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All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory which accounts for interactions between chemical species within a…

Statistical Mechanics · Physics 2021-03-09 Francesco Avanzini , Emanuele Penocchio , Gianmaria Falasco , Massimiliano Esposito

Quantum thermodynamics is an emerging research field aiming to extend standard thermodynamics and non-equilibrium statistical physics to ensembles of sizes well below the thermodynamic limit, in non-equilibrium situations, and with the full…

Quantum Physics · Physics 2017-07-05 Sai Vinjanampathy , Janet Anders

We apply the framework of non-equilibrium quantum thermodynamics to the physics of quenched small-sized bosonic quantum gases in a one-dimensional harmonic trap. We show that dynamical orthogonality can occur in these few-body systems with…

Dealing with a generic time-local non-Markovian master equation, we define current and power to be process-dependent as in classical thermodynamics. Each process is characterized by a symmetry transformation, a gauge of the master equation,…

Quantum Physics · Physics 2023-08-01 Fernando Nicacio , Raphael N. P. Maia

The quantum-mechanical and thermodynamic properties of a 3-level molecular cooling cycle are derived. An inadequacy of earlier models is rectified in accounting for the spontaneous emission and absorption associated with the coupling to the…

Quantum Physics · Physics 2009-11-07 Jose P. Palao , Ronnie Kosloff , Jeffrey M. Gordon

The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime,…

Statistical Mechanics · Physics 2016-06-29 Kay Brandner , Udo Seifert

The nonequilibrium description of quantum systems requires, for more than two or three particles, the use of a reduced description to be numerically tractable. Two possible approaches are based on either reduced density matrices or…

Strongly Correlated Electrons · Physics 2013-09-19 S. Hermanns , K. Balzer , M. Bonitz

We initially prepare a quantum linear oscillator weakly coupled to a bath in equilibrium at an arbitrary temperature. We disturb this system by varying a Hamiltonian parameter of the coupled oscillator, namely, either its spring constant or…

Statistical Mechanics · Physics 2015-05-27 Ilki Kim

A key objective in nuclear and high-energy physics is to describe nonequilibrium dynamics of matter, e.g., in the early universe and in particle colliders, starting from the Standard Model. Classical-computing methods, via the framework of…

This review presents a thermodynamic perspective on quantum coupled transport processes in nanoscale systems. Our analysis is formulated within the framework of entropy production rate, the central quantity governing non-equilibrium…

Quantum Physics · Physics 2026-03-09 Shuvadip Ghosh , Arnab Ghosh

Thermodynamics is a branch of science blessed by an unparalleled combination of generality of scope and formal simplicity. Based on few natural assumptions together with the four laws, it sets the boundaries between possible and impossible…

Quantum Physics · Physics 2014-02-06 Luis A. Correa , José P. Palao , Daniel Alonso , Gerardo Adesso

Quantum thermodynamics aims at investigating both the emergence and the limits of the laws of thermodynamics from a quantum mechanical microscopic approach. In this scenario, thermodynamic processes with no heat exchange, namely, adiabatic…

We define thermodynamic configurations and identify two primitives of discrete quantum processes between configurations for which heat and work can be defined in a natural way. This allows us to uncover a general second law for any discrete…

Quantum Physics · Physics 2015-06-12 Janet Anders , Vittorio Giovannetti

Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi

The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and…

Quantum Physics · Physics 2024-10-25 Alberto Rolandi

Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as…

Quantum Physics · Physics 2016-01-13 James Millen , André Xuereb

It is well known that quantum feedback can alter the dynamics of open quantum systems dramatically. In this paper, we show that non-ergodicity may be induced through quantum feedback and resultantly create system dynamics that have lasting…

Quantum Physics · Physics 2020-07-02 Lewis A. Clark , Fiona Torzewska , Ben Maybee , Almut Beige

Quantum decoherence is seen as an undesired source of irreversibility that destroys quantum resources. Quantum coherences seem to be a property that vanishes at thermodynamic equilibrium. Away from equilibrium, quantum coherences challenge…

Quantum Physics · Physics 2013-08-13 César A. Rodríguez-Rosario , Thomas Frauenheim , Alán Aspuru-Guzik

Quantum thermodynamics supplies a consistent description of quantum heat engines and refrigerators up to the level of a single few level system coupled to the environment. Once the environment is split into three;a hot, cold and work…

Quantum Physics · Physics 2015-04-17 Ronnie Kosloff , Amikam Levy

The thermodynamics and covariant kinetic theory have been elaborately investigated in a non-extensive environment considering the non-extensive generalization of Bose-Einstein (BE) and Fermi-Dirac (FD) statistics. Starting with Tsallis'…

Nuclear Theory · Physics 2018-02-08 Sukanya Mitra