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A new phase field crystal (PFC) type theory is presented, which accounts for the full spectrum of solid-liquid-vapor phase transitions within the framework of a single density order parameter. Its equilibrium properties show the most…

Materials Science · Physics 2015-06-23 Gabriel Kocher , Nikolas Provatas

We determine the full kinetic phase diagram for nucleation and growth of crystal phases in a suspension of charged colloids. We calculate nucleation barrier heights for face-centered cubic (fcc) and body-centered cubic (bcc) crystal phases…

Soft Condensed Matter · Physics 2022-08-31 Willem Gispen , Marjolein Dijkstra

Using both dynamical density functional theory and particle-resolved Brownian dynamics simulations, we explore the flow of two-dimensional colloidal solids and fluids driven through a linear channel with a geometric constriction. The flow…

Soft Condensed Matter · Physics 2016-05-25 Urs Zimmermann , Frank Smallenburg , Hartmut Löwen

Using dynamical density functional theory we calculate the speed of solidification fronts advancing into a quenched two-dimensional model fluid of soft-core particles. We find that solidification fronts can advance via two different…

Soft Condensed Matter · Physics 2014-10-22 A. J. Archer , M. C. Walters , U. Thiele , E. Knobloch

In this article we consider systems of parallel hard {\it superellipsoids}, which can be viewed as a possible interpolation between ellipsoids of revolution and cylinders. Superellipsoids are characterized by an aspect ratio and an exponent…

Soft Condensed Matter · Physics 2009-11-13 Yuri Martinez-Raton , Enrique Velasco

We study numerically the crystallization process in a supersaturated suspension of repulsive colloidal particles driven by simple shear flow. The effect of the shear flow on crystallization is two-fold: while it suppresses the initial…

Soft Condensed Matter · Physics 2013-07-02 Boris Lander , Udo Seifert , Thomas Speck

We report the formation of colloidal complexes resulting from the electrostatic co-assembly between anionic surfactants and cationic polyelectrolytes or block copolymers. Combining light and x-ray scattering experiments with cryogenic…

Soft Condensed Matter · Physics 2009-04-01 J. -F. Berret

We present a computer simulation study on the crystal nucleation process in suspensions of hard spheres, fully taking into account the solvent hydrodynamics. If the dynamics of collodial crystallization were purely diffusive, the crystal…

Soft Condensed Matter · Physics 2015-06-12 Marc Radu , Tanja Schilling

An understanding of homogeneous nucleation of crystalline structure from a disordered medium such as a liquid remains an important unsolved problem in condensed matter physics. Guided by the results from a number of experiments on granular…

Soft Condensed Matter · Physics 2018-09-26 Charles Radin , Harry L. Swinney

Microcanonical Monte Carlo simulations of a polydisperse soft-spheres model for liquids and colloids have been performed for very large polydispersity, in the region where a phase-separation is known to occur when the system (or part of it)…

Soft Condensed Matter · Physics 2011-08-31 L. A. Fernandez , V. Martin-Mayor , B. Seoane , P. Verrocchio

Liquids and solids are two fundamental states of matter. However, due to the lack of direct experimental determination, our understanding of the 3D atomic structure of liquids and amorphous solids remained speculative. Here we advance…

A phase-field crystal model based on the density-field approach incorporating high-order interparticle direct correlations is developed to study vapor-liquid-solid coexistence and transitions within a single continuum description.…

Materials Science · Physics 2020-10-21 Zi-Le Wang , Zhirong Liu , Zhi-Feng Huang , Wenhui Duan

In this work, we apply phase field simulations to examine the coarsening behavior of morphologically complex two-phase microstructures in which the phases have highly dissimilar mobilities, a condition approaching that found in experimental…

Materials Science · Physics 2022-06-10 W. Beck Andrews , Peter W. Voorhees , Katsuyo Thornton

We investigate the atomistic mechanism of homogeneous nucleation during solidification in molybdenum employing transition path sampling. The mechanism is characterized by the formation of a pre-structured region of high bond-orientational…

Materials Science · Physics 2020-10-16 Sarath Menon , Grisell Díaz Leines , Ralf Drautz , Jutta Rogal

Despite the wide existence of vesicles in living cells as well as their important applications like drug-delivery, the underlying mechanism of vesicle fusion/fission remains under debate. Here, we develop a constrained self-consistent field…

Soft Condensed Matter · Physics 2023-05-22 Luofu Liu , Chao Duan , Rui Wang

Modulating liquid-to-solid transitions and the resulting crystalline structure for tailored properties is much desired. Colloidal systems are exemplary to this end, but the fundamental knowledge gaps in relating the influence of…

Statistical Mechanics · Physics 2025-11-04 Porhouy Minh , Steven W. Hall , Ryan S. DeFever , Sapna Sarupria

We experimentally study the crystallization of a monolayer of vibrated discs with a built-in polar asymmetry, a model system of active liquids, and contrast it with that of vibrated isotropic discs. Increasing the packing fraction $\phi$,…

Soft Condensed Matter · Physics 2016-09-05 G. Briand , O. Dauchot

Previously we reported on the stable (i.e. minimal enthalpy) structures of soft monodisperse spheres in a long cylindrical channel. Here, we present further simulations, which significantly extend the original phase diagram up to D/d =…

Soft Condensed Matter · Physics 2018-10-10 Adil Mughal , Jens Winkelmann , Denis Weaire , Stefan Hutzler

We present a computer simulation study of the crystalline phases of hard ellipsoids of revolution. A previous study [Phys. Rev. E, \textbf{75}, 020402 (2007)] showed that for aspect ratios $a/b\ge 3$ the previously suggested stretched-fcc…

Statistical Mechanics · Physics 2015-05-13 M. Radu , P. Pfleiderer , T. Schilling

Ultrasoft colloids typically do not spontaneously crystallize, but rather vitrify, at high concentrations. Combining in-situ rheo-SANS experiments and numerical simulations we show that shear facilitates crystallization of colloidal star…

Soft Condensed Matter · Physics 2018-02-21 J. Ruiz-Franco , J. Marakis , N. Gnan , J. Kohlbrecher , M. Gauthier , M. P. Lettinga , D. Vlassopoulos , E. Zaccarelli