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A neutron scattering investigation of the magnetoelectric coupling in PbFe_{1/2}Nb_{1/2}O_{3} (PFN) has been undertaken. Ferroelectric order occurs below 400 K, as evidenced by the softening with temperature and subsequent recovery of the…

Materials Science · Physics 2018-07-20 C. Stock , S. R. Dunsiger , R. A. Mole , X. Li , H. Luo

The PbFe0.5Nb0.5O3 (PFN), a well-known A(B'1/2B"1/2)O3 type multiferroic was successfully synthesized in single phase by a single step solid state reaction method. The single phase PFN was characterized through XRD, microstructure through…

Materials Science · Physics 2015-01-08 Shidaling Matteppanavar , Basavaraj Angadi , Sudhindra Rayaprol

Neutron scattering techniques have been used to study the relaxor ferroelectric 0.68PbMg1/3Nb2/3O3-0.32PbTiO3 denoted in this paper as 0.68PMN-0.32PT. On cooling, these relaxor ferroelectrics have a long-range ordered ferroelectric phase…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , B. Roessli , R. A. Cowley , S. Kojima , S. G. Lushnikov

Experimental and theoretical studies of unusual polar, dielectric and magnetic properties of room temperature multiferroics, such as perovskites Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (PFN) and Pb(Fe$_{1/2}$Ta$_{1/2}$)O$_3$ (PFT), are very…

Relaxor-ferroelectrics display exceptional dielectric properties resulting from the underlying random dipolar fields induced by strong chemical inhomogeneity. An unusual structural aspect of relaxors is a skin-effect where the near-surface…

Strongly Correlated Electrons · Physics 2024-08-01 N. Giles-Donovan , A. D. Hillier , K. Ishida , B. V. Hampshire , S. R. Giblin , B. Roessli , P. M. Gehring , G. Xu , X. Li , H. Luo , S. Cochran , C. Stock

Combining our comprehensive investigations of polarization evolution, soft-mode by Raman scattering and microstructure by TEM, and the results reported in the literatures, we show that prototypical relaxor Pb(Mg1/3Nb2/3)O3 (PMN) is…

Materials Science · Physics 2013-01-17 Desheng Fu , Hiroki Taniguchi , Mitsuru Itoh , Shigeo Mori

We report on the single phase synthesis and room temperature structural characterization of PbFe0.67W0.33O3 (PFW) multiferroic. The PFW was synthesized by low temperature sintering, Columbite method. Analysis of powder XRD pattern exhibits…

Materials Science · Physics 2015-01-07 Shidaling Matteppanavar , Basavaraj Angadi , Sudhindra Rayapro

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We review some of the current research on two of the ultra-high piezoelectric relaxors Pb(Mg1/3Nb2/3)O3 (PMN) and Pb(Zn1/3Nb2/3)O3 (PZN). The discovery of a monoclinic phase in Pb(Zr1-xTix)O3 (PZT) in 1999 by Noheda et al. forced a…

Materials Science · Physics 2007-05-23 G. Shirane , P. M. Gehring

Neutron scattering measurements of the lowest-energy TO phonons in the relaxor Pb(Mg1/3Nb2/3)O3 (PMN) are reported for 10<=T<=750 K. The soft mode, which is overdamped by the polar nanoregions below the Burns temperature T_d = 620 K,…

Materials Science · Physics 2009-11-07 S. Wakimoto , C. Stock , R. J. Birgeneau , Z. -G. Ye , W. Chen , W. J. L. Buyers , P. M. Gehring , G. Shirane

The correlation between static magnetoelectric coupling and magnetic structure was investigated in $TbMn_{0.98}Fe_{0.02}O_{3}$ with magnetic field up to 8 T and down to 2 K. Single-crystal neutron diffraction experiments reveal a…

In this paper the structural, magnetic, and dielectric properties of langasite compound Pb$_3$TeMn$_3$P$_2$O$_{14}$ have been investigated as a candidate of short-range magnetic correlations driven development of dielectric anomaly above…

Materials Science · Physics 2021-07-01 Rafikul Ali Saha , Desheng Fu , Mitsuru Itoh , Sugata Ray

Magnetic and dielectric properties on a polycrystalline La0.7Bi0.3CrO3 have been investigated. A canted antiferromagnetic (CAF) phase transition giving weak ferromagnetism at TN = 230K has been observed. M-H at 10K shows non-saturating…

Strongly Correlated Electrons · Physics 2014-03-17 Aga Shahee , Dhirendra kumar , N. P. Lalla

Magnetoelectric systems offer potential for device applications exploiting coupled states between electric and magnetic properties. Among magnetoelectric materials, \FNO has attracted special attention because of its pronounced dielectric…

We report a giant linear magnetoelectric coupling in strained BiMnO3 thin films in which the disorder associated with an islanded morphology gives rise to extrinsic relaxor ferroelectricity that is not present in bulk centrosymmetric…

Materials Science · Physics 2016-04-13 Patrick R. Mickel , Hyoungjeen Jeen , Pradeep Kumar , Amlan Biswas , Arthur F. Hebard

Hexagonal rare-earth ferrite RFeO$_3$ family represents a unique class of multiferroics exhibiting weak ferromagnetism, and a strong coupling between magnetism and structural trimerization is predicted. However, the hexagonal structure for…

The microstructure and phase transition in relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN) and its solid solution with PbTiO3 (PT), PMN-xPT, remain to be one of the most puzzling issues of solid state science. In the present work we have…

Materials Science · Physics 2009-11-07 Z. -G. Ye , Y. Bing , J. Gao , A. A. Bokov , P. Stephens , B. Noheda , G. Shirane

The (H,T)-phase diagram of the multiferroic perovskite TbMnO$_3$ was studied by high-resolution thermal expansion $\alpha(T)$ and magnetostriction $\Delta L(H)/L$ measurements. Below $T_{N}\simeq 42$ K, TbMnO$_3$ shows antiferromagnetic…

Strongly Correlated Electrons · Physics 2009-11-13 D. Meier , N. Aliouane , D. N. Argyriou , J. A. Mydosh , T. Lorenz

The magnetic structures and the magnetic phase transitions in the Mn-doped orthoferrite TbFeO$_3$ studied using neutron powder diffraction are reported. Magnetic phase transitions are identified at $T^\mathrm{Fe/Mn}_N \approx$ 295~K where a…

Strongly Correlated Electrons · Physics 2016-02-17 Harikrishnan S. Nair , Tapan Chatterji , C. M. N. Kumar , T. Hansen , Hariharan Nhalil , Suja Elizabeth , A. M. Strydom

Synchrotron x-ray scattering studies of anti-ferroelectric nanoregions (AFR) as fluctuations, which give rise to 1/2(hk0) superlattice reflections (alpha spots), were systematically performed in Pb(Mg1/3Nb2/3)O3 (PMN) ferroelectric relaxor.…

Materials Science · Physics 2007-05-23 A. Tkachuk , Haydn Chen
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