franosch

Motivated by a number of recent experimental and computational studies of the dynamics of fluids plunged in quenched-disordered external fields, we report on a theoretical investigation of this topic within the framework of the…

Soft Condensed Matter · Physics 2018-10-05 Thomas Konincks , Vincent Krakoviack

We consider a toy model for glassy dynamics of colloidal suspensions: a single Brownian particle diffusing among immobile obstacles. If Gaussian factorization of static density fluctuations is assumed, this model can be solved without…

Soft Condensed Matter · Physics 2009-11-10 Grzegorz Szamel

We present a study of diffusion of small tagged particles in a solvent, using mode coupling theory (MCT) analysis and computer simulations. The study is carried out for various interaction potentials. For the first time, using MCT, it is…

Soft Condensed Matter · Physics 2015-06-12 Manoj Kumar Nandi , Atreyee Banerjee , Sarika Maitra Bhattacharyya

The equations of fluctuating nonlinear hydrodynamics for a two component mixture are obtained with a proper choice of slow variables which correspond to the conservation laws in the system. Using these nonlinear equations we construct the…

Statistical Mechanics · Physics 2016-01-20 Madhu Priya , Neeta Bidhoodi , Shankar P. Das

Electrostatic correlations and variable permittivity of electrolytes are essential for exploring many chemical and physical properties of interfaces in aqueous solutions. We propose a continuum electrostatic model for the treatment of these…

Soft Condensed Matter · Physics 2015-06-23 Manman Ma , Zhenli Xu

The dynamics of Lennard-Jones fluid is studied through extended mode coupling theory (MCT) with the inclusion of the slow mode of defect density. Inclusion of defect density facilitates the liquid like state for temperatures much lower than…

Statistical Mechanics · Physics 2009-11-07 Sudha Srivastava , Shankar P. Das