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A multi-high-frequency electron paramagnetic resonance method is used to probe the magnetic excitations of a dimer of single-molecule magnets. The measured spectra display well resolved quantum transitions involving coherent superposition…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 S. Hill , R. S. Edwards , N. Aliaga-Alcalde , G. Christou

Quantum entanglement effects between the electronic spin and charge degrees of freedom are examined in an organic molecular solid, termed a dimer-Mott insulating system, in which molecular dimers are arranged in a crystal as fundamental…

Strongly Correlated Electrons · Physics 2016-05-18 Makoto Naka , Sumio Ishihara

Laterally coupled quantum dot molecules are studied using exact diagonalization techniques. We examine the two-electron singlet-triplet energy difference as a function of magnetic field strength and investigate the magnetization and vortex…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Helle , A. Harju , R. M. Nieminen

This chapter takes a microscopic view of quantum tunneling of magnetization (QTM) in single-molecule magnets (SMMs), focusing on the interplay between exchange and anisotropy. Careful consideration is given to the relationship between…

Mesoscale and Nanoscale Physics · Physics 2013-03-04 Junjie Liu , Enrique del Barco , Stephen Hill

The dimeric form of the single-molecule magnet [Mn$_4$O$_3$Cl$_4$(O$_2$CEt)$_3$(py)$_3$]$_2$ recently revealed interesting phenomena: no quantum tunneling at zero field and tunneling before magnetic field reversal. This is attributed to…

A new family of supramolecular, antiferromagnetically exchange-coupled dimers of single-molecule magnets (SMMs) has recently been reported [W. Wernsdorfer, N. Aliaga-Alcalde, D.N. Hendrickson, and G. Christou, Nature 416, 406 (2002)]. Each…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 R. Tiron , W. Wernsdorfer , D. Foguet-Albiol , N. Aliaga-Alcalde , G. Christou

The synthesis of molecular magnets has undergone rapid progress in recent years. Each of the identical molecular units can contain as few as two and up to several dozens of paramagnetic ions (spins). Although these materials appear as…

Strongly Correlated Electrons · Physics 2009-11-11 J. Schnack

We study interaction effects on the orbital magnetism of diffusive mesoscopic quantum systems. By combining many-body perturbation theory with semiclassical techniques, we show that the interaction contribution to the ensemble averaged…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 D. Ullmo , K. Richter , H. U. Baranger , F. von Oppen , R. A. Jalabert

A new type of the single-molecule magnet [Mn_4 O_3 Cl_4 (O_2 CEt)_3(py)_3] forms dimers. Recent magnetic hysteresis measurements on this single-molecular magnet revealed interesting phenomena: an absence of quantum tunneling at zero…

Materials Science · Physics 2009-11-10 Kyungwha Park , Mark R. Pederson , Noam Bernstein

We investigate theoretically the long-range electrostatic interactions between a ground-state homonuclear alkali-metal dimer and an excited alkali-metal atom taking into account its fine-structure. The interaction involves the combination…

Chemical Physics · Physics 2017-09-13 Maxence Lepers , Olivier Dulieu

We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to…

Quantum Physics · Physics 2016-09-28 Milan Sindelka , Nimrod Moiseyev

We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…

Quantum Physics · Physics 2024-09-24 Felipe Isaule , Robert Bennett , Jörg B. Götte

Magnetic molecules are a class of compounds that is also investigated in view of their magnetocaloric properties. The isothermal entropy change and the adiabatic temperature change are key figures of merit for magnetocaloric performance.…

Chemical Physics · Physics 2026-02-23 D. Westerbeck , J. Schnack

We discuss how quantum dimer models may be used to provide "proofs of principle" for the existence of exotic magnetic phases in quantum spin systems.

Strongly Correlated Electrons · Physics 2015-05-13 K. S. Raman , E. Fradkin , R. Moessner , S. Papanikolaou , S. L. Sondhi

We analyze the phases of an S=1/2 spin model on a lattice of coupled tetrahedra. The presence of both Heisenberg and antisymmetric, Dzyaloshinsky-Moriya interactions can lead to two types of symmetry-broken states: non-magnetic dimer order…

Strongly Correlated Electrons · Physics 2016-08-31 Valeri N. Kotov , Michael E. Zhitomirsky , Maged Elhajal , Frederic Mila

In this study the magnetization phenomenon has been investigated as a behavior of interacting elementary moments ensemble, with the help of Ising model [1] in the frame of non-extensive statistical mechanics. To investigate the physical…

Statistical Mechanics · Physics 2007-05-23 M. Karabekirogullari , F. Buyukkilic , D. Demirhan

We show that a double quantum-dot system made of diluted magnetic semiconductor behaves unlike usual molecules. In a semiconductor double quantum dot or in a diatomic molecule, the ground state of a single carrier is described by a…

Other Condensed Matter · Physics 2009-11-11 Wei Zhang , Tianming Dong , Alexander O. Govorov

We present a study of systems of single-molecule magnets using a semiclassical analysis and catastrophe theory. Separatrices in parameter space are constructed which are useful to determine the structure of the Hamiltonians energy levels.…

Quantum Physics · Physics 2023-06-21 David Stefan , Lohr-Robles , Enrique , Lopez-Moreno , Peter Otto Hess

The spectral properties of up to four interacting electrons confined within a quasi one--dimensional system of finite length are determined by numerical diagonalization including the spin degree of freedom. The ground state energy is…

Condensed Matter · Physics 2009-10-22 Wolfgang Haeusler , Bernhard Kramer , PTB Braunschweig

We study the thermal entanglement in the two-qubit anisotropic XXZ model and the Heisenberg model with Dzyaloshinski-Moriya (DM) interactions. The DM interaction is another kind of anisotropic antisymmetric exchange interaction. The effects…

Quantum Physics · Physics 2009-11-07 Xiaoguang Wang
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