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Recently developed electronic pre-resonance stimulated Raman scattering (epr-SRS) microscopy, in which the Raman signal of a dye is significantly boosted by setting the incident laser frequency near the electronic excitation energy, has…

Chemical Physics · Physics 2023-03-10 Jiajun Du , Xuecheng Tao , Tomislav Begušić , Lu Wei

Nanoscale gaps between adjacent metallic nanostructures give rise to extraordinarily large field enhancements, known as "hot spots", upon illumination. Incident light with the electric field polarized across the gap (along the interparticle…

Mesoscale and Nanoscale Physics · Physics 2013-03-27 Joseph B. Herzog , Mark W. Knight , Yajing Li , Kenneth M. Evans , Naomi J. Halas , Douglas Natelson

We study the effects of chemical bonding on Raman scattering from benzenethiol chemisorbed on silver clusters using time-dependent density functional theory (TDDFT). Raman scattering cross sections are computed using a formalism that…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Semion K. Saikin , Roberto Olivares-Amaya , Dmitrij Rappoport , Michael Stopa , Alán Aspuru-Guzik

Surface Quasi-Elastic Light Scattering (SQELS) is an application of dynamic light scattering to measure the dynamics of the thermal roughness of liquid surfaces. An analysis of the spectrum of thermal fluctuations provides information on…

Soft Condensed Matter · Physics 2007-05-23 Pietro Cicuta , Ian Hopkinson

Photo-Induced Enhanced Raman Spectroscopy (PIERS) is a new surface enhanced Raman spectroscopy (SERS) modality with an order-of-magnitude Raman signal enhancement of adsorbed analytes over that of typical SERS substrates. Despite the…

Materials Science · Physics 2021-06-01 Junzhi Ye , Rakesh Arul , Michel K. Nieuwoudt , Junzhe Dong , Wei Gao , M. Cather Simpson

We report measurements of enhanced tensor polarization on solid-state targets. The results here represent an increase in tensor polarization over that previously achieved in high energy and nuclear scattering experiments that focused on the…

Instrumentation and Detectors · Physics 2020-08-24 Dustin Keller , Don Crabb , Donal Day

It is an established understanding that the electromagnetic contribution (the plasmon-mediated enhancement of the laser and scattered local electromagnetic fields) is the main actor in Surface Enhanced Raman Scattering (SERS), with the…

We use dynamical mean field theory to find an exact solution for inelastic light scattering in strongly correlated materials such as those near a quantum-critical metal-insulator transition. We evaluate the results for $\textbf{q}=0$…

Strongly Correlated Electrons · Physics 2009-11-10 A. M. Shvaika , O. Vorobyov , J. K. Freericks , T. P. Devereaux

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

The dichroism and birefringence effects in stumulated Raman scattering (SRS) in polyatomic molecules were studied theoretically. General expressions have been derived describing the change of the intensity and polarization of the probe…

Chemical Physics · Physics 2023-11-07 Bogdan V. Semak , Yaroslav M. Beltukov , Oleg S. Vasyutinskii

Speckle patterns produced by disordered scattering systems exhibit a sensitivity to addition of individual particles which can be used for sensing applications. Using a coupled dipole model we investigate how multiple scattering can enhance…

Optics · Physics 2021-08-03 Joel Berk , Matthew R. Foreman

Harmonic generation in the scattered fields produced by a dielectric sphere coated with a time-varying conductive shell is studied using a Mie theory approach hybridized with conversion matrix methods. Analytic results are derived for plane…

Optics · Physics 2022-09-21 Kurt Schab , Bradley Shirley , K. C. Kerby-Patel

Lack of inversion symmetry in metals breaks SU(2) symmetry which results in spin-splitting of the electronic states at the Fermi level due to various types of spin-orbit coupling (SOC) such as Dresselhaus, Rashba, or Ising (also called…

Mesoscale and Nanoscale Physics · Physics 2026-04-02 Mojdeh Saleh , Saurabh Maiti

A consistent semiquantitative theoretical analysis of electronic Raman scattering from many-electron quantum dots under resonance excitation conditions has been performed. The theory is based on random-phase-approximation-like wave…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Alain Delgado , Augusto Gonzalez , D. J. Lockwood

We study the modification of the far-field cross sections and the near-field enhancement for gold and silver nanospheres illuminated by a tightly focused beam. Using a multipole-expansion approach we obtain an analytical solution to the…

Optics · Physics 2008-04-02 Nassiredin M. Mojarad , Vahid Sandoghdar , Mario Agio

Stimulated Raman scattering (SRS) has played an increasingly pivotal role in chemistry and photonics. Recently, understanding of light-molecule interaction during SRS was brought to a new quantitative level through the introduction of…

Chemical Physics · Physics 2023-12-13 Wei Min , Xin Gao

The theory of surface electromagnetic waves (SEMWs) propagating at optical frequencies along the interface of an isotropic noble metal [e.g., gold (Au)] and a uniaxial crystal [e.g., Rutile (TiO$_2$)] is revisited with the Drude-Lorentz…

Applied Physics · Physics 2020-12-30 A. P. Misra , M. Shahmansouri , N. Khoddam

The polarization of radiation by scattering on an atom embedded in combined external quadrupole electric and uniform magnetic fields is studied theoretically. Analytic formulae are derived for the scattering phase matrix. Limiting cases of…

Astrophysics · Physics 2007-05-23 Yee Yee Oo , K. N. Nagendra , Sharath Ananthamurthy , G. Ramachandran

In the quantum process of stimulated Raman scattering (SRS), a laser photon propagating in a resonance medium undergoes multifold conversions into a Stokes photon and back. The nontrivial ``cooperative'' behavior of the Stokes component of…

Quantum Physics · Physics 2007-05-23 Valery I. Rupasov

We explain quantitatively why resonant Raman scattering spectroscopy, an extensively used experimental tool in studying elementary electronic excitations in doped low dimensional semiconductor nanostructures, always produces an observable…

Strongly Correlated Electrons · Physics 2009-10-31 S. Das Sarma , Daw-Wei Wang