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We study, using Monte Carlo simulations, the interaction between charged colloidal particles confined to the air-water interface. The dependence of force on ionic strength and counterion valence is explored. For 1:1 electrolyte, we find…

Soft Condensed Matter · Physics 2018-02-05 Matheus Girotto , Alexandre P. dos Santos , Yan Levin

The bare Coulomb interaction between two like-charges is repulsive. When these charges are immersed in an electrolyte, the thermal fluctuations of the ions turn the bare Coulomb interaction into an effective interaction between the two…

Statistical Mechanics · Physics 2023-03-15 Gabriel Tellez

This study investigates the interplay between Strong Coupling (SC) attraction and hydration repulsion in nanoconfined water between like-charged phospholipid layers. It challenges the assumption that SC attraction requires multivalent…

The physics of an electron solid, held on a cryogenic liquid surface by a pressing electric field, is examined in a low-density regime that has not been explored before. We consider the effect of the pressing field in distorting the surface…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Masudul Haque , Indranil Paul , Sergey Pankov

We present a new analytical approach to the strong electrostatic coupling regime (SC), that can be achieved equivalently at low temperatures, high charges, low dielectric permittivity etc. Two geometries are analyzed in detail: one charged…

Statistical Mechanics · Physics 2015-06-03 L. Šamaj , E. Trizac

We probe the electrostatic mechanism driving adsorption of polyelectrolytes onto like-charged membranes upon the addition of tri- and tetravalent counterions to a bathing monovalent salt solution. We develop a one-loop-dressed strong…

Soft Condensed Matter · Physics 2019-10-02 Sahin Buyukdagli , Rudolf Podgornik

The behavior of polyelectrolytes between charged surfaces immersed in semi-dilute solutions is investigated theoretically. A continuum mean field approach is used for calculating numerically concentration profiles between two electrodes…

Soft Condensed Matter · Physics 2007-05-23 I. Borukhov , D. Andelman , H. Orland

In the study of colloidal, biological and electrochemical systems, it is customary to treat surfaces, macromolecules and electrodes as homogeneously charged. This simplified approach is proven successful in most cases, but fails to describe…

Soft Condensed Matter · Physics 2022-08-04 Ram M. Adar , David Andelman , Haim Diamant

Recent progress in the understanding of the effect of electrostatics in soft matter is presented. A vast amount of materials contains ions ranging from the molecular scale (e.g., electrolyte) to the meso/macroscopic one (e.g., charged…

Soft Condensed Matter · Physics 2008-12-01 Rene Messina

The sliding motion of aqueous droplets on hydrohobic surfaces leads to charge separation at the trailing edge, with implications from triple-line friction to hydrovoltaic energy generation. Charges deposited on the solid surface have been…

Soft Condensed Matter · Physics 2025-09-12 Zouhir Benrahla , Tristan Saide , Louis Burnaz , Emilie Verneuil , Simon Gravelle , Jean Comtet

The contact value theorem was originally derived for Coulomb fluids of mobile charged particles in thermal equilibrium, in the presence of interfaces carrying a {\em uniform} surface charge density and in the absence of dielectric…

Statistical Mechanics · Physics 2025-03-03 Ladislav Šamaj

In this paper, we theoretically study the electrostatic interaction between a pair of identical colloids with constant surface potentials sitting in close vicinity of each other at a fluid interface. By employing a simplified yet reasonable…

Soft Condensed Matter · Physics 2020-07-29 Rick Bebon , Arghya Majee

The interaction of charges in dielectric materials is screened by the dielectric constant of the bulk dielectric. In dielectric theories, screening is assigned to the surface charge appearing from preferential orientations of dipoles along…

Soft Condensed Matter · Physics 2019-09-04 Salman Seyedi , Daniel R. Martin , Dmitry V. Matyushov

The electrostatic Schwinger-Dyson equations are derived and solved for an electrolyte mixture composed of mono- and multivalent ions confined to a negatively charged nanoslit. The closure of these equations is based on an asymmetric…

Soft Condensed Matter · Physics 2020-01-06 Sahin Buyukdagli

Screening of a strongly charged macroion by oppositely charged colloidal particles, micelles, or short polyelectrolytes is considered. Due to strong lateral repulsion such multivalent counterions form a strongly correlated liquid at the…

Soft Condensed Matter · Physics 2009-10-31 T. T. Nguyen , A. Yu. Grosberg , B. I. Shklovskii

We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

Soft Condensed Matter · Physics 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

Electric double layers (EDL) with counterions only, say electrons with the elementary charge $-e$, in thermal equilibrium at the inverse temperature $\beta$ are considered. In particular, we study the effect of the surface charge modulation…

Statistical Mechanics · Physics 2022-07-26 Ladislav Šamaj

Randomly charged net-neutral dielectric slabs are shown to interact across a featureless dielectric continuum with long-range electrostatic forces that scale with the statistical variance of their quenched random charge distribution and…

Soft Condensed Matter · Physics 2015-06-05 Vahid Rezvani , Jalal Sarabadani , Ali Naji , Rudolf Podgornik

We explore interactions between equally charged surfaces, in the presence of simple salt and either neutral or monovalently charged polyampholytes. We consider the possibility of using these charged polymers as crude models of ion clusters.…

Soft Condensed Matter · Physics 2026-03-19 David Ribar , Clifford E Woodward , Jan Forsman

We explore, using the recently developed efficient Monte Carlo simulation method, the interaction of an anionic polyelectrolyte solution with a like-charged dielectric surface. In addition to polyions, the solution also contains salt with…

Soft Condensed Matter · Physics 2018-01-12 Alexandre P. dos Santos , Matheus Girotto , Yan Levin