Related papers: Large deviations and the Boltzmann entropy formula
Superstatistics generalizes Boltzmann statistics by assuming spatio-temporal fluctuations of the intensive variables. It has many applications in the analysis of experimental and simulated data. The fluctuation of the intensity variable is…
In two respects Ludwig Boltzmann was a pioneer of quantum mechanics. First because in his statistical interpretation of the second law of thermodynamics he introduced the theory of probability into a fundamental law of physics and thus…
We develop a rigorous theory of hard-sphere dynamics in the kinetic regime, away from thermal equilibrium. In the low density limit, the empirical density obeys a law of large numbers and the dynamics is governed by the Boltzmann equation.…
The theory of large deviations deals with the probabilities of rare events (or fluctuations) that are exponentially small as a function of some parameter, e.g., the number of random components of a system, the time over which a stochastic…
A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the…
We present a mathematical theory of dynamical fluctuations for the hard sphere gas in the Boltzmann-Grad limit. We prove that: (1) fluctuations of the empirical measure from the solution of the Boltzmann equation, scaled with the square…
The structure of very complicated irregular "microscopic" (local) entropy fluctuations around a big separated "macroscopic" (global) fluctuation in the statistical equilibrium was studied in numerical experiments on a simple 2--freedom…
A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…
Quantum mechanics and classical statistical mechanics are two physical theories that share several analogies in their mathematical apparatus and physical foundations. In particular, classical statistical mechanics is hallmarked by the…
This paper gives a short review of the history of statistical physics starting from D. Bernoulli's kinetic theory of gases in the 18th century until the recent new developments in nonequilibrium kinetic theory in the last decades of this…
These notes are a written version of lectures given in the 2024 Les Houches Summer School on {\it Large deviations and applications}. They are are based on a series of works published over the last 25 years on steady properties of…
In this brief note I address the question not frequently asked, namely, why did it take two decades between Einstein's first proposal of photons and derivation of the full Planck formula from first principles of Statistical Mechanics,…
I will argue, pace a great many of my contemporaries, that there's something right about Boltzmann's attempt to ground the second law of thermodynamics in a suitably amended deterministic time-reversal invariant classical dynamics, and that…
Using the information current, we develop a Lorentz-covariant framework for modeling equilibrium fluctuations in relativistic kinetic theory in the grand-canonical ensemble. The resulting stochastic theory is proven to be causal and…
In recent work [1] we uncovered intriguing connections between Otto's characterisation of diffusion as entropic gradient flow [16] on one hand and large-deviation principles describing the microscopic picture (Brownian motion) on the other.…
Stefan-Boltzmann law was empirically deduced by Stefan in 1874 by fitting existing experiments and theoretically validated by Boltzmann in 1884 on the basis of a classical model involving thermodynamics principles and the Maxwell equations.…
Large deviation theory (LDT) provides a mathematical framework to quantify the probabilities of rare events in stochastic systems. In this study, we applied LDT to model a chemical reaction system and demonstrated that the fluctuation…
We present numerical investigations into the question of the validity of the Boltzmann prescription in Statistical Mechanics for large systems, addressing the issue of whether extensivity of energy implies the extensivity of the Boltzmann…
Boltzmann's principle S=k ln W allows to extend equilibrium thermo-statistics to ``Small'' systems without invoking the thermodynamic limit. The clue is to base statistical probability on ensemble averaging and not on time averaging. It is…
We briefly review a perspective along which the Boltzmann-Gibbs statistical mechanics, the strongly chaotic dynamical systems, and the Schroedinger, Klein-Gordon and Dirac partial differential equations are seen as linear physics, and are…