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The magnetic anisotropy and exchange coupling between spins localized at the positions of 3d transition metal atoms forming two-dimensional metal-organic coordination networks (MOCNs) grown on the Au(111) metal surface are studied. In…

Metallic ferromagnets with strongly interacting electrons often exhibit remarkable electronic phases such as ferromagnetic superconductivity, complex spin textures, and nontrivial topology. In this report, we discuss the synthesis of a…

Multiferroicity and magnetodielectric coupling in metal-organic-frameworks (MOFs) is rare and so far restricted mainly to formate-based systems with perovskite structure. In the course of this work we designed a tetragonal framework…

Materials Science · Physics 2017-10-31 Tathamay Basu , A. Jesche , B. Bredenkotter , M. Grzywa , D. Denysenko , D. Volkmer , A. Loidl , S. Krohns

The electronic and magnetic properties of Mn coordinated to 1,2,4,5-tetracyanobenzene (TCNB) in the Mn-TCNB 2D metal-ligand networks have been investigated by combining scanning tunneling microscopy and X-ray magnetic circular dichroism…

We study the magnetic and electronic properties of Ni-intercalated NbSe$_2$.We calculate the magnetic exchanges of Ni$_x$NbSe$_2$ ($x = 1/3, 1/4,$ and $1$) and find that the out-of-plane magnetic coupling depends on the Ni connectivity: it…

Materials Science · Physics 2025-11-20 Xujia Gong , Amar Fakhredine , Carmine Autieri

Spin coupling between magnetic metal atoms and organic radicals plays a pivotal role in high-performance magnetic materials. The complex interaction involving multi-spin centers in bulk materials makes it challenging to study spin coupling…

The spin-helical surface states in three-dimensional topological insulator (TI), such as Bi2Se3, are predicted to have superior efficiency in converting charge current into spin polarization. This property is said to be responsible for the…

Materials Science · Physics 2016-08-03 Jia Zhang , Julian P. Velev , Xiaoqian Dang , Evgeny Y. Tsymbal

The binary intermetallic materials, $M_3$Sn$_2$ ($M$ = 3d transition metal) present a new class of strongly correlated systems that naturally allows for the interplay of magnetism and metallicity. Using first principles calculations we…

Strongly Correlated Electrons · Physics 2020-07-10 Santu Baidya , Aabhaas Vineet Mallik , Subhro Bhattacharjee , Tanusri Saha-Dasgupta

The macroscopic magnetic characterization of the Mn(II) - nitronyl nitroxide free radical chain (Mn(hfac)2(R)-3MLNN) evidenced its transition from a 1-dimensional behavior of ferrimagnetic chains to a 3-dimensional ferromagnetic long range…

Materials Science · Physics 2008-09-12 E. Lhotel , V. Simonet , E. Ressouche , B. Canals , D. B. Amabilino , C. Sporer , D. Luneau , J. Veciana , C. Paulsen

Density-functional calculations are carried out to investigate incommensurate magnetic structures and ferroelectric polarization in newly discovered multiferroic material MnI$_2$. The exchange interactions among local moments on Mn are…

Strongly Correlated Electrons · Physics 2013-05-30 Xianxin Wu , Yingxiang Cai , Qing Xie , Hongming Weng , Heng Fan , Jiangping Hu

Cross-correlation between magnetism and dielectric is expected to offer novel emergent phenomena. Here, magnetic excitations in the organic donor-acceptor spin-chain system, TTF-BA, with a ferroelectric ground state is investigated by…

Materials Science · Physics 2020-12-09 K. Sunami , Y. Sakai , R. Takehara , H. Adachi , K. Miyagawa , S. Horiuchi , K. Kanoda

Because of large spatial separation of the Mn atoms in Heusler alloys the Mn 3d states belonging to different atoms do not overlap considerably. Therefore an indirect exchange interaction between Mn atoms should play a crucial role in the…

Materials Science · Physics 2009-11-13 E. Sasioglu , L. M. Sandratskii , P. Bruno

Magnetism in Ni-Mn-Z (Z = Ga,In,Sn,Sb) Heusler alloys has so far been predominantly attributed to Rudermann-Kittel-Kasuya-Yoshida type interactions between Mn atoms. We investigate magnetic interactions in one such alloy,…

Materials Science · Physics 2015-06-15 K. R. Priolkar , P. A. Bhobe , D. N. Lobo , S. W. D'Souza , S. R. Barman , A. Chakrabarti , S. Emura

To explore how anion substitution modifies the existing magnetism in strongly correlated oxides, we investigate local electronic states and magnetic ordering in nickel oxide (NiO) induced by substituting oxygen (O) with nitrogen (N). Each N…

We investigate the electronic structure of Chromium Nitride (CrN) across the first-order magneto-structural transition at T_N ~ 286 K. Resonant photoemission spectroscopy shows a gap in the 3d partial density of states at the Fermi level…

Using spin density functional theory we have carried out a comparative study of chemical bonding and magnetism in Fe_4N, Fe_3N and Fe_2N. All of these compounds form close packed Fe lattices, while N occupies octahedral interstitial…

Materials Science · Physics 2009-10-31 M. Sifkovits , H. Smolinski , S. Hellwig , W. Weber

First-principles calculations are used to investigate the magnetic properties of Ti$_{1-x}$Cr$_{x}$N solid solutions. We show that the magnetic interactions between Cr spins that favour antiferromagnetism in CrN is changed upon alloying…

Materials Science · Physics 2010-12-14 B. Alling

Contrary to prior calculations, the Ni-rich ordered structures of the Cr-Ni alloy system are found to be antiferromagnetic under semi-local density-functional theory. The optimization of local magnetic moments significantly increases the…

Materials Science · Physics 2023-08-23 Flynn Walsh , Robert O. Ritchie , Mark Asta

Altermagnets represent a promising class of magnetic materials owing to their distinctive spin-split band structures in the absence of net magnetization. Here, we present a first-principles investigation of altermagnetism in magnetically…

Materials Science · Physics 2026-01-07 Ezra Day-Roberts , Huan Wu , Onur Erten , A. S Botana

Achieving long-range ferrimagnetic order in purely organic systems remains a major challenge in molecular magnetism. Here we report the synthesis and characterization of heterospin-coupling motifs, formed by covalently linking spin-1/2 and…

Mesoscale and Nanoscale Physics · Physics 2026-04-10 Elia Turco , Fupeng Wu , Annika Bernhardt , Nils Krane , Ji Ma , Roman Fasel , Michal Juriček , Xinliang Feng , Pascal Ruffieux
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