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We demonstrate insights into the three-dimensional structure of defects in graphene, in particular grain boundaries, obtained via a new approach from two transmission electron microscopy images recorded at different angles. The structure is…

We perform a MonteCarlo simulation in order to study the connection between the morphology and the transport properties of grain boundaries (GBs) in graphene. We explore the configurational space of GBs to generate ensembles of realistic…

Mesoscale and Nanoscale Physics · Physics 2021-07-15 Fernando Gargiulo

Grain boundary (GB) kinetics is important for many applications in 2d materials and metal thin films. To study how the substrate shape affects GB mobility and kinetics, we develop a kinetic Monte Carlo (kMC) simulation method and an…

Materials Science · Physics 2022-01-24 Kongtao Chen

Grain boundaries (GBs) are ubiquitous in large-scale graphene samples, playing a crucial role in their overall performance. Due to their complexity, they are usually investigated as model structures, under the assumption of a fully relaxed…

As undesirable defects, grain boundaries (GBs) are widespread in epitaxial graphene using existing growth methods on metal substrates. Employing density functional theory calculations, we first identify that the misorientations of carbon…

Materials Science · Physics 2015-06-03 Wei Chen , Hua Chen , Haiping Lan , Ping Cui , Tim P. Schulze , Wenguang Zhu , Zhenyu Zhang

Atomistic simulations were utilized to obtain microscopic information of the elongation process in graphene sheets consisting of various embedded symmetric tilt grain boundaries (GBs). In contrast to pristine graphene, these GBs fractured…

Mesoscale and Nanoscale Physics · Physics 2012-02-14 Young In Jhon , Pil Seung Chung , Robert Smith , Myung S. Jhon

Grain boundary roughness can affect electronic and mechanical properties of two-dimensional materials. This roughness depends crucially on the growth process by which the two-dimensional material is formed. To investigate the key mechanisms…

Materials Science · Physics 2022-04-06 Fabio D. A. Aarão Reis , Bastien Marguet , Olivier Pierre-Louis

Grain boundaries (GBs), an important constituent of polycrystalline materials, have a wide range of manifestion and significantly affect the properties of materials. Fully understanding the effects of GBs is stalemated due to lack of…

Materials Science · Physics 2021-03-19 Cheng-yan Liu , Zhi-ming Li , Xin-gao Gong

Chemical vapor deposition (CVD) on Cu foil is one of the most promising methods to produce graphene samples despite of introducing numerous grain boundaries into the perfect graphene lattice. A rich variety of GB structures can be realized…

Mesoscale and Nanoscale Physics · Physics 2013-10-28 Péter Vancsó , Géza I. Márk , Philippe Lambin , Alexandre Mayer , Chanyong Hwang , László P. Biró

Using molecular dynamics simulations and first principles calculations, we have studied the structure and mechanical strength of tilt grain boundaries in graphene sheets that arise during CVD growth of graphene on metal substrates.…

Materials Science · Physics 2015-05-19 Rassin Grantab , Vivek B. Shenoy , Rodney S. Ruoff

The grain boundary (GB) energy is a quantity of fundamental importance for understanding several key properties of graphene. Here we present a comprehensive theoretical and numerical study of the entire space of symmetric and asymmetric…

Materials Science · Physics 2016-11-22 Ashivni Shekhawat , Colin Ophus , Robert O. Ritchie

The strong interest in graphene has motivated the scalable production of high quality graphene and graphene devices. Since large-scale graphene films synthesized to date are typically polycrystalline, it is important to characterize and…

Defects such as grain boundaries (GBs) are almost inevitable during the synthesis process of 2D materials. To take advantage of the fascinating properties of 2D materials, understanding the nature and impact of various GB structures on the…

Grain boundaries play a major role for electron transport in graphene sheets grown by chemical vapor deposition. Here we investigate the electronic structure and transport properties of idealized graphene grain boundaries (GBs) in…

Mesoscale and Nanoscale Physics · Physics 2024-03-19 Aleksander Bach Lorentzen , Fei Gao , Peter Bøggild , Antti-Pekka Jauho , Mads Brandbyge

Grain boundaries (GBs) are central defects for describing polycrystalline materials, and playing major role in a wide-range of physical properties of polycrystals. Control over GB kinetics provides effective means to tailor polycrystal…

Materials Science · Physics 2018-10-10 Jian Han , Spencer L. Thomas , David J. Srolovitz

We have characterized the structure of 176 different single-layer graphene grain boundaries using $>$1000 experimental HRTEM images using a semi-automated structure processing routine. We introduce a new algorithm for generating grain…

Materials Science · Physics 2015-08-04 Colin Ophus , Ashivni Shekhawat , Haider I Rasool , Alex Zettl

In order to control the grain structure of multi-crystalline (mc) silicon during directional solidification, the development process of grain boundaries (GBs) with respect to the temperature gradient should be understood. A phase-field…

Materials Science · Physics 2022-06-13 Chuanqi Zhu , Yuichiro Koizumi , Chunwen Guo

Computing the grain boundary (GB) counterparts to bulk phase diagrams represents an emerging research direction. Using a classical embrittlement model system Ga-doped Al alloy, this study demonstrates the feasibility of computing…

Materials Science · Physics 2022-01-20 Chongze Hu , Yanwen Li , Zhiyang Yu , Jian Luo

Although the corresponding carbon-metal interactions can be very different, a similar nonlinear growth behavior of graphene has been observed for different metal substrates. To understand this interesting experimental observation, a…

Materials Science · Physics 2013-09-10 Huijun Jiang , Ping Wu , Zhonghuai Hou , Zhenyu Li , Jinlong Yang

Grain boundary (GB) energy is a fundamental property that affects the form of grain boundary and plays an important role to unveil the behavior of polycrystalline materials. With a better understanding of grain boundary energy distribution…

Computational Physics · Physics 2020-02-04 Haoyu Wang , Srikanth Patala , Brian J. Reich
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