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Vanadium oxides are strongly correlated materials which display metal-insulator transitions as well as various structural and magnetic properties that depend heavily on oxygen stoichiometry. Therefore, it is crucial to precisely control…

Materials Science · Physics 2020-12-21 Min-Han Lee , Yoav Kalcheim , Javier del Valle , Ivan K. Schuller

We have grown VO2 thin films by laser ablation for electronic device applications. In obtaining the thin films of the pure VO2 phase, oxygen partial pressure is a critical parameter because vanadium oxides have several phases with the…

Materials Science · Physics 2007-05-23 B. G. Chae , D. H. Youn , H. T. Kim , S. Y. Maeng , K. Y. Kang

Vanadium oxide (VOx) is a material of significant interest due to its metal-insulator transition (MIT) properties as well as its diverse stable antiferromagnetism depending on the valence states of V and O with distinct MIT transitions and…

Vanadium dioxide with metal-to-insulator transition (MIT) that is triggered by heat, current or light is a promising material for modern active THz/mid-IR metasurfaces and all-optical big data processing systems. Multilayer VO2-based active…

Vanadium dioxide is a complex oxide material, which shows large resistivity and optical reflectance change while transitioning from the insulator to metal phase at ~68 {\deg}C. In this work, we use a modified atmospheric thermal oxidation…

Applied Physics · Physics 2021-05-24 P Ashok , Yogesh Singh Chauhan , Amit Verma

Pristine vanadium dioxide (VO2), an insulator-to-metal transition (IMT) material, is grown via furnace oxidation followed by rapid thermal annealing with forming gas (5%H2/95%N2) which reduces surface over-oxides such as V2O5 formed during…

Materials Science · Physics 2025-12-25 Ken Araki , Vishwa Krishna Rajan , Liping Wang

Despite widespread interest in the phase-change applications of vanadium dioxide (VO$_2$), the fabrication of high-quality VO$_2$ thin films with elevated transition temperatures (TIMT) and high Insulator-Metal-Transition resistance…

Materials Science · Physics 2024-01-01 Achintya Dutta , Ashok P , Amit Verma

Vanadium dioxide (VO2) is a phase transition material that undergoes a reversible insulator-metal phase transition at ~ 68 C. Atmospheric pressure thermal oxidation (APTO) of vanadium (V) is a simple VO2 synthesis method in which V thin…

Materials Science · Physics 2021-07-06 Ashok P , Yogesh Singh Chauhan , Amit Verma

The metal-insulator transition (MIT) in vanadium dioxide (VO2) has the potential to lead to a number of disruptive technologies, including ultra-fast data storage, optical switches, and transistors which move beyond the limitations of…

Strongly Correlated Electrons · Physics 2018-02-28 T. J. Huffman , D. J. Lahneman , S. L. Wang , T. Slusar , Bong-Jun Kim , Hyun-Tak Kim , M. M. Qazilbash

Amorphous VO$_x$ films without a hysteretic phase transition are stable with respect to thermal cycling and highly demanded as sensitive elements of the resistive thermometers and microbolometers. In this paper we present simple and…

Materials Science · Physics 2023-09-14 E. V. Tarkaeva , V. A. Ievleva , A. I. Duleba , A. V. Muratov , A. Yu. Kuntsevich

Vanadium dioxide, a well-known Mott insulator, is a highly studied electronic material with promising applications in information processing and storage. While fully crystalline layers exhibit exceptional properties, such as a sharp and…

The growth of wafer-scale and uniform monoclinic VO2 film was a challenge if considering the multivalent vanadium atom and the various phase structures of VO2 compound. Directly oxidizing metallic vanadium film in oxygen gas seemed to be an…

Materials Science · Physics 2020-05-20 H. Ren , B. Li , X. Zhou , S. Chen , Y. Li , C. Hu , J. Tian , G. Zhang , Y. Pan , C. Zou

This work reports the fabrication and characterization of high-quality tungsten-doped vanadium dioxide (WxV1-xO2, x = 0~3 at. %) by thermal oxidation of sputtered tungsten-vanadium alloyed thin films with different atomic percentages and…

Materials Science · Physics 2025-12-25 Vishwa Krishna Rajan , Ken Araki , Robert Y. Wang , Liping Wang

In this work, the results of fabricating ultra thin VO$_2$ films on the technologically relevant amorphous SiO$_2$ surface using reactive DC magnetron sputtering are presented. Results indicate that a post deposition anneal in low partial…

Materials Science · Physics 2016-08-16 Fangfang Song , B. E. White

Vanadium oxide thin films exhibit temperature-driven electronic transitions desirable for sensing and microelectronic applications, yet their performance is often limited by thermal hysteresis. This study demonstrates that electronic…

Materials Science · Physics 2025-12-03 Abhijeet Das , Ram Pratap Yadav , Rashmi Roy Karmakar , Jyoti Jaiswal , Sanjeev Kumar

We have succeeded in growing epitaxial films of rocksalt VOx on MgO(001) substrates. The oxygen content as a function of oxygen flux was determined using 18O2-RBS and the vanadium valence using XAS. The upper and lower stoichiometry limits…

Strongly Correlated Electrons · Physics 2009-09-29 A. D. Rata , A. R. Chezan , T. Hibma , M. W. Haverkort , L. H. Tjeng , H. H. Hsieh , H. J. Lin , C. T. Chen

We grew highly textured phase pure VO2 thin films on c-plane Al2O3 substrates with different oxygen partial pressure. X-ray absorption and photoemission spectroscopy confirm the identical valence state of vanadium ions despite the different…

Materials Science · Physics 2015-06-09 Salinporn Kittiwatanakul , Jude Laverock , Dave Newby , Kevin E. Smith , Stuart A. Wolf , Jiwei Lu

Phase competition in correlated oxides offers tantalizing opportunities as many intriguing physical phenomena occur near the phase transitions. Owing to a sharp metal-insulator transition (MIT) near room temperature, correlated vanadium…

We report the growth of ultrathin VO$_{2}$ films on rutile TiO$_{2}$ (001) substrates via reactive molecular-beam epitaxy. The films were formed by the cyclical deposition of amorphous vanadium and its subsequent oxidation and…

Impedance spectroscopy measurements were performed in high quality Vanadium dioxide (VO2) thin films. This technique allows us investigate the resistive and capacitive contribution to the dielectric response near the metal-insulator…

Materials Science · Physics 2011-05-24 J. -G. Ramírez , Edgar J. Patiño , Rainer Schmidt , Amos Sharoni , M. E. Gómez , Ivan K. Schuller
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