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The fundamental understanding of water confined in porous coordination polymers (PCPs) is significantly important not only for their applications such as gas storage and separation, but also for exploring the confinement effects in the…

Graphene nanochannels are relevant for their possible applications, as in water purification, and for the challenge of understanding how they change the properties of confined liquids. Here, we use all-atom molecular dynamics simulations to…

Soft Condensed Matter · Physics 2021-03-25 Carles Calero , Giancarlo Franzese

In this study, we present a detailed analysis of the squeeze-out dynamics of nanoconfined water confined between two hydrophilic surfaces measured by small-amplitude dynamic atomic force microscopy (AFM). Explicitly considering the…

Soft Condensed Matter · Physics 2015-10-28 Shah H. Khan , Peter M. Hoffmann

Multilayered graphene-based nanoporous membranes with electrolyte incorporated between individual sheets is a unique nano-heterostructure system in which nanoconfined electrons in graphene and ions confined in between sheets are intimately…

Mesoscale and Nanoscale Physics · Physics 2020-06-30 Jing Xiao , Hualin Zhan , Zaiquan Xu , Xiao Wang , Ke Zhang , Zhiyuan Xiong , George P. Simon , Zhe Liu , Dan Li

The fundamental understanding of crystallization, in terms of microscopic kinetic and thermodynamic details, remains a key challenge in the physical sciences. Here, by using in situ graphene liquid cell transmission electron microscopy, we…

In this paper we present a review on our recent experimental investigations into the phase behavior of the deeply cooled water confined in a nanoporous silica material, MCM-41, with elastic neutron scattering technique. Under such strong…

Soft Condensed Matter · Physics 2016-12-13 Zhe Wang , Kanae Ito , Sow-Hsin Chen

Coarse grained molecular dynamics simulations are presented in which the sensitivity of the ice nucleation rate to the hydrophilicity of a graphene nanoflake is investigated. We find that an optimal interaction strength for promoting ice…

Materials Science · Physics 2015-06-01 Stephen J. Cox , Shawn M. Kathmann , Ben Slater , Angelos Michaelides

The issue of ice accumulation at low-temperature circumstances causes multiple problems and serious damages in many civil infrastructures which substantially influence human daily life. However, despite the significant consideration in…

Chemical Physics · Physics 2020-11-24 Amir Afshar , Dong Meng

Graphene supported on a substrate in contact with water underpins a wide range of processes and technologies, yet its wettability remains controversial. Understanding how substrate charges and graphene's properties influence water…

Chemical Physics · Physics 2025-11-11 Yongkang Wang , Yair Litman , Minhaeng Cho , Stephen Cox , Mischa Bonn

Despite relevance to disparate areas such as cloud microphysics and tribology, major gaps in the understanding of the structures and phase transitions of low-dimensional water ice remain. Here we report a first principles study of confined…

Water inside the low dimensional carbon structures has been considered seriously owing to fundamental interest in its flow and structures as well as its practical impact. Recently, the anomalous perfect penetration of water through graphene…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Danil W. Boukhvalov , Mikhail I. Katsnelson , Young-Woo Son

In this work, the dielectric behavior of water inside charged nanoslit of graphene is studied to analized the water molecules under electrical confinement; through polarizing the nanoslit of graphene, creating an electric field inside the…

Soft Condensed Matter · Physics 2022-08-12 Raúl Fuentes-Azcatl , José Rafael Bordin , Marcia C. Barbosa

The properties of liquid water are known to change drastically in confined geometries. A most interesting and intriguing phenomenon is that the diffusion of water is found to be strongly enhanced by the proximity of a hydrophobic confining…

Soft Condensed Matter · Physics 2024-12-06 Lorenzo Agosta , Kersti Hermansson , Mikhail Dzugutov

Water is essential for almost every aspect of life on our planet and, unsurprisingly, its properties have been studied in great detail. However, disproportionately little remains known about the electrical properties of interfacial and…

We have explored a model for adsorption of water into slit-like nanochannels with two walls chemically modified by grafted polymer layers forming brushes. A version of density functional method is used as theoretical tools. The water-like…

Soft Condensed Matter · Physics 2020-05-26 V. M. Trejos , M. Aguilar , S. Sokołowski , O. Pizio

The non-wetting phenomena of water on certain solid surfaces have been under intensive study for decades, but the nature of hydrophobic/water interfaces remains controversial. Here a water/graphite interface is investigated with…

Soft Condensed Matter · Physics 2012-04-02 Ing-Shouh Hwang , Chih-Wen Yang , Yi-Hsien Lu

The wetting properties of graphene have proven controversial and difficult to assess. The presence of a graphene layer on top of a substrate does not significantly change the wetting properties of the solid substrate, suggesting that a…

Soft Condensed Matter · Physics 2017-02-10 Bijoyendra Bera , Noushine Shahidzadeh , Himanshu Mishra , Daniel Bonn

This work describes the behaviour of water molecules in 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid under nanoconfinement between graphene sheets. By means of molecular dynamics simulations, an adsorption of water molecules…

Through molecular dynamics simulations considering thermal vibration of surface atoms, ionic behaviors in concentrated NaCl solutions confined between discretely charged silicon surfaces have been investigated. The electric double layer…

Chemical Physics · Physics 2017-04-06 Yinghua Qiu , Jian Ma , Yunfei Chen

Molecular Dynamics simulations of water molecules in nanometre sized cylindrical channels connecting two reservoirs show that the permeation of water is very sensitive to the channel radius and to electric polarization of the embedding…

Soft Condensed Matter · Physics 2009-11-07 Rosalind Allen , Simone Melchionna , Jean-Pierre Hansen