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Introduction: molecular geometry, the three-dimensional arrangement of atoms within a molecule, is fundamental to understanding chemical reactivity, physical properties, and biological activity. The prevailing models used to describe…

General Physics · Physics 2026-05-12 Sebastian Ali Sacasa-Cespedes

We present a method based on graph theory for evaluation of the inelastic propensity rules for molecules exhibiting complete destructive quantum interference in their elastic transmission. The method uses an extended adjacency matrix…

Mesoscale and Nanoscale Physics · Physics 2017-05-11 Rudolf Sýkora , Tomáš Novotný

We find that energy surfaces of more than two atoms or molecules interacting via dipole-dipole po- tentials generically possess conical intersections (CIs). Typically only few atoms participate strongly in such an intersection. For the…

Atomic Physics · Physics 2013-05-29 S. Wüster , A. Eisfeld , J. M. Rost

We consider a simple model for the assembly of chiral molecules in two dimensions driven by maximization of the contact area. We derive a macroscopic model described by a parameter taking nine possible values corresponding to the possible…

Mathematical Physics · Physics 2015-12-04 Andrea Braides , Adriana Garroni , Mariapia Palombaro

Molecular crystals possess a highly complex crystallographic landscape which in many cases results in the experimental observation of multiple crystal structures for the same compound. Accurate results can often be obtained for such systems…

Chemical Physics · Physics 2025-12-19 Alexander List , A. Daniel Boese , Johannes Hoja

The Glauber theory description of particle- and nucleus-crystal Coulomb interactions at high-energy is developed. The allowance for the lattice thermal vibrations is shown to produce strong absorption effect which is of prime importance for…

High Energy Physics - Phenomenology · Physics 2009-11-10 V. R. Zoller

New interlayer intermolecular potential model was proposed and it represented ``ABAB'' staking of graphite. Hydrogen atom sputtering on graphite surface was investigated using molecular dynamics simulation. In the initial short time period,…

Materials Science · Physics 2007-11-26 Atsushi Ito , Hiroaki Nakamura

We view molecular optimization as a graph-to-graph translation problem. The goal is to learn to map from one molecular graph to another with better properties based on an available corpus of paired molecules. Since molecules can be…

Machine Learning · Computer Science 2019-01-30 Wengong Jin , Kevin Yang , Regina Barzilay , Tommi Jaakkola

We extend previous work on injectivity in chemical reaction networks to general interaction networks. Matrix- and graph-theoretic conditions for injectivity of these systems are presented. A particular signed, directed, labelled, bipartite…

Dynamical Systems · Mathematics 2009-10-15 Murad Banaji , Gheorghe Craciun

Geometric, topological and graph theory modeling and analysis of biomolecules are of essential importance in the conceptualization of molecular structure, function, dynamics, and transport. On the one hand, geometric modeling provides…

Biomolecules · Quantitative Biology 2016-12-07 Kelin Xia , Guo-Wei Wei

Multiparticle systems on complicated metric graphs might have many applications in physics, biology and social life. But the corresponding science still does not exist. Here we start it with simplest examples where there is quadratic…

Mathematical Physics · Physics 2023-06-16 V. A. Malyshev , A. A. Zamyatin

Very often it is an implied paradigm of molecular magnetism that magnetic molecules in a crystal interact so weakly that measurements of dc magnetic observables reflect ensemble properties of single molecules. But the number of cases where…

Strongly Correlated Electrons · Physics 2016-03-02 J. Schnack

In this paper, we present a survey of the use of graph theoretical techniques in Biology. In particular, we discuss recent work on identifying and modelling the structure of bio-molecular networks, as well as the application of centrality…

Molecular Networks · Quantitative Biology 2007-05-23 Oliver Mason , Mark Verwoerd

Graph generation techniques are increasingly being adopted for drug discovery. Previous graph generation approaches have utilized relatively small molecular building blocks such as atoms or simple cycles, limiting their effectiveness to…

Machine Learning · Computer Science 2020-04-21 Wengong Jin , Regina Barzilay , Tommi Jaakkola

There are several applications in computational biophysics which require the optimization of discrete interacting states; e.g., amino acid titration states, ligand oxidation states, or discrete rotamer angles. Such optimization can be very…

Biomolecules · Quantitative Biology 2016-05-17 Emilie Purvine , Kyle Monson , Elizabeth Jurrus , Keith Star , Nathan A. Baker

A macroscopic theory for the molecular or Casimir interaction of dielectric materials with arbitrarily shaped surfaces is developed. The interaction is generated by the quantum and thermal fluctuations of the electromagnetic field which…

Statistical Mechanics · Physics 2009-11-10 Rauno Buescher , Thorsten Emig

Current experimental and theoretical studies on the effect of intermolecular interactions on molecular conduction appear to be in conflict with each other. In particular, some experimental results, e.g., the observation of 2-dimensional…

Mesoscale and Nanoscale Physics · Physics 2007-07-23 A. Landau , L. Kronik , A. Nitzan

We present a hierarchical neural message passing architecture for learning on molecular graphs. Our model takes in two complementary graph representations: the raw molecular graph representation and its associated junction tree, where nodes…

Machine Learning · Computer Science 2020-06-23 Matthias Fey , Jan-Gin Yuen , Frank Weichert

The interaction energy between a water molecule and graphitic structured clusters terminated by hydrogen atoms is analyzed by ab initio methods and decomposed into electrostatic, induction, Pauli repulsion, and correlation energy…

Computational Physics · Physics 2008-01-21 D. J. Wallace Geldart , I. Wayan Sudiarta , Glen Lesins , Petr Chylek

Accurate calculations of molecular crystals are crucial for drug design and crystal engineering. However, periodic high-level density functional calculations using hybrid functionals are often prohibitively expensive for relevant systems.…

Chemical Physics · Physics 2024-01-23 Johannes Hoja , Alexander List , A. Daniel Boese
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