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(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…

Astrophysics of Galaxies · Physics 2015-05-13 K. I. Oberg , R. T. Garrod , E. F. van Dishoeck , H. Linnartz

Context: Complex molecules such as ethanol and dimethyl ether have been observed in a number of hot molecular cores and hot corinos. Attempts to model the molecular formation process using gas phase only models have so far been…

Astrophysics of Galaxies · Physics 2015-05-18 P. Hall , T. J. Millar

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water…

Astrophysics of Galaxies · Physics 2017-11-08 Vianney Taquet , Eva Wirström , Steven B. Charnley , Alexandre Faure , Ana López-Sepulcre , Carina M. Persson

The chemical complexity in low-metallicity hot cores has been confirmed by observations. We investigate the effect of varying physical parameters, such as temperature, density and the cosmic ray ionisation rate (CRIR), on the molecular…

Astrophysics of Galaxies · Physics 2024-07-10 Yara Sobhy , Hideko Nomura , Tetsuo Yamamoto , Osama Shalabeia

In star-forming regions, molecular cloud history and dynamics set the trend in the chemical composition. Ice formation, in particular, is affected by the evolution of physical conditions, which can lead to different ice compositions within…

Astrophysics of Galaxies · Physics 2025-07-02 A. Taillard , V. Wakelam , P. Gratier , E. Dartois , M. Chabot , J. A. Noble , L. Chu

There is accumulating evidence for the presence of complex molecules, including carbon-bearing and organic molecules, in the interstellar medium. Much of this evidence comes to us from studies of chemical composition, photo- and…

Earth and Planetary Astrophysics · Physics 2015-10-21 David W. Marshall , H. R. Sadeghpour

Massive star-forming regions exhibit an extremely rich and diverse chemistry, which in principle provides a wealth of molecular probes, as well as laboratories for interstellar prebiotic chemistry. Since the chemical structure of these…

Cosmic rays (CRs) are important drivers for molecular chemistry in star-forming regions, and laboratory experiments have shown that CRs can stimulate the release of complex organic molecules (COMs) such as methanol. Observationally, this…

Complex organic molecules (COMs) are known to be abundant toward some low-mass young stellar objects (YSOs), but how these detections relate to typical COM abundance are not yet understood. We aim to constrain the frequency distribution of…

Astrophysics of Galaxies · Physics 2015-06-19 Karin I. Oberg , Trish Lauck , Dawn Graninger

Icy interstellar dust grains are a source of complex organic molecule (COM) production, although their formation mechanisms are debated. Laboratory experiments show that atomic C deposited onto interstellar ice analogs can react with…

Astrophysics of Galaxies · Physics 2025-10-27 Sydney A. Willis , Serge A. Krasnokutski , Nathaniel J. Morin , Robin T. Garrod

We present maps of the column densities of H$_2$O, CO$_2$, and CO ices towards the molecular cores B~35A, DC~274.2-00.4, BHR~59, and DC~300.7-01.0. These ice maps, probing spatial distances in molecular cores as low as 2200~AU, challenge…

Astrophysics of Galaxies · Physics 2017-03-06 J. A. Noble , H. J. Fraser , K. M. Pontoppidan , A. M. Craigon

A rich inventory of complex organic molecules (COMs) has been observed in high abundances in the gas phase toward Class 0 protostars. These molecules are suggested to be formed in ices and sublimate in the warm inner envelope close to the…

Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…

Earth and Planetary Astrophysics · Physics 2021-02-22 R. Basalgète , R. Dupuy , G. Féraud , C. Romanzin , L. Philippe , X. Michaut , J. Michoud , L. Amiaud , A. Lafosse , J. -H. Fillion , M. Bertin

Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mantles on interstellar grains. With a simple astrochemical…

Astrophysics of Galaxies · Physics 2022-07-04 Juris Kalvāns , Kedron Silsbee

In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy…

Astrophysics of Galaxies · Physics 2022-09-07 Alec Paulive , Joshua T. Carder , Eric Herbst

Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…

Astrophysics of Galaxies · Physics 2015-06-23 Juris Kalvans

The high abundances of Complex Organic Molecules (COMs) with respect to methanol, the most abundant COM, detected towards low-mass protostars, tend to be underpredicted by astrochemical models. This discrepancy might come from the large…

Solar and Stellar Astrophysics · Physics 2015-05-20 Vianney Taquet , Ana López-Sepulcre , Cecilia Ceccarelli , Roberto Neri , Claudine Kahane , Steven B. Charnley

Here we present high spatial resolution (<1 arcsecond) observations of molecular emission in Orion-KL conducted using the Combined Array for Research in Millimeter-Wave Astronomy (CARMA). This work was motivated by recent millimeter…

Astrophysics of Galaxies · Physics 2015-06-05 Susanna L. Widicus Weaver , Douglas N. Friedel

Carbon ($^3$P) atom is a reactive species that, according to laboratory experiments and theoretical calculations, condensates with interstellar ice components. This fact is of uttermost importance for the chemistry in the interstellar…

Astrophysics of Galaxies · Physics 2023-07-19 Stefano Ferrero , Cecilia Ceccarelli , Piero Ugliengo , Mariona Sodupe , Albert Rimola

Complex organic molecules (COMs) have been detected in a few Class 0 protostars but their origin is not well understood. Going beyond studies of individual objects, we want to investigate the origin of COMs in young protostars on a…