Related papers: Cosmic-ray-induced dissociation and reactions in w…
Cosmic rays are able to heat interstellar dust grains. This may enhance molecule mobility in icy mantles that have accumulated on the grains in dark cloud cores. A three-phase astrochemical model was used to investigate the molecule…
Cosmic-ray-induced whole-grain heating induces evaporation and other processes that affect the chemistry of interstellar clouds. With recent data on grain heating frequencies as an input for a modified rate-equation astrochemical model,…
Cosmic-ray (CR) induced heating of whole interstellar grains is an important desorption mechanism for grain surface molecules in interstellar molecular clouds. This study aims to provide a detailed temperature spectra for such CR-induced…
Non-thermal desorption of ices on interstellar grains is required to explain observations of molecules that are not synthesized efficiently in the gas phase in cold dense clouds. Perhaps the most important non-thermal desorption mechanism…
In this paper, we present preliminary results illustrating the effect of cosmic rays on solid-phase chemistry in models of both TMC-1 and several sources with physical conditions identical to TMC-1 except for hypothetically enhanced…
Heating of whole interstellar dust grains by cosmic-ray (CR) particles affects the gas-grain chemistry in molecular clouds by promoting molecule desorption, diffusion, and chemical reactions on grain surfaces. The frequency of such heating…
The standard model of cosmic ray heating-induced desorption of interstellar ices is based on a continuous representation of the sporadic desorption of ice mantle components from classical (0.1 micron) dust grains. This has been re-evaluated…
Icy grains in the interstellar medium and star-formation regions consist of a variety of materials. Such composite grains interact differently with cosmic-ray (CR) particles compared to simple single-material grains. We aim to calculate the…
Context. Evaporative (sublimation) cooling of icy interstellar grains occurs when the grains have been suddenly heated by a cosmic-ray (CR) particle or other process. It results in thermal desorption of icy species, affecting the chemical…
We present a new gas-grain chemical model to constrain the effect of grain size distribution on molecular abundances in starless and pre-stellar cores. We introduce grain-size dependence simultaneously for cosmic-ray (CR)-induced desorption…
In cold core of dark molecular clouds, where the UV radiation from external sources is strongly attenuated, cosmic rays can induce chemical reactions on the surface of ice-covered grains promoting the ejection of the processed material to…
Some observations of warm carbon chain chemistry (WCCC) cores indicate that they are often located near the edges of molecular clouds. This finding may suggest that WCCC is promoted in star-forming cores exposed to radiation from the…
The typical amount of molecular hydrogen (${\rm H_2}$) in interstellar ices is not known, but significant freeze-out of ${\rm H_2}$ on dust grains is not expected. However, chemical models ubiquitously predict large amounts of $\rm H_2$…
Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…
Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the freeze-out of molecules onto grains. The processing is caused by…
Cosmic rays are crucial for the chemistry of molecular clouds and their evolution. They provide essential ionizations, dissociations, heating and energy to the cold, dense cores. As cosmic rays pierce through the clouds they are attenuated…
Under cold conditions in dense cores, gas-phase molecules and atoms are depleted from the gas-phase to the surface of interstellar grains. Considering the time scales and physical conditions within these cores, a portion of these molecules…
Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on the immediate environment of adsorbed molecules. Aims. We…
Species abundances in the interstellar medium (ISM) strongly depend on the chemistry occurring at the surfaces of the dust grains. To describe the complexity of the chemistry, various numerical models have been constructed. In most of these…
In molecular cloud cores, the cosmic ray (CR) induced sputtering via CR ion-icy grain collision is one of the desorption processes for ice molecules from mantles around dust grains. The efficiency of this process depends on the incident CR…