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Inspired by responses to the work (arXiv:1310.6514), we solved the one-dimensional, nonlinear Fourier initial and boundary condition problem using the finite element method. Examination of all possible parameters reveals the following: 1.…

Chemical Physics · Physics 2015-01-16 Xi Zhang , Yongli Huang , Zengsheng Ma , Chang Q Sun

We demonstrate that the Mpemba paradox arises intrinsically from the release rate of energy initially stored in the covalent H-O part of the O:H-O bond in water albeit experimental conditions. Generally, heating raises the energy of a…

Chemical Physics · Physics 2015-01-29 Xi Zhang , Yongli Huang , Zengsheng Ma , Chang Q Sun

The "Mpemba effect" is the name given to the assertion that hot water freezes quicker than cold water1 or, in a modern and more general form, that the system that is initially more distant from its equilibrium state comes to this state…

Chemical Physics · Physics 2025-08-08 Andrei A. Klimov , Alexei V. Finkelstein

The Mpemba effect occurs when a hot system cools faster than an initially colder one, when both are refrigerated in the same thermal reservoir. Using the custom built supercomputer Janus II, we study the Mpemba effect in spin glasses and…

The Mpemba effect, in which a hotter system cools faster than a colder one, remains one of the most intriguing anomalies in thermodynamics. Here, we investigate its microscopic origin within the framework of quantum resource theories and…

Quantum Physics · Physics 2026-04-17 Doruk Can Alyürük , Mahir H. Yeşiller , Vlatko Vedral , Onur Pusuluk

Under certain conditions, it takes a shorter time to cool a hot system than to cool the same system initiated at a lower temperature. This phenomenon - the "Mpemba Effect" - is well known in water, and has recently been observed in other…

Statistical Mechanics · Physics 2017-09-28 Zhiyue Lu , Oren Raz

Despite decades of research, the Mpemba Effect challenges scientists, prompting further investigation and refinement of existing hypotheses. This work uses optical tools such as thermography to analyze and study the Mpemba effect on drops.…

The Mpemba effect has initially been noticed in macroscopic systems -- namely that hot water can freeze faster than cold water -- but recently its extension to open quantum systems has attracted significant attention. This phenomenon can be…

Mesoscale and Nanoscale Physics · Physics 2025-04-08 Juliane Graf , Janine Splettstoesser , Juliette Monsel

An accurate experimental investigation on the Mpemba effect (that is, the freezing of initially hot water before cold one) is carried out, showing that in the adiabatic cooling of water a relevant role is played by supercooling as well as…

Chemical Physics · Physics 2009-11-13 S. Esposito , R. De Risi , L. Somma

The Mpemba effect is a counterintuitive physical phenomenon where a hot system cools faster than a warm one. In recent years, theoretical analyses of the Mpemba effect have been developed for microscopic systems and experimentally verified.…

Statistical Mechanics · Physics 2025-03-12 Tan Van Vu , Hisao Hayakawa

The so-called Mpemba effect, i.e. the observation that the warmer of two otherwise identical systems cools faster when both are refrigerated in the same thermal reservoir, is a hotly debated topic in condensed mater physics and statistical…

Materials Science · Physics 2019-09-11 A. Gijón , A. Lasanta , E. R. Hernández

We review the Mpemba effect, where intially hot water freezes faster than initially cold water. While the effect appears impossible at first sight, it has been seen in numerous experiments, was reported on by Aristotle, Francis Bacon, and…

History and Philosophy of Physics · Physics 2011-11-10 Monwhea Jeng

In classical thermodynamics, the Mpemba effect refers to the counterintuitive observation that hot water can freeze faster than cold water, manifesting as an anomalous crossing of dynamical trajectories. While analogues of this phenomenon…

Quantum Physics · Physics 2026-05-25 Zhilong Liu , Zehua Tian , Jieci Wang

An ancient and counterintuitive phenomenon know as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for…

When a hot system cools down faster than an equivalent cold one, it exhibits the Mpemba Effect. This counterintuitive phenomenon was observed in several systems including water, magnetic alloys and polymers. In most experiments the system…

Statistical Mechanics · Physics 2023-07-07 Gianluca Teza , Ran Yaacoby , Oren Raz

Under certain conditions, two samples of fluid at different initial temperatures present a counterintuitive behavior known as the Mpemba effect: it is the hotter system that cools sooner. Here, we show that the Mpemba effect is present in…

Soft Condensed Matter · Physics 2017-10-06 Antonio Lasanta , Francisco Vega Reyes , Antonio Prados , Andrés Santos

The Mpemba effect describes the situation in which a hot system cools faster than an identical copy that is initiated at a colder temperature. In many of the experimental observations of the effect, e.g. in water and clathrate hydrates, it…

Statistical Mechanics · Physics 2023-05-23 Roi Holtzman , Oren Raz

As the temperature of a cooling object decreases as it relaxes to thermal equilibrium, it is intuitively assumed that a hot object should take longer to cool than a warm one. Yet, some 2,300 years ago, Aristotle observed that "to cool hot…

Statistical Mechanics · Physics 2020-08-07 Avinash Kumar , John Bechhoefer

The Mpemba effect is a counter-intuitive relaxation phenomenon, where a system prepared at a hot temperature cools down faster than an identical system initiated at a cold temperature when both are quenched to an even colder bath. Such…

Statistical Mechanics · Physics 2019-07-03 Israel Klich , Oren Raz , Ori Hirschberg , Marija Vucelja

Water exhibits many unique properties compared to other liquids, with some of these explained and others remaining enigmatic. Among them, it was proposed and extensively debated that hot water would freeze faster than cold water. Numerous…

Chemical Physics · Physics 2025-12-02 James D. Brownridge , Matthieu Zinet , Paul Sotta , Francois Ganachaud
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