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The quadrupolar splittings of perdeuteriated n-decane dissolved in nematic phases formed by mesogenic dimers of the CBnCB series, for n=7,9,10,11 are measured throughout the entire temperature range of these phases. The results of the…

A ferroelectric monoclinic phase of space group $Cm$ ($M_A$ type) has been discovered in 0.65Pb(Mg$_{1/3}$Nb$_{2/3})O_3$-0.35PbTiO$_3$ by means of high resolution synchrotron X-ray diffraction. It appears at room temperature in a single…

Materials Science · Physics 2009-11-07 Z. -G. Ye , B. Noheda , M. Dong , D. Cox , G. Shirane

Room temperature angle-dispersive x-ray diffraction measurements on zircon-type TbVO4 and CeVO4 were performed in a diamond-anvil cell up to 50 GPa using neon as pressure-transmitting medium. In TbVO4 we found at 6.4 GPa evidence of a…

Materials Science · Physics 2012-01-26 D. Errandonea , R. S. Kumar , S. N. Achary , A. K. Tyagi

The structure of Nd$_{1-x}$Pb$_{x}$MnO$_{3}$ crystals is determined by single crystal X-ray diffraction. Substitution of Pb at the Nd site results in structural phase change from tetragonal (x = 0.25) to cubic (x = 0.37). These changes are…

Strongly Correlated Electrons · Physics 2007-05-23 Nilotpal Ghosh , Suja Elizabeth , H. L. Bhat , G. Nalini , B. Muktha , T. N. Guru Row

We present an investigation into the crystal structure of ErVO4 under variable pressure conditions. The high-pressure single crystal X-ray diffraction experiments performed employing helium as the pressure medium facilitated structure…

The effects of pressure on the crystal structure of scheelite-type perrhenates were studied using synchrotron powder X-ray diffraction and density-functional theory. At ambient conditions, the studied materials AgReO4, KReO4, and RbReO4,…

Amorphous, glass, and glass-ceramic materials practically always include a significant number (more than eight) of crystalline phases, with the contents of the latter ranging from a few wt.% to several hundredths or tenths of wt.%. The…

In the present work, a detailed analysis of the glassy behavior and the relaxation dynamics of the liquid crystal dimer {\alpha}-(4-cyanobiphenyl-4'-yloxy)-{\omega}-(1-pyrenimine-benzylidene-4'-oxy) heptane (CBO7O.Py) throughout both…

Soft Condensed Matter · Physics 2018-10-02 David O. López , Josep Salud , María Rosario de la Fuente , Nerea Sebastián , Sergio Diez-Berart

We propose a survey of those oxadiazole compounds, which are mesogenic. We will see that they can have bend-shaped molecules, a biaxial nematic phase, or other interesting peculiarities in the nematic and smectic phase. With large electric…

Soft Condensed Matter · Physics 2008-12-04 Amelia Sparavigna

The continuous nematic to smectic-A (N-SmA) phase transition has been studied by high-resolution ac-calorimetry in binary mixtures of the liquid crystal octylcyanobiphenyl(8CB) and a non-mesogenic, low-molecular weight, solvent…

Soft Condensed Matter · Physics 2015-05-19 Krishna P Sigdel , Germano S Iannacchione

In-plane temperature dependent dielectric behavior of BiFeO3 (BFO) as-grown thin films show diffuse but prominent phase transitions near 450 (+/-10) K and 550 K with dielectric loss temperature dependences that suggest skin layer effects.…

Materials Science · Physics 2015-06-04 Ashok Kumar , J. F. Scott , R. Martinez , G. Srinivasan , R. S. Katiyar

Here we report successful growth of mm scale single crystals of stoichiometric FeSc2S4. Single crystal X-ray diffraction yields a cubic structure, spacegroup Fd-3m, with a=10.5097(2) angstroms at T=110(2) K consistent with previous…

Materials Science · Physics 2016-09-07 Jennifer R. Morey , Kemp W. Plumb , Chris M. Pasco , Tyrel M. McQueen , Seyed M. Koohpayeh

We used low-temperature synchrotron x-ray diffraction to investigate the structural phase transitions of Fe1+yTe in the vicinity of a tricitical point in the phase diagram. Detailed analysis of the powder diffraction patterns and…

Superconductivity · Physics 2013-10-03 Cevriye Koz , Sahana Rößler , Alexander A. Tsirlin , Steffen Wirth , Ulrich Schwarz

Pentacene crystallizes in a layered structure with a herringbone arrangement within the layers. The electronic properties depend strongly on the stacking of the molecules within the layers (Haddon et al., 2002). We have synthesized four…

(Bi1-xSbx)2Te3 (x=0.60, 0.65, 0.68, 0.70, 0.75 and 0.80) mixed crystals have been synthesized by solid state reaction. In depth structural, thermal, transport and electronic properties are reported. Defect and disorder play a crucial role…

Applied Physics · Physics 2021-08-03 K. Malik , S. Mahakal , Diptasikha Das , Aritra Banerjee , S. Chatterjee , Anusree Das

We have studied the effects of quenched random disorder created by dispersed aerosil nanoparticle gels on the nematic to smectic-A (N-SmA) and smectic-A to reentrant nematic (SmA- RN) phase transitions of thermotropic liquid crystal…

Soft Condensed Matter · Physics 2009-11-13 M. Ramazanoglu , S. Larochelle , C. W. Garland , R. J. Birgeneau

We investigate the swelling and shrinking of L_beta lamellar gel phases composed of surfactant and fatty alcohol after contact with aqueous poly(ethylene-glycol) solutions. The height change $\Delta h(t)$ is diffusion-like with a swelling…

Soft Condensed Matter · Physics 2011-05-11 David J Fairhurst , Mark E Baker , Neil Shaw , Stefan U. Egelhaaf

This paper complements a previous study of the isotropic and nematic phases of the Gay-Berne liquid-crystal model [Mehri et al., Phys. Rev. E 105, 064703 (2022)] with a study of its smectic B phase found at high density and low…

Soft Condensed Matter · Physics 2023-12-12 Saeed Mehri , Jeppe C. Dyre , Trond S. Ingebrigtsen

We present an x-ray study of freely suspended hexatic films of the liquid crystal 3(10)OBC. Our results reveal spatial inhomogeneities of the bond-orientational (BO) order in the vicinity of the hexatic-smectic phase transition and the…

We present an experimental study of the surface effects (interactions with the container walls) during the nucleation and growth of smectic B crystals from the nematic in free growth and directional solidification of a mesogenic molecule…

Soft Condensed Matter · Physics 2015-06-24 T. Borzsonyi , S. Akamatsu
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