Related papers: The Theory of Surface Enhanced Hyper Raman Scatter…
The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some models of rough metal surfaces and of some features of the dipole…
The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some models of rough metal surfaces and of some features of the dipole…
The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of the strongly irregular surface roughness. The main SERS…
The expression for the SEHR cross-section of symmetrical molecules within the framework of the dipole-quadrupole theory is obtained. It is formed by contributions, which depend on various dipole and quadrupole moments. Estimation of the…
The paper analyses the SEHR spectra of symmetrical molecules on the base of the dipole-quadrupole SEHRS theory. Existence of the bands, caused by vibrations transforming after the unit irreducible representations of corresponding symmetry…
The paper presents briefly some general points of the theory of Surface Enhanced Raman Scattering on metals, semiconductors, dielectrics and graphene. It is pointed out that the reason of SERS on graphene and some other 2D materials is not…
It is demonstrated that explanation of appearance of strong forbidden lines in the SEHR spectra of pyrazine and phenazine, caused by totally symmetric vibrations and also other details of their SER and SEHR spectra can be made on the base…
Surface Enhanced Raman Scattering (SERS) and Surface-Enhanced Fluorescence (SEF) are studied within the framework of modified Spontaneous Emission (SE), and similarities and differences are highlighted. This description sheds new light into…
The paper presents main aspects of the Dipole-Quadrupole theory of Surface Enhanced Infrared Absorption (SEIRA). It is pointed out the possibility of appearance of the lines, caused by totally symmetric vibrations transforming after the…
The spectral relationships between surface enhanced resonant Raman scattering (SERRS) and plasmon resonance observed in far field scattering cross are investigated using single silver nanoparticle dimers with focusing on the lowest energy…
It is demonstrated in the framework of the Dipole-Quadrupole theory, that strong quadrupole light-molecule interaction, which is responsible for the most enhancement of SEHRS in the methane molecule, which belongs to the symmetry group,…
We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…
The long-range action of surface-enhanced Raman scattering (SERS) is probed via distance-dependent measurements of molecular Raman spectra. To this end, identical SERS substrates composed of irregular silver nanoisland arrays were covered…
We present an in-depth analysis of the experimental estimation of cross sections in Surface Enhanced Raman Scattering (SERS) by vibrational pumping. The paper highlights the advantages and disadvantages of the technique, pinpoints the main…
We provide the theoretical framework to understand the phenomenology and statistics of single-molecule (SM) signals arising in Surface-Enhanced Raman Scattering (SERS) under the presence of so-called electromagnetic hot-spots (HS's). We…
The present approach to SERS does not rely on a hihj electrical conductivity substrate or admixture to enable the SERS process. The novelty of our method is to create an artificial periodic electron distribution on a surface by illumination…
We examine SERS from two perspectives: as a phenomenon described by the Laplace Equation (the electrostatic or Rayleigh limit) and by the Helmholtz Equation (electrodynamic or Mie limit). We formulate the problem in terms of the scalar…
The SEHRS and SERS spactra of 4,4 - Bipyridine are analyzed on the base of the Dipole-Quadrupole theory for two possible geometries of the molecule. It is demonstrated that there appear strong lines caused by vibrations transforming after a…
The low efficiency of Raman spectroscopy can be overcome by placing the active molecules in the vicinity of scatterers, typically rough surfaces or nanostructures with various shapes. This surface-enhanced Raman scattering (SERS) leads to…
The interaction between molecules is commonly ignored in surface-enhanced Raman scattering (SERS). Under this assumption, the total SERS signal is described as the sum of the individual contributions of each molecule treated independently.…