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Determining the level of chemical complexity within dense starless and gravitationally bound prestellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We…

Astrophysics of Galaxies · Physics 2021-04-28 Samantha Scibelli , Yancy Shirley , Anton Vasyunin , Ralf Launhardt

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry…

Observational studies reveal that complex organic molecules (COMs) can be found in various objects associated with different star formation stages. The identification of COMs in prestellar cores, i.e., cold environments in which thermally…

Solar and Stellar Astrophysics · Physics 2017-06-28 Gleb Fedoseev , Ko-Ju Chuang , Sergio Ioppolo , Danna Qasim , Ewine F. van Dishoeck , Harold Linnartz

We report on a systematic search for oxygen-bearing Complex Organic Molecules (COMs) in the Solar-like protostellar shock region L1157-B1, as part of the IRAM Large Program "Astrochemical Surveys At IRAM" (ASAI). Several COMs are…

Astrophysics of Galaxies · Physics 2017-05-31 B. Lefloch , C. Ceccarelli , C. Codella , C. Favre , L. Podio , C. Vastel , S. Viti , R. Bachiller

Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…

Astrophysics of Galaxies · Physics 2024-01-09 Rafael Martín-Doménech , Alexander DelFranco , Karin I. Öberg , Mahesh Rajappan

Massive young stellar objects (MYSOs) with hot cores are classic sources of complex organic molecules. The origins of these molecules in such sources, as well as the small- and large-scale differentiation between nitrogen- and…

Solar and Stellar Astrophysics · Physics 2015-03-25 Edith C. Fayolle , Karin I. Öberg , Robin T. Garrod , Ewine F. van Dishoeck , Suzanne E. Bisschop

Complex organic molecules (COMs) detected in the gas phase are thought to be mostly formed on icy grains, but no unambiguous detection of icy COMs larger than CH3OH has been reported so far. Exploring this matter in more detail has become…

Up to now, mostly relatively simple molecules have been detected in interstellar diffuse molecular clouds in our galaxy, but more complex species have been reported in the diffuse/translucent medium of a z = 0.89 spiral galaxy. We aim at…

Astrophysics of Galaxies · Physics 2017-09-20 V. Thiel , A. Belloche , K. M. Menten , R. T. Garrod , H. S. P. Müller

Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…

Astrophysics of Galaxies · Physics 2025-12-10 Guillermo M. Muñoz Caro , Héctor Carrascosa de Lucas , Rafael Martín-Doménech

We present the results of chemical modeling of complex organic molecules (COMs) under conditions typical for prestellar cores. We utilize an advanced gas-grain astrochemical model with updated gas-phase chemistry, with a multilayer approach…

Astrophysics of Galaxies · Physics 2017-06-28 Anton I. Vasyunin , Paola Caselli , François Dulieu , Izaskun Jiménez-Serra

The interstellar medium is characterized by a rich and diverse chemistry. Many of its complex organic molecules are proposed to form through radical chemistry in icy grain mantles. Radicals form readily when interstellar ices (composed of…

Astrophysics of Galaxies · Physics 2016-09-13 Karin I. Oberg

Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes.…

Astrophysics · Physics 2009-11-13 Robin T. Garrod , Susanna L. Widicus Weaver , Eric Herbst

During the process of star formation, the dense gas undergoes significant chemical evolution leading to the emergence of a rich variety of molecules associated with hot cores and hot corinos. However, the physical and chemical conditions…

Astrophysics of Galaxies · Physics 2024-06-19 Laure Bouscasse , Timea Csengeri , Friedrich Wyrowski , K. M. Menten , S. Bontemps

The chemical evolution in star forming regions is driven by the interplay between gas and ice mantles. Identifying the ice compositions at the early stage of star formation thus provides constraints on the chemical processes inaccessible…

Astrophysics of Galaxies · Physics 2026-02-06 Andrew M. Turner , Yao-Lun Yang , Rachel Gross , Nami Sakai , Ralf I. Kaiser

Massive stars play a pivotal role in shaping their galactic surroundings due to their high luminosity and intense ionizing radiation. However, the precise mechanisms governing the formation of massive stars remain elusive. Complex organic…

Complex organic molecules (COMs) have been observed in comets, hot cores and cold dense regions of the interstellar medium. It is generally accepted that these COMs form on icy dust grain through the recombination reaction of radicals…

Solar and Stellar Astrophysics · Physics 2018-09-12 K. -J. Chuang

(Abridged) We aim to enlarge the number of known hot corinos and carry out a first comparative study with hot cores. The ultimate goal is to understand whether complex organic molecules form in the gas phase or on grain surfaces, and what…

Hot corinos are compact regions around solar-mass protostellar objects that are very rich in interstellar complex organic molecules (iCOMs). They are believed to represent the very early phases of our Solar System's birth, which was very…

During massive star formation, dense gas undergoes chemical evolution, producing both simple and complex organic molecules (COMs) characteristic of hot molecular cores. How this evolution depends on protostellar physical properties remains…

Astrophysics of Galaxies · Physics 2025-10-31 D. Gigli , P. Gorai , C. Y. Law , J. C. Tan , M. Bonfand , T. Rahman , Y. Zhang , K. Taniguchi , R. Fedriani , Z. Telkamp , V. Rosero , G. Cosentino

Orion KL is one of the prime templates of astrochemical and prebiotic chemical studies. We wish to explore more organic molecules with increasing complexity in this region. In particular, we have searched for one of the most complex organic…

Solar and Stellar Astrophysics · Physics 2019-02-13 Yaping Peng , V. M. Rivilla , Li Zhang , J. X. Ge , Bing Zhou