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Compulsory Dirac multipoles in the bilayer perovskite Ca3Ru2O7 are absent in published analyses of experimental data. In a first step at correcting knowledge of the magnetic structure, we have analysed existing Bragg diffraction patterns…

Strongly Correlated Electrons · Physics 2019-05-08 S W Lovesey , D D Khalyavin , G van der Laan

Magnetic axial and polar (Dirac) nickel multipoles contribute to resonant x-ray Bragg amplitudes in a symmetry informed analysis of monoclinic Li2Ni3P4O14 presented for future diffraction experiments. Magnetic long-range order below a…

Strongly Correlated Electrons · Physics 2025-08-08 Stephen W. Lovesey

Experimental techniques using Bragg diffraction may elucidate electronic and magnetic properties of ferric ions in multiferroic ScFeO3 that are puzzling. A collinear magnetic motif of dipole moments is not expected for s-state ions with an…

Strongly Correlated Electrons · Physics 2017-01-18 S W Lovesey , D D Khalyavin

The Bragg diffraction of neutrons and x-rays are well-suited to the task of determining the distribution of magnetization in crystals. Applications of the two techniques proceed by contrasting observed intensities with intensities…

Strongly Correlated Electrons · Physics 2022-12-21 Stephen W. Lovesey

The scope of magnetic neutron scattering has been expanded by the observation of electronic Dirac dipoles (anapoles) that are polar (parity-odd) and magnetic (time-odd). A zero-magnetization ferromagnet Sm0.976Gd0.024Al2 with a diamond-type…

Materials Science · Physics 2019-02-06 S. W. Lovesey , T. Chatterji , A. Stunault , D. D. Khalyavin , G. van der Laan

Magnetic diffraction of polarized neutrons by the cubic Laves compound UAl2 in a magnetic field has unveiled weak Bragg spots that are nominally forbidden. On the one hand, they can be viewed as magnetic analogues of the basis-forbidden (2,…

Strongly Correlated Electrons · Physics 2020-01-08 S. W. Lovesey , D. D. Khalyavin , G. van der Laan

A theory that fully describes previously observed neutron Bragg spots indicative of magnetic order in the pseudo-gap phase of YBa2Cu3O6 + x is presented. Magnetic diffraction intensities, unveiled by polarization analysis, are explained by…

Strongly Correlated Electrons · Physics 2015-05-01 S. W. Lovesey , D. D. Khalyavin , U. Staub

Ruthenium trichloride is the subject of many recent experimental and theoretical studies. Johnson et al. infer a candidate for the magnetic structure (Cc2/m) from results gathered in an extensive set of experiments on an untwined sample of…

Strongly Correlated Electrons · Physics 2022-11-01 S W Lovesey

Antiferromagnetic compounds chromium sesquioxide (Cr$_2$O$_3$) and dioxomolybdenum selenite present linear magnetoelectric effects. Anti-inversion symmetry in the corresponding magnetic crystal classes dictate the makeup of magnetic Bragg…

Strongly Correlated Electrons · Physics 2024-07-29 S. W. Lovesey , G. van der Laan

The Landau free-energy of a compound that benefits from a linear coupling of an electric field and a magnetic field includes a product of the two fields, one polar and time-even and one axial and time-odd. In ME compounds, expectation…

Strongly Correlated Electrons · Physics 2023-05-10 S. W. Lovesey

The magnetic properties of materials hosting Eu2+(J = 7/2, 4f7) ions have attracted much attention in the science of strongly correlated electrons. In part because crystal electric field effects are impoverished for an s-state ion, as with…

Strongly Correlated Electrons · Physics 2025-07-01 Stephen W. Lovesey

Cerium electronic multipoles in trigonal symmetry viewed in magnetic neutron diffraction are investigated. Analytic expressions for all the magnetic multipoles, and radial integrals calculated with an established atomic code, are used to…

Strongly Correlated Electrons · Physics 2020-04-22 S. W. Lovesey , G. van der Laan

We present single-crystal neutron-diffraction data for the spin-chain compound Ca3Co2O6. The intensity and line shapes of the two families of Bragg peaks characterising both the antiferromagnetic and the ferromagnetic components of the…

Strongly Correlated Electrons · Physics 2017-04-03 C. L. Fleck , M. R. Lees , S. Agrestini , G. J. McIntyre , O. A. Petrenko

Resonant soft x-ray Bragg diffraction at the Dy M4,5 edges has been exploited to study Dy multipole motifs in DyB2C2. Our results are explained introducing the intra-atomic quadrupolar interaction between the core 3d and valence 4f shell.…

Strongly Correlated Electrons · Physics 2009-11-11 A. M. Mulders , U. Staub , V. Scagnoli , S. W. Lovesey , E. Balcar , T. Nakamura , A. Kikkawa , G. van der Laan , J. M. Tonnerre

Fundamental block and staggered orders of magnetic Fe multipoles in Na2FeSe2 are classified by their symmetry and magnetoelectric properties. Our structure model incorporates ferromagnetic or antiferromagnetic coupling between chains. The…

Strongly Correlated Electrons · Physics 2021-04-28 S. W. Lovesey , D. D. Khalyavin

A theoretical investigation of a plausible construct for electronic structure in iridate perovskites demonstrates the existence of magnetic multipoles hitherto not identified. The strange multipoles, which are parity-even, time-odd and even…

Strongly Correlated Electrons · Physics 2014-05-15 S W Lovesey , D D Khalyavin

KV3Sb5 has recently attracted a considerable attention, due to its low temperature superconducting properties, which are heralded by a charge density wave. The apparent presence of a very weak magnetism does not result in long range…

Strongly Correlated Electrons · Physics 2022-08-31 V. Scagnoli , D. D. Khalyavin , S. W. Lovesey

We have investigated the antiferromagnetic insulating phase of the Mott-Hubbard insulator V$_2$O$_3$ by resonant x-ray Bragg diffraction at the vanadium K-edge. Combining the information obtained from azimuthal angle scans, linear incoming…

Scrutiny of an established monoclinic magnetic space group for NdFeO3 reveals hitherto unknown properties of the orthoferrite. Future experiments using neutron and x-ray diffraction techniques can verify them. Neodymium ions possess Dirac…

Strongly Correlated Electrons · Physics 2023-06-28 Stephen W. Lovesey

Properties of two ThCr2Si2-type materials are discussed within the context of their established structural and magnetic symmetries. Both materials develop collinear, G-type antiferromagnetic order above room temperature, and magnetic ions…

Strongly Correlated Electrons · Physics 2017-11-07 S W Lovesey , D D Khalyavin
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