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We present a study of the elemental depletion in the interstellar medium. We combined the results of a Galatic model describing the gas physical conditions during the formation of dense cores with a full-gas-grain chemical model. During the…

Astrophysics of Galaxies · Physics 2020-07-29 V. Wakelam , W. Iqbal , J. -P. Melisse , P. Gratier , M. Ruaud , I. Bonnell

We investigate the effect of pressure, temperature and acidity on the composition of water-rich carbon-bearing fluids at thermodynamic conditions that correspond to the Earth's deep Crust and Upper Mantle. Our first-principles molecular…

Chemical Physics · Physics 2020-06-24 Riccardo Dettori , Davide Donadio

The chemical differentiation of seven COMs in the extended region around Sgr B2 has been observed: CH$_2$OHCHO, CH$_3$OCHO, t-HCOOH, C$_2$H$_5$OH, and CH$_3$NH$_2$ were detected both in the extended region and near the hot cores Sgr B2(N)…

Astrophysics of Galaxies · Physics 2021-04-14 Yao Wang , Fujun Du , Dmitry Semenov , Hongchi Wang , Juan Li

We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…

Astrophysics of Galaxies · Physics 2024-08-14 Germán Molpeceres , Kenji Furuya , Yuri Aikawa

Cold dense cores are unique among the structures found in the interstellar medium (ISM), as they harbor a rich chemical inventory, including complex organic molecules (COMs), which will be inherited by future evolutionary stages. These…

Astrophysics of Galaxies · Physics 2025-04-28 S. Maitrey , Liton Majumdar , Varun Manilal , Baibhav Srivastava , Prathap Rayalacheruvu , Karen Willacy , Eric Herbst

Complex organic molecules (COMs) have been observed towards several low-mass young stellar objects (LYSOs). Small and heterogeneous samples have so far precluded conclusions on typical COM abundances, as well as the origin(s) of abundance…

Solar and Stellar Astrophysics · Physics 2017-06-21 Jennifer B. Bergner , Karin I. Öberg , Robin T. Garrod , Dawn M. Graninger

Simple and complex organic molecules (COMs) are observed along different phases of star and planet formation and have been successfully identified in prestellar environments such as dark and translucent clouds. Yet the picture of organic…

Carbon containing molecules in cold molecular clouds show various levels of isotopic fractionation through multiple observations. To understand such effects, we have developed a new gas-grain chemical model with updated 13C fractionation…

Astrophysics of Galaxies · Physics 2020-10-07 Jean-Christophe Loison , Valentine Wakelam , Pierre Gratier , Kevin M. Hickson

Warm cores (or hot corinos) around low-mass protostellar objects show a rich chemistry with strong spatial variations. This chemistry is generally attributed to the sublimation of icy mantles on dust grains initiated by the warming effect…

Solar and Stellar Astrophysics · Physics 2015-05-19 Zainab Awad , Serena Viti , Mark P. Collings , David A. Williams

Using the high angular resolution provided by the ALMA interferometre we want to resolve the COM emission in the hot molecular core Sagittarius B2(N1) and thereby shed light on the desorption process of Complex Organic Molecules (COMs) in…

Astrophysics of Galaxies · Physics 2022-09-21 Laura A. Busch , Arnaud Belloche , Robin T. Garrod , Holger S. P. Müller , Karl M. Menten

We have performed new laboratory experiments which gave us the possibility to obtain an estimate of the amount of carbon chain oxides (namely C3O2, C2O, and C3O) formed after irradiation (with 200 keV protons) of pure CO ice, at 16 K. The…

Astrophysics · Physics 2009-11-13 M. E. Palumbo , P. Leto , C. Siringo , C. Trigilio

It is currently assumed that infrared dark clouds (IRDCs) represent the earliest evolutionary stages of high-mass stars ($>$ 8 M$_{\odot}$). Submillimeter and millimeter-wave studies performed over the past 15 years show that IRDCs possess…

Solar and Stellar Astrophysics · Physics 2015-06-17 T. Vasyunina , A. I. Vasyunin , E. Herbst , H. Linz , M. Voronkov , T. Britton , I. Zinchenko , F. Schuller

Under cold conditions in dense cores, gas-phase molecules and atoms are depleted from the gas-phase to the surface of interstellar grains. Considering the time scales and physical conditions within these cores, a portion of these molecules…

Astrophysics of Galaxies · Physics 2021-08-11 V. Wakelam , E. Dartois , M. Chabot , S. Spezzano , D. Navarro-Almaida , J. -C. Loison , A. Fuente

Recent astronomical observations have shown that interstellar complex organic molecules (COMs) exist even in cold environments ($\sim$10 K), while various interstellar COMs have conventionally been detected in the hot gas ($\gtrsim$ 100 K)…

Astrophysics of Galaxies · Physics 2023-08-11 Yu Komatsu , Kenji Furuya

Ice mantles on dust grains play a central role in astrochemistry. Water and complex organic molecules (COMs) are thought to first form on the ice mantles and subsequently are released into the gas phase due to star formation activity.…

Astrophysics of Galaxies · Physics 2020-03-11 Thiem Hoang , Le Ngoc Tram

Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…

Earth and Planetary Astrophysics · Physics 2016-03-31 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Nadia Balucani

Radical recombination has been proposed to lead to the formation of complex organic molecules (COMs) in CO-rich ices in the early stages of star formation. These COMs can then undergo hydrogen addition and abstraction reactions leading to a…

Astrophysics of Galaxies · Physics 2018-06-07 S. Álvarez-Barcia , P. Russ , J. Kästner , T. Lamberts

To correctly model the abundances of interstellar complex organic molecules (iCOMS) in different environments, both formation and destruction routes should be appropriately accounted for. While several scenarios have been explored for the…

Solar and Stellar Astrophysics · Physics 2019-05-15 Daniela Ascenzi , Andrea Cernuto , Nadia Balucani , Paolo Tosi , Cecilia Ceccarelli , Luca Matteo Martini , Fernando Pirani

Complex organic molecules (COMs), which are the seeds of prebiotic material and precursors of amino acids and sugars, form in the icy mantles of circumstellar dust grains but cannot be detected remotely unless they are heated and released…

Solar and Stellar Astrophysics · Physics 2019-02-08 Jeong-Eun Lee , Seokho Lee , Giseon Baek , Yuri Aikawa , Lucas Cieza , Sung-Yong Yoon , Gregory Herczeg , Doug Johnstone , Simon Casassus

The presence of complex organic molecules (COMs) in the interstellar medium (ISM) is of great interest since it may link to the origin and prevalence of life in the universe. Aiming to investigate the occurrence of COMs and their possible…

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