Related papers: Mechanism of the Cassie-Wenzel transition via the …
A liquid in contact with a textured surface can be found in two states, Wenzel and Cassie. In the Wenzel state the liquid completely wets the corrugations while in the Cassie state the liquid is suspended over the corrugations with air or…
Understanding the critical condition and mechanism of the droplet wetting transition between Cassie-Baxter state and Wenzel state triggered by an external electric field is of considerable importance because of its numerous applications in…
Wetting is often perceived as an intrinsic surface property of materials, but determining its evolution is complicated by its complex dependence on roughness across the scales. The Wenzel state, where liquids have intimate contact with the…
Micro-patterned surfaces have attracted significant attention in numerous applications owing to their potential to enhance hydrophobic and icephobic properties. A Cassie state of final wetting of a droplet upon impact on a micro-patterned…
In this contribution we study wetting and nucleation of vapor bubbles on nanodecorated surfaces via free energy molecular dynamics simulations. The results shed light on the stability of superhydrophobicity in submerged surfaces with…
The water-repellence properties of superhydrophobic surfaces make them promising for many applications. However, in some extreme environments, such as high humidities and low temperatures, condensation on the surface is inevitable, which…
We generalize the string method, originally designed for the study of thermally activated rare events, to the calculation of quantum tunneling rates. This generalization is based on the analogy between quantum mechanics and statistical…
This paper proposes a diffusive wetting model for the weakly-compressible smoothed particle hydrodynamics (WCSPH) method to simulate individual water entry/exit as well as the complete process from water entry to exit. The model is composed…
We present a new and efficient method for computing the transition pathways, free energy barriers, and transition rates in complex systems with relatively smooth energy landscapes. The method proceeds by evolving strings, i.e. smooth curves…
A charge density wave (CDW) is one of the fundamental instabilities of the Fermi surface occurring in a wide range of quantum materials. In dimensions higher than one, where Fermi surface nesting can play only a limited role, the selection…
We present in this Letter a free-energy approach to the dynamics of a fluid near a nanostructured surface. The model accounts both for the static phase equilibrium in the vicinity of the surface (wetting angles, Cassie-Wenzel transition)…
Liquid drops on textured surfaces show different dynamical behaviors depending on their wetting states. They are extremely mobile when they are supported by composite solid-liquid-air interfaces (Cassie-Baxter state) and immobile when they…
In this article, we generalize Wenzel law, which assigns an effective contact angle for a droplet on a rough substrate, when the wetting layer has an ordered phase, like a nematic. We estimate the conditions for which the wetting behavior…
The Cassie-Wenzel transition of a symmetric binary liquid mixture in contact with a nano-corrugated wall is studied. The corrugation consists of a periodic array of nano-pits with square cross sections. The substrate potential is the sum…
Classical density functional theory is applied to investigate the validity of a phenomenological force-balance description of the stability of the Cassie state of liquids on substrates with nanoscale corrugation. A bulk free-energy…
We investigate directly at the microscale the morphology of the electrowetting induced transition between the Cassie-Baxter and Wenzel states for a water droplet on a superhydrophobic surface. Our experiments demonstrate that the transition…
A novel and powerful method is presented for the study of rare switching events in complex systems with multiscale energy landscapes. The method performs an umbrella sampling of the equilibrium distribution of the system in hyperplanes…
Rare transition events in meta-stable systems under noisy fluctuations are crucial for many non-equilibrium physical and chemical processes. In these processes, the primary contributions to reactive flux are predominantly near the…
Super-antiwettability is an extreme situation of wetting where liquids stay at the tops of rough surfaces, in the so-called Cassie state1. Owing to the dramatic reduction of solid/liquid contact, it has many applications, such as…
When a drop of water is placed on a rough surface, there are two possible extreme regimes of wetting: the one called Cassie-Baxter (CB) with air pockets trapped underneath the droplet and the one characterized by the homogeneous wetting of…