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Accurate molecular imaging via high-order harmonic generation relies on comparing the harmonic emission from a molecule and an adequate reference system. However, an ideal reference atom with the same ionization properties as the molecule…

Atomic Physics · Physics 2015-05-28 Elmar V. van der Zwan , Manfred Lein

High-order harmonic generation (HHG) is a powerful tool for probing electronic structure and ultrafast dynamics in matter. Traditionally studied in atomic and molecular gases, HHG has recently been extended to condensed matter, enabling…

High-order harmonic generation in polyatomic molecules generally involves multiple channels, each associated with a different orbital. Their unambiguous assignment remains a major challenge for high-harmonic spectroscopy. Here we present a…

High-order harmonic generation (HHG) in aligned linear molecules can offer valuable information about strong-field interactions in lower-lying molecular orbitals, but extracting this information is difficult for three-dimensional molecular…

We present an experimental technique using orbital angular momentum (OAM) in a fundamental laser field to drive High Harmonic Generation (HHG). The mixing of beams with different OAM allows to generate two laser foci tightly spaced to study…

Chemical Physics · Physics 2019-07-24 Jan Troßand Carlos A. Trallero-Herrero

High-order harmonic generation (HHG) results from strong-field laser matter interaction and it is one of the main processes that are used to extract electron structural and dynamical information about the atomic or molecular targets with…

High harmonic generation in the interaction of femtosecond lasers with atoms and molecules opens the path to molecular orbital tomography and to probe the electronic dynamics with attosecond-{\AA}ngstr\"{o}m resolutions. Molecular orbital…

The generation of high harmonics in laser-irradiated light homonuclear diatomics (H2+, N2 and O2) compared to that in atomic counterparts (of nearly identical binding energy) is studied within the velocity gauge version of conventional…

Atomic Physics · Physics 2009-11-11 Vladimir I. Usachenko , Pavel E. Pyak , Shih-I Chu

This tutorial presents the most important aspects of the molecular self-probing paradigm, which views the process of high harmonic generation as "a molecule being probed by one of its own electrons". Since the properties of the electron…

Atomic Physics · Physics 2021-03-31 Stefan Haessler , Jérémie Caillat , Pascal Salières

An all-optical measurement of high-order fractional molecular echoes is demonstrated by using high-order harmonic generation (HHG). Excited by a pair of time-delayed short laser pulses, the signatures of full and high order fractional (1/2…

Chemical Physics · Physics 2019-10-23 Baoning Wang , Lixin He , Yanqing He , Yinfu Zhang , Renzhi Shao , Pengfei Lan , Peixiang Lu

We study high-order harmonic generation in aligned molecules close to the ionization threshold. Two distinct contributions to the harmonic signal are observed, which show very different responses to molecular alignment and ellipticity of…

Atomic Physics · Physics 2011-09-16 H. Soifer , P. Botheron , D. Shafir , A. Diner , O. Raz , B. D. Bruner , Y. Mairesse , B. Pons , N. Dudovich

We report theoretical investigations of the tomographic procedure suggested by Itatani {\it et al.} [Nature, {\bf 432} 867 (2004)] for reconstructing highest occupied molecular orbitals (HOMO) using high-order harmonic generation (HHG).…

Atomic Physics · Physics 2009-10-30 Van-Hoang Le , Anh-Thu Le , Rui-Hua Xie , C. D. Lin

High-order harmonic generation by a bicircular field, which consists of two coplanar counter-rotating circularly polarized fields of frequency $r\omega$ and $s\omega$ ($r$ and $s$ are integers), is investigated for a polyatomic molecule.…

Atomic Physics · Physics 2016-10-05 Senad Odžak , Elvedin Hasović , Dejan B. Milošević

Thermotropic liquid crystals are versatile optical materials that exhibit a state of matter intermediate between liquids and solids. Their properties can change significantly with temperature, pressure, or other external factors, leading to…

A three step model for high harmonic generation from impurities in solids is developed. The process is found to be similar to high harmonic generation in atomic and molecular gases with the main difference coming from the non-parabolic…

Atomic Physics · Physics 2018-10-31 S. Almalki , A. Parks , G. Bart , P. B. Corkum , T. Brabec , C. R. McDonald

We use extreme-ultraviolet interferometry to measure the phase of high-order harmonic generation from transiently aligned CO2 molecules. We unambiguously observe a reversal in phase of the high order harmonic emission for higher harmonic…

Atomic Physics · Physics 2009-11-13 Xibin Zhou , Robynne Lock , Wen Li , Nick Wagner , Margaret. M. Murnane , Henry C. Kapteyn

High-harmonic spectroscopy driven by circularly-polarized laser pulses and their counter-rotating second harmonic is a new branch of attosecond science which currently lacks quantitative interpretations. We extend this technique to the…

Atomic Physics · Physics 2019-09-04 Denitsa Baykusheva , Simon Brennecke , Manfred Lein , Hans Jakob Wörner

We demonstrate to image asymmetric molecular orbitals via high-order harmonic generation in a one-color inhomogeneous field. Due to the broken inversion symmetry of the inhomogeneous field in space, the returning electrons with energy in a…

Optics · Physics 2018-03-14 Hua Yuan , Lixin He , Feng Wang , Baoning Wang , Xiaosong Zhu , Pengfei Lan , Peixiang Lu

The use of plane wave approximation in molecular orbital tomography via high-order harmonic generation has been questioned since it was proposed, owing to the fact that it ignores the essential property of the continuum wave function. To…

Atomic Physics · Physics 2015-06-18 Yang Li , Xiaosong Zhu , Pengfei Lan , Qingbin Zhang , Meiyan Qin , Peixiang Lu

An important goal in molecular physics and chemistry today is to obtain structure-dependent information about molecular function to obtain a deeper understanding into chemical reactions. However, until now, asymmetric tops, which comprise…

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