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A review of the approximations in any time-dependent density functional calculation of excitation energies is given. The single-pole approximation for the susceptibility is used to understand errors in popular approximations for the…

Materials Science · Physics 2007-05-23 Kieron Burke , Martin Petersilka , E. K. U. Gross

An explicit expression for the quadratic density-response function of a many-electron system is obtained in the framework of the time-dependent density-functional theory, in terms of the linear and quadratic density-response functions of…

Materials Science · Physics 2009-11-10 V. U. Nazarov , J. M. Pitarke , C. S. Kim , Y. Takada

We explore the ground states and dynamics of ultracold atomic droplets in the crossover region from three to two dimensions by solving the two-dimensional and the quasi two-dimensional extended Gross-Pitaevskii equations numerically and…

Dimensionality serves as an indispensable ingredient in any attempt to formulate the low-dimensional physics, and studying the dimensional crossover at a fundamental level is challenging. The purpose of this work is to study the…

Quantum Gases · Physics 2022-11-22 KangKang Li , Zhaoxin Liang

Development of the electronic kinetic-energy density functional is a subject of major interest in theoretical physics and chemistry. In this work, the nonlocal kinetic-energy functional is developed in terms of the response function for the…

Chemical Physics · Physics 2022-06-17 Hideaki Takahashi

To obtain accurate independent-particle descriptions for ferromagnetic two-dimensional van der Waals materials, we apply the quasiparticle self-consistent $GW$ (QSGW) method to VI$_3$, CrI$_3$, CrGeTe$_3$, and Fe$_3$GeTe$_2$. QSGW provides…

Strongly Correlated Electrons · Physics 2020-06-09 Y. Lee , Takao Kotani , Liqin Ke

Three-dimensional random electron systems undergo quantum phase transitions and show rich phase diagrams. Examples of the phases are the band gap insulator, Anderson insulator, strong and weak topological insulators, Weyl semimetal, and…

Disordered Systems and Neural Networks · Physics 2017-03-16 Tomi Ohtsuki , Tomoki Ohtsuki

We introduce a new class of exchange-correlation potentials for a static and time-dependent Density Functional Theory of strongly correlated systems in 3D. The potentials are obtained via Dynamical Mean Field Theory and, for strong enough…

Strongly Correlated Electrons · Physics 2015-05-18 Daniel Karlsson , Antonio Privitera , Claudio Verdozzi

The accuracy of density-functional theory (DFT) is determined by the quality of the approximate functionals, such as exchange-correlation in electronic DFT and the excess functional in the classical DFT formalism of fluids. The exact…

Upon increasing the electron density in a quantum wire, the one-dimensional electron system undergoes a transition to a quasi-one-dimensional state. In the absence of interactions between electrons, this corresponds to filling up the second…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Julia S. Meyer , K. A. Matveev , A. I. Larkin

The strongly correlated two-dimensional electron liquid within SmTiO$_3$/SrTiO$_3$/SmTiO$_3$ quantum well structures exhibits a pseudogap phase when the quantum well width is sufficiently narrow. Using low-temperature transport and optical…

Strongly Correlated Electrons · Physics 2023-05-08 Xinyi Wu , Lu Chen , Jianan Li , Megan Briggeman , Patrick B. Marshall , Susanne Stemmer , Patrick Irvin , Jeremy Levy

A quantitative and predictive theory of quantum light-matter interactions in ultra thin materials involves several fundamental challenges. Any realistic model must simultaneously account for the ultra-confined plasmonic modes and their…

We investigate the behavior of the kinetic and the exchange energy densities near the nuclear cusp of atomic systems. Considering hydrogenic orbitals, we derive analytical expressions near the nucleus, for single shells, as well as in the…

Other Condensed Matter · Physics 2016-04-01 L. A. Constantin , E. Fabiano , F. Della Sala

The results of tunnelling studies of the energy spectrum of two-dimensional (2D) states in a surface quantum well in a semiconductor with inverted band structure are presented. The energy dependence of quasimomentum of the 2D states over a…

Condensed Matter · Physics 2009-10-28 G. M. Minkov , A. V. Germanenko , V. A. Larionova , O. E. Rut

We identify peak and valley structures in the exact exchange-correlation potential of time-dependent density functional theory that are crucial for time-resolved electron scattering in a model one-dimensional system. These structures are…

Chemical Physics · Physics 2018-01-03 Yasumitsu Suzuki , Lionel Lacombe , Kazuyuki Watanabe , Neepa T. Maitra

Quantum effects of plasmonic phenomena have been explored through ab-initio studies, but only for exceedingly small metallic nanostructures, leaving most experimentally relevant structures too large to handle. We propose instead an…

Mesoscale and Nanoscale Physics · Physics 2015-09-24 Wei Yan , Martijn Wubs , N. Asger Mortensen

A density functional theory of two-dimensional freezing is presented for a soft interaction potential that scales as inverse cube of particle distance. This repulsive potential between parallel, induced dipoles is realized for paramagnetic…

Soft Condensed Matter · Physics 2009-05-28 Sven van Teeffelen , Christos N. Likos , Norman Hoffmann , Hartmut Löwen

We develop a scheme for building the scalar exchange-correlation (xc) kernel of time-dependent density functional theory (TDDFT) from the tensorial kernel of time-dependent {\em current} density functional theory (TDCDFT) and the Kohn-Sham…

Materials Science · Physics 2009-11-13 V. U. Nazarov , J. M. Pitarke , Y. Takada , G. Vignale , Y. -C. Chang

Multipole moments are the first order responses of the energy to spatial derivatives of the electric field strength. The quality of density functional theory (DFT) prediction of molecular multipole moments thus characterizes errors in…

Chemical Physics · Physics 2021-02-23 Diptarka Hait , Yu Hsuan Liang , Martin Head-Gordon

We construct a generalized-gradient approximation for the exchange-energy density of finite two-dimensional systems. Guided by non-empirical principles, we include the proper small-gradient limit and the proper tail for the exchange-hole…

Strongly Correlated Electrons · Physics 2014-03-26 J. G. Vilhena , E. Rasanen , M. A. L. Marques , S. Pittalis
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