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Understanding of recently reported putative close-to-room-temperature superconductivity in C-S-H compounds at 267 GPa demands reproducible synthesis protocol as well as knowledge of its structure and composition. We synthesized C-S-H…

The recent reports on 203 K superconductivity in compressed hydrogen sulfide, H$_3$S, has attracted great interest in sulfur-hydrogen system under high pressure. Here, we investigated the superconductivity of P-doped and Cl-doped H$_3$S…

Superconductivity · Physics 2018-12-26 Akitaka Nakanishi , Takahiro Ishikawa , Katsuya Shimizu

The discovery of the high temperature superconducting state in compounds of hydrogen, carbon and sulfur with the critical temperature (Tc) of 288 K at high pressure is an important milestone towards room-temperature superconductors. Here,…

Superconductivity · Physics 2021-07-23 Mingyang Du , Zihan Zhang , Tian Cui , Defang Duan1

Using density functional theory the atomic and electronic structure of sodium are predicted to depart substantially from those expected of simple metals for $r_s <$ 2.48 ($p > 130$ GPa). Newly-predicted phases include those with low…

Materials Science · Physics 2009-10-31 J. B. Neaton , N. W. Ashcroft

Using ab initio evolutionary structure prediction method in conjunction with density functional theory, we performed a systematic investigation on the structural transition of elemental scandium under pressure up to 250 GPa. Our prediction…

Materials Science · Physics 2019-01-09 Shengcai Zhu , Xiao-Zhi Yan , Scott Fredericks , Yan-Ling Li , Qiang Zhu

Binary metal sulfides are potential material family for exploring high Tc superconductors under high pressure. In this work, we study the crystal structures, electronic structures and superconducting properties of the Lu-S system in the…

Superconductivity · Physics 2023-12-25 Juefei Wu , Bangshuai Zhu , Chi Ding , Dexi Shao , Cuiying Pei , Qi Wang , Jian Sun , Yanpeng Qi

Superconductivity at temperatures up to 190 K at high pressures has recently been observed in $H_2S$ and interpreted as conventional BCS-electron-phonon-driven superconductivity.\cite{h2s} Instead we propose that it is another example of…

Superconductivity · Physics 2015-04-24 J. E. Hirsch , F. Marsiglio

Silicate frameworks exhibit diverse structural responses under extreme conditions, which are strongly influenced by hydration. Here, we present a comparative high-pressure synchrotron X-ray diffraction study of Na2ZrSi2O7 and its hydrated…

Pressure-stabilized hydrides are a new rapidly growing class of high-temperature superconductors which is believed to be described within the conventional phonon-mediated mechanism of coupling. Here we report the synthesis of yttrium…

A comparative computational study of stability of candidate structures for an as yet unknown silver dichloride AgCl2 is presented. It is found that all considered candidates have a negative enthalpy of formation, but are unstable towards…

Materials Science · Physics 2022-01-25 A. Grzelak , W. Grochala

This study reports the decomposition of beta-SnWO4 into Sn, SnO2, and WO3 induced by static compression. We performed high-pressure synchrotron powder angle-dispersive X-ray diffraction measurements and found that decomposition occurs at a…

With the motivation of searching for new superconductors in the Mg-B system, we performed ab initio evolutionary searches for all the stable compounds in this binary system in the pressure range of 0-200 GPa. We found previously unknown,…

Superconductivity · Physics 2017-05-24 M. M. Davari Esfahani , Q. Zhu , H. Dong , A. R. Oganov , S. Wang , M. S. Rakitin , X-F. Zhou

Metallic hydrogen is expected to exhibit remarkable physics. Of particular interest in this work is the possibility of high-temperature superconductivity. Comparing calculations of the superconducting critical temperatures of the solid…

Superconductivity · Physics 2021-07-02 Craig M. Tenney , Zachary F. Croft , Jeffrey M. McMahon

It is generally believed that magnetization measurements on sulfur hydride under high pressure performed in 2015 [1] provided "final convincing evidence of superconductivity" [2] in that material, in agreement with theoretical predictions…

Superconductivity · Physics 2021-05-13 J. E. Hirsch , F. Marsiglio

Based on ab initio calculations and metadynamics simulations, we predict that 2H-MoS$_2$, a layered insulator, will metallize under pressures in excess of 20-30 GPa. In the same pressure range, simulations and enthalpy optimization predict…

Materials Science · Physics 2015-06-12 Liliana Hromadová , Roman Martoňák , Erio Tosatti

We report the impact of hydrostatic pressure (0-1.97GPa) on superconductivity of recently discovered 2K superconductor Sr0.5La0.5FBiS2. Resistivity under pressure measurements are performed by using HPC-33 Piston type pressure cell with…

Superconductivity · Physics 2015-06-18 Rajveer Jha , Brajesh Tiwari , V. P. S. Awana

The study of superconductivity in compressed hydrides is of great interest due to measurements of high critical temperatures (Tc) in the vicinity of room temperature, beginning with the observations of LaH10 at 170-190 GPa. However, the…

The lighter group-V element phosphorus forms the As-type (hR2) structure under pressure, above 5 GPa, and at 10 GPa transforms to the simple cubic structure (cP1), similar to arsenic. Despite of its low packing density, the simple cubic…

Materials Science · Physics 2018-06-22 V. F Degtyareva

High-pressure metal superhydrides have attracted intense scientific interest due to their remarkable superconducting properties. While superconductivity is known to be sensitive to material composition, compositional variability is often…

Superconductivity · Physics 2025-04-04 Xixi Jia , Haoran Chen , Xiaoqiu Ye , Jian Lv , Xitian Zhang , Hui Wang , Yansun Yao

Hydrogen-rich compounds are important for understanding the dissociation of dense molecular hydrogen, as well as searching for room temperature Bardeen-Cooper-Schrieffer (BCS) superconductors. A recent high pressure experiment reported the…

Materials Science · Physics 2017-05-12 Yangmei Chen , Hua Y. Geng , Xiaozhen Yan , Yi Sun , Qiang Wu , Xiangrong Chen