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Inspired by the first boron-carbon (B-C) clathrate SrB$_3$C$_3$ and the ternary borohydride KB$_2$H$_8$ [Miao et al., Phys. Rev. B 104 L100504 (2021)], we have performed first-principles density functional theory calculations of the…

Superconductivity · Physics 2024-05-24 Bin Li , Yulan Cheng , Cong Zhu , Jie Cheng , Shengli Liu

Motivated by the recent report of superconductivity above 200 K in ultra-dense hydrogen sulfide, we search for high-\tc\ conventional superconductivity in the phase diagram of the binary Li-S system, using {\em ab-initio} methods for…

Superconductivity · Physics 2016-08-10 Christian Kokail , Christoph Heil , Lilia Boeri

It is challenging to search for high Tc superconductivity (SC) in transition metal elements wherein d electrons are usually not favored by conventional BCS theory. Here we report discovery of surprising SC up to 310 GPa with Tc above 20 K…

The search for room temperature superconductivity has accelerated dramatically in the last few years driven largely by theoretical predictions that first indicated alloying dense hydrogen with other elements could produce conventional…

This article reports the experimentally clarified crystal structure of a recently discovered sulfur hydride in high temperature superconducting phase which has the highest critical temperature Tc over 200 K which has been ever reported. For…

Hydrogen-sulfide (H2S) was studied by x-ray synchrotron diffraction (XRD) and Raman spectroscopy up to 150 GPa at 180-295 K and by quantum-mechanical variable-composition evolutionary simulations. The experiments show that H2S becomes…

Studies on polyhydrides are attracting growing attentions recently due to their potential high temperature superconductivity (SC). We here report the discovery of SC in hafnium polyhydrides at high pressures. The hafnium superhydrides are…

Recent discovery of high-temperature superconductivity (Tc = 190 K) in sulfur hydrides at megabar pressures breaks the traditional belief on the Tc limit of 40 K for conventional superconductors, and open up the doors in searching new…

Pressure plays an essential role in the induction1 and control2,3 of superconductivity in iron-based superconductors. Substitution of a smaller rare-earth ion for the bigger one to simulate the pressure effects has surprisingly raised the…

To raise the superconducting-transition temperature (Tc) has been the driving force for the long, sustained effort in superconductivity research. Recent progress in hydrides with Tcs up to 287 K under 267 GPa has heralded a new era of…

It is demonstrated that resistive transition at 203 K observed in metallic sulfur hydride system at high pressure can be magnetic (rather than superconducting (SC)) in nature. The onset temperature of genuine superconducting transition in…

Superconductivity · Physics 2015-10-02 L. S. Mazov

We survey the landscape of binary hydrides across the entire periodic table from 10 to 500 GPa using a crystal structure prediction method. Building a critical temperature ($T_c$) model, with inputs arising from density of states…

Superconductivity · Physics 2021-08-11 Alice M. Shipley , Michael J. Hutcheon , Richard J. Needs , Chris J. Pickard

The phenomenon of high temperature superconductivity, approaching room temperature, has been realized in a number of hydrogen-dominant alloy systems under high pressure conditions1-12. A significant discovery in reaching room temperature…

What factors fundamentally determine the value of superconducting transition temperature (Tc) in high temperature superconductors has been the subject of intense debate. Following the establishment of an empirical law known as Homes'law,…

We present a new technique for measuring the critical temperature Tc in the high pressure, high Tc electron-phonon-driven superconducting hydrides. This technique does not require connecting leads to the sample. In the multiphonon region of…

Superconductivity · Physics 2018-08-01 J. P. Carbotte , E. J. Nicol , T. Timusk

Recently superconductivity has been discovered at around 200~K in a hydrogen sulfide system and around 260~K in a lanthanum hydride system, both under pressures of about 200 GPa. These record-breaking transition temperatures bring within…

Superconductivity · Physics 2020-07-15 Sabri Elatresh , T. Timusk , E. J. Nicol

Superconductivity commonly appears under pressure in charge density wave (CDW)-bearing transition metal dichalcogenides (TMDs), but has emerged so far only via either intercalation with electron donors or electrostatic doping in CDW-free…

Recently, the superconducting transition temperature Tc = 287 K has been experimentally obtained in the material composed of carbon, sulfur, and hydrogen under the high pressure of 267 GPa. The material structure is unknown yet, where the…

Superconductivity · Physics 2022-08-08 Zheng-Wei Liao , Zhen Zhang , Jing-Yang You , Bo Gu , Gang Su

We report the experimental discovery of superconductivity with critical temperature Tc above 70 K in zirconium polyhydrides, the record high so far for 3d transition metal hydrides. The superconducting zirconium polyhydrides are synthesized…

Superconductivity · Physics 2022-04-01 C. L. Zhang , X. He , Z. W. Li , S. J. Zhang , S. M. Feng , X. C. Wang , R. C. Yu , C. Q. Jin

Recent studies of hydrogen-dominant (superhydride) materials, such as LaH10 have led to putative discoveries of near-room temperature superconductivity at high pressures, with a superconducting transition temperature (Tc) of 250 K observed…

Superconductivity · Physics 2025-09-26 Xuejie Li , Wenbo zhao , Yuzhou Hao , Xiaoying Wang , Zhibin Gao , Xiangdong Ding