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We report a single-crystal neutron diffraction study of the layered $\rm Sr_2IrO_4$. This work unambiguously determines the magnetic structure of the system and reveals that the spin orientation rigidly tracks the staggered rotation of the…

Strongly Correlated Electrons · Physics 2013-04-23 Feng Ye , Songxue Chi , Bryan C. Chakoumakos , Jaime A. Fernandez-Baca , Tongfei Qi , G. Cao

An anomalous optical second-harmonic generation (SHG) signal was previously reported in Sr$_2$IrO$_4$ and attributed to a hidden odd-parity bulk magnetic state. Here we investigate the origin of this SHG signal using a combination of bulk…

Strongly Correlated Electrons · Physics 2020-11-25 K. L. Seyler , A. de la Torre , Z. Porter , E. Zoghlin , R. Polski , M. Nguyen , S. Nadj-Perge , S. D. Wilson , D. Hsieh

At room temperature, the normal oxide spinels NiCr_2O_4 and CuCr_2O_4 are tetragonally distorted and crystallize in the I4_1/amd space group due to cooperative Jahn-Teller ordering driven by the orbital degeneracy of tetrahedral Ni$^{2+}$…

Materials Science · Physics 2012-09-11 Matthew R. Suchomel , Daniel P. Shoemaker , Lynn Ribaud , Moureen C. Kemei , Ram Seshadri

Sr2IrO4 is a prototype of the class of Mott insulators in the strong spin-orbit interaction (SOI) limit described by a $J_{\mathrm{eff}}=1/2$ ground state. In Sr2IrO4, the strong SOI is predicted to manifest itself in the slaving of the…

Strongly Correlated Electrons · Physics 2013-09-30 S. Boseggia , H. C. Walker , J. Vale , R. Springell , Z. Feng , M. Moretti Sala , H. M. Rønnow , S. P. Collins , D. F. McMorrow

Neutron single crystal diffraction and rotational anisotropy optical second harmonic generation data are presented resolving the nature of the structural distortion realized in electron-doped (Sr$_{1-x}$La$_x$)$_3$Ir$_2$O$_7$ with $x=0.035$…

Strongly Correlated Electrons · Physics 2017-06-28 Tom Hogan , Xiaoping Wang , H. Chu , David Hsieh , Stephen D. Wilson

Layered 5$d$ transition iridium oxides, Sr$_2$(Ir,Rh)O$_4$, are described as unconventional Mott insulators with strong spin-orbit coupling. The undoped compound, Sr$_2$IrO$_4$, is a nearly ideal two-dimensional pseudospin-$1/2$ Heisenberg…

Strongly Correlated Electrons · Physics 2017-05-02 Jaehong Jeong , Yvan Sidis , Alex Louat , Véronique Brouet , Philippe Bourges

We put forward a scheme to study the anisotropic magnetic couplings in Sr2IrO4 by mapping fully relativistic constrained noncollinear density functional theory including an on-site Hubbard U correction onto a general spin model Hamiltonian.…

Neutron diffraction measurements are presented exploring the magnetic and structural phase behaviors of the candidate J$_{eff}=1/2$ Mott insulating iridate Sr$_2$IrO$_4$. Comparisons are drawn between the correlated magnetism in this single…

Strongly Correlated Electrons · Physics 2013-04-09 Chetan Dhital , Tom Hogan , Z. Yamani , Clarina de la Cruz , Xiang Chen , Sovit Khadka , Zhensong Ren , Stephen D. Wilson

The iso-electronic $d^{4}$ compounds of the $4d$ series show rich phase diagrams due to competing spin, charge and orbital degrees of freedom in presence of strong correlations and structural distortions. One such iso-electronic series,…

Strongly Correlated Electrons · Physics 2018-07-10 Swagata Acharya , Dibyendu Dey , T Maitra , A Taraphder

Ba$_2$IrO$_4$ has been refined in the tetragonal $I4/mmm$ phase without octahedral rotations, and its physical properties have been interpreted in this high-symmetry structure. However, the dynamical stability of this undistorted phase has…

Materials Science · Physics 2025-12-30 Alaska Subedi

A structural phase transition from cubic $Fd\bar{3}m$ to tetragonal $I$4$_1$/$amd$ symmetry with $c/a >$ 1 is observed at $T_{\rm{S}}$ = 16 K in spinel GeCo$_2$O$_4$ below the N\'eel temperature $T_N$ = 21 K. Structural and magnetic…

We constructed, by the first-principles calculations, a magnetic phase diagram of Sr$_{2}$RuO$_4$ in the space spanned by structural distortions. Our phase diagram can qualitatively explain the experimental one for Ca$_{2-x}$Sr$_x$RuO$_4$.…

Materials Science · Physics 2016-08-31 Zhong Fang , Kiyoyuki Terakura

For the Sr2-xIrO4 system, recent work pointed out the abnormal electronic and magnetic properties around the critical point. Here, to understand Sr-vacancy effect on spin-orbit coupled Mott insulator Sr2IrO4, the electronic structure and…

Strongly Correlated Electrons · Physics 2019-01-07 Jie Cheng , Shengli Liu , Bin Li , Haiyun Wang , Yu Wang , Wei Xu

The phase diagram of Ca$_{2-x}$Sr$_x$RuO$_4$ has been studied by neutron diffraction on powder and single-crystalline samples. The experiments reveal antiferromagnetic order and structural distortions characterized by tilts and rotations of…

Superconductivity · Physics 2009-10-31 O. Friedt , M. Braden , G. Andre , P. Adelmann , S. Nakatsuji , Y. Maeno

The anisotropic magnetic properties of Sr$_2$IrO$_4$ are investigated, using longitudinal and torque magnetometry. The critical scaling across $T_c$ of the longitudinal magnetization is the one expected for the 2D XY universality class.…

Strongly Correlated Electrons · Physics 2016-04-20 L. Fruchter , D. Colson , V. Brouet

We investigate ultrafast dynamics from photoinduced reflectivity of Sr2RhO4 by using femtosecond near-infrared pulses. We observe a clear temperature-dependent anomaly in its electronic dynamics which slows down below 160 K. In addition,…

We use single-crystal neutron diffraction to determine the crystal structure symmetry and the magnetic evolution in the rhodium doped iridates $\rm Sr_2Ir_{1-x}Rh_{x}O_4$ ($0\leq x \leq 0.16$). Throughout this doping range, the crystal…

We carried out detailed studies of the magnetic structure, magnetoelastic coupling, and thermal properties of EuCrO$_3$ nano-powders from room temperature to liquid helium temperature. Our neutron powder diffraction and X-ray powder…

Strongly Correlated Electrons · Physics 2016-04-07 M. Taheri , F. S. Razavi , Z. Yamani , R. Flacau , P. G. Reuvekamp , A. Schulz , R. K. Kremer

A material in possession of localized 4f-electron magnetism and delocalized 3d-electron or band magnetism can often present A material in possession of localized 4f-electron magnetism and delocalized 3d-electron or band magnetism can often…

Strongly Correlated Electrons · Physics 2025-06-24 S W Lovesey

The structural, electronic, and optical properties of pyrochlore-type Pb$_{2}$Ir$_{2}$O$_{6}$O'$_{0.55}$, which is a metal without spatial inversion symmetry at room temperature, were investigated. Structural analysis revealed that the…

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