English
Related papers

Related papers: Transformation pathways in high-pressure solid nit…

200 papers

Manganese nitrides should be with amazing properties and promised application, because manganese atom is particular for its magnetism, valence states, high electron density, etc., and N atoms in compounds form different substructures. It is…

Materials Science · Physics 2021-11-04 Li Li , Kuo Bao , Xingbin Zhao , Tian Cui

By employing first-principles metadynamics simulations, we explore the 300 K structures of solid hydrogen over the pressure range 150-300 GPa. At 200 GPa, we find the ambient-pressure disordered hexagonal close-packed (hcp) phase transited…

Materials Science · Physics 2012-08-16 Hanyu Liu , Li Zhu , Wenwen Cui , Yanming Ma

Crystal structure prediction methods and first-principles calculations have been used to explore low-energy structures of carbon monoxide (CO). Contrary to the standard wisdom, the most stable structure of CO at ambient pressure was found…

Materials Science · Physics 2017-04-06 Kang Xia , Jian Sun , Chris J. Pickard , Dennis D. Klug , Richard J. Needs

The immense interest in carbon nanomaterials continues to stimulate intense research activities aimed to realize carbon nanowires, since linear chains of carbon atoms are expected to display novel and technologically relevant optical,…

Materials Science · Physics 2010-11-02 Xing-Qiu Chen , C. L. Fu , C. Franchini

We report here a study of reversible pressure-induced structural transformation between two amorphous forms of SO$_2$: molecular at pressures below 26 GPa and polymeric above this pressure, at temperatures of 77 - 300 K. The transformation…

We used ab initio random structure searching (AIRSS) to investigate polymorphism in C3N4 carbon nitride as a function of pressure. Our calculations reveal new framework structures, including a particularly stable chiral polymorph of space…

Materials Science · Physics 2016-09-14 Chris J. Pickard , Ashkan Salamat , Michael J. Bojdys , Richard J. Needs , Paul F. McMillan

First-principles molecular dynamics (FPMD) simulations are performed on 6 and 12% Na in dense liquid N. A detailed description of structural and electronic properties leading to an understanding of the effect of Na-doping on the…

Materials Science · Physics 2017-11-15 Marc M. E. Cormier , Stanimir A. Bonev

Nuclear liquid-gas phase transitions are investigated in the framework of static antisymmetrized molecular dynamics (static AMD) model under either a constant volume or a constant pressure. A deuteron quadrupole momentum fluctuation…

Nuclear Theory · Physics 2021-06-24 W. Lin , P. Ren , X. Liu , H. Zheng , M. Huang , G. Qu , R. Wada

A magnetohydrodynamic model of a steady, transverse C-type shock in a dense molecular cloud is presented. A complete gas-grain chemical network is taken into account: the gas-phase chemistry, the adsorption of gas species on dust grains,…

Astrophysics of Galaxies · Physics 2018-06-12 A. V. Nesterenok

Solid CS$_{2}$ is superficially similar to CO$_{2}$, with the same $Cmca$ molecular crystal structure at low pressures, which has suggested similar phases also at high pressures. We carried out an extensive first principles evolutionary…

Materials Science · Physics 2015-06-23 S. Shahab Naghavi , Yanier Crespo , Roman Martonak , Erio Tosatti

We map the high-pressure phase diagram of nitrogen hydrate up to 16 GPa at room temperature by combining neutron diffraction, Raman spectroscopy, and crystal structure prediction. We reveal a rich sequence of structural transformations,…

We report a novel multi-scale simulation methodology to quantitatively predict the thermodynamic behaviour of polymer mixtures, that exhibit phases with broken orientational symmetry. Our system consists of a binary mixture of oligomers and…

Soft Condensed Matter · Physics 2021-12-07 William S. Fall , Hima Bindu Kolli , Biswaroop Mukherjee , Buddhapriya Chakrabarti

We present molecular dynamics simulations of solid NaNO$_2$ using pair potentials with the rigid-ion model. The crystal potential surface is calculated by using an \emph{a priori} method which integrates the \emph{ab initio} calculations…

Materials Science · Physics 2009-11-10 Wei-Guo Yin , C. -G. Duan , W. N. Mei , J. Liu , R. W. Smith , J. R. Hardy

We performed simulations for solid molecular hydrogen at high pressures (250GPa$\leq$P$\leq$500GPa) along two isotherms at T=200 K (phases III and VI) and at T=414 K (phase IV). At T=200K we considered likely candidates for phase III, the…

Materials Science · Physics 2017-11-22 Giovanni Rillo , Miguel A. Morales , David M. Ceperley , Carlo Pierleoni

Cubic gauche polynitrogen (cg-N) is an attractive high-energy density material. However, high-pressure synthesized cg-N will decompose at low-pressure and cannot exist at ambient conditions. Here, the stabilities of cg-N surfaces with and…

Materials Science · Physics 2024-12-02 Guo Chen , Caoping Niu , Wenming Xia , Jie Zhang , Zhi Zeng , Xianlong Wang

Combining elastic incoherent neutron scattering experiments at different resolutions with molecular dynamics simulations, we report the observation of a protein-like dynamical transition in linear chains of Poly(N-isopropylacrylamide). We…

Soft Condensed Matter · Physics 2021-03-11 L. Tavagnacco , M. Zanatta , E. Buratti , B. Rosi , B. Frick , F. Natali , J. Ollivier , E. Chiessi , M. Bertoldo , E. Zaccarelli , A. Orecchini

We report filling-fraction dependent dielectric spectroscopy measurements on the relaxation dynamics of the rod-like nematogen 7CB condensed in 13 nm silica nanochannels. In the film-condensed regime, a slow interface relaxation dominates…

Soft Condensed Matter · Physics 2015-04-21 Sylwia Calus , Andriy V. Kityk , Manfred Eich , Patrick Huber

High pressure in-situ synchrotron X-ray diffraction experiments were performed on Ag2Te up to 42.6 GPa at room temperature and four phases were identified. Phase I ({\beta}-Ag2Te) transformed into phase II at 2.4 GPa, and phase III and…

Materials Science · Physics 2015-05-01 Zhao Zhao , Shibing Wang , Haijun Zhang , Wendy L. Mao

Consider a model of particles (nucleons) which has a two-body interaction which leads to bound composites with saturation properties. These properties are : all composites have the same density and the ground state energies of composites…

Statistical Mechanics · Physics 2009-11-11 G. Chaudhuri , S. Das Gupta , M. Sutton

We apply correlation matrix renormalization theory (CMRT) to cerium nitride (CeN) under pressure. For B1 (NaCl-type) phase, CMRT gives an equation of state consistent with ambient pressure experiments. It produces electronic…

Strongly Correlated Electrons · Physics 2025-11-24 Jun Liu , Jianhua Zhang , Yongxin Yao , Kai-Ming Ho , Cai-Zhuang Wang