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We report the experimental observation of the rotation of the polarization plane of light propagating in a gas of fast-spinning molecules (molecular super-rotors). In the observed effect, related to Fermi's prediction of "polarization drag"…

Atomic Physics · Physics 2021-08-18 Alexander A. Milner , Uri Steinitz , Ilya Sh. Averbukh , Valery Milner

We study the dynamics of paramagnetic molecular superrotors in an external magnetic field. Optical centrifuge is used to create dense ensembles of oxygen molecules in ultra-high rotational states. It is shown for the first time, that the…

Quantum Physics · Physics 2015-06-10 A. A. Milner , A. Korobenko , J. Floß , I. Sh. Averbukh , V. Milner

We investigate experimentally the effect of quantum resonance in the rotational excitation of the simplest quantum rotor - a diatomic molecule. By using the techniques of high-resolution femtosecond pulse shaping and rotational…

Quantum Physics · Physics 2013-05-30 S. Zhdanovich , C. Bloomquist , J. Floß , I. Sh. Averbukh , J. W. Hepburn , V. Milner

The formation of diatomic molecules with rotational and vibrational coherence is demonstrated experimentally in free-to-bound two-photon femtosecond photoassociation of hot atoms. In a thermal gas at a temperature of 1000 K, pairs of…

Single molecule spectroscopy aims at unveiling often hidden but potentially very important contributions of single entities to a system's ensemble response. Albeit contributing tremendously to our ever growing understanding of molecular…

Chemical Physics · Physics 2017-12-19 Matz Liebel , Costanza Toninelli , Niek F. van Hulst

We investigate how vibration affects molecular photoemission dynamics, through simulations on two-dimension asymmetric model molecules including the electronic and nuclear motions in a fully correlated way. We show that a slight anisotropy…

Chemical Physics · Physics 2024-02-14 Antoine Desrier , Morgan Berkane , Camille Lévêque , Richard Taïeb , Jérémie Caillat

We provide a vivid demonstration of the mechanical effect of transverse spin momentum in an optical beam in free space. This component of the Poynting momentum was previously thought to be virtual, and unmeasurable. Here, its effect is…

Optics · Physics 2018-06-29 V. Svak , O. Brobohaty , M. Siler , P. Jakl , J. Kanka , P. Zemanek , S. H. Simpson

High harmonic light sources make it possible to access attosecond time-scales, thus opening up the prospect of manipulating electronic wave packets for steering molecular dynamics. However, two decades after the birth of attosecond physics,…

The generation of unidirectional motion has been a long-standing challenge in engineering of molecular motors and, more generally, machines. A molecular motor is characterized by a set of low energy states that differ in their…

We produce oriented rotational wave packets in CO and measure their characteristics via high harmonic generation. The wavepacket is created using an intense, femtosecond laser pulse and its second harmonic. A delayed 800 nm pulse probes the…

We study the quantum dynamics of a material wavepacket bouncing off a modulated atomic mirror in the presence of a gravitational field. We find the occurrence of coherent accelerated dynamics for atoms beyond the familiar regime of…

Quantum Physics · Physics 2015-06-26 Farhan Saif , Pierre Meystre

We describe a pulsed rotating supersonic beam source, evolved from an ancestral device [M. Gupta and D. Herschbach, J. Phys. Chem. A 105, 1626 (2001)]. The beam emerges from a nozzle near the tip of a hollow rotor which can be spun at…

Vibrational dynamics in conventional molecules usually takes place on a timescale of picoseconds or shorter. A striking exception are ultralong-range Rydberg molecules, for which dynamics is dramatically slowed down as a consequence of the…

The nuclear spin, being much more isolated from the environment than its electronic counterpart, enables quantum experiments with prolonged coherence times and presents a gateway towards uncovering the intricate dynamics within an atom.…

Mesoscale and Nanoscale Physics · Physics 2023-09-08 Lukas M. Veldman , Evert W. Stolte , Mark P. Canavan , Rik Broekhoven , Philip Willke , Laëtitia Farinacci , Sander Otte

Hyperfine interaction of electron spins with nuclear spins, in coupled double quantum dots is studied. Results of successive electron spin measurements exhibit bunching due to correlations induced via the nuclear spins. Further nuclear…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Ozgur Cakir , Toshihide Takagahara

Semiclassical catastrophes in the dynamics of a quantum rotor (molecule) driven by a strong time-varying field are considered. We show that for strong enough fields, a sharp peak in the rotor angular distribution can be achieved via…

Quantum Physics · Physics 2007-05-23 I. Sh. Averbukh , R. Arvieu , M. Leibscher

We propose a novel platform for the investigation of quantum wave packet dynamics, offering a complementary approach to existing theoretical models and experimental systems. It relies on laser-cooled neutral atoms which orbit around an…

Quantum Physics · Physics 2013-06-11 Fam Le Kien , Kohzo Hakuta , Philipp Schneeweiss , Arno Rauschenbeutel

Understanding molecular state evolution is central to many disciplines, including molecular dynamics, precision measurement, and molecule-based quantum technology. Details of the evolution are obscured when observing a statistical ensemble…

Atomic Physics · Physics 2024-08-05 Yu Liu , Julian Schmidt , Zhimin Liu , David R. Leibrandt , Dietrich Leibfried , Chin-wen Chou

Conventional approaches to probing ultrafast molecular dynamics rely on the use of synchronized laser pulses with a well-defined time delay. Typically, a pump pulse excites a wavepacket in the molecule. A subsequent probe pulse can then…

Mesoscale and Nanoscale Physics · Physics 2020-03-27 R. E. F. Silva , Javier del Pino , Francisco J. García-Vidal , Johannes Feist

Quantum light spectroscopy, providing novel molecular information non-accessible by classical light, necessitates new computational tools when applied for complex molecular systems. We introduce two computational protocols for the molecular…

Chemical Physics · Physics 2021-09-14 Bing Gu , Daniel Keefer , Shaul Mukamel